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Growth and characterization of L‐histidine hydrochloride monohydrate single crystals

J. Madhavan、S. Aruna、Preema C. Thomas 等 6 位作者2006-12-22Crystal Research and Technology

Abstract Good optical quality single crystal of L‐histidine hydrochloride monohydrate (LHC) a novel semi organic NLO material was grown by slow solvent evaporation technique. The crystal was characterized by X‐ray diffractometry (XRD), Fourier Transform Infra‐red (FTIR), UV‐Vis‐NIR, TGA, DTA, microhardness and solubil…

Crystal structures of chemical compoundsNonlinear Optical Materials ResearchSolid-state spectroscopy and crystallography

Structural and magnetic studies of Mn‐doped ZnO

Vijay Kumar Sharma、R. Xalxo、G. D. Varma2006-12-22Crystal Research and Technology

Abstract The bulk samples of Mn‐doped ZnO were synthesized with the nominal compositions Zn 1‐x Mn x O (x = 0.02, 0.05, 0.10, 0.15) by the solid‐state reaction and sol‐gel methods. In both the methods the samples were finally sintered at ∼700 °C in air. The X‐ray diffraction (XRD) studies of the samples synthesized by…

ZnO doping and propertiesCopper-based nanomaterials and applicationsElectronic and Structural Properties of Oxides

Modulation of Fluorescence through Coassembly of Molecules in Organic Nanostructures

Heather A. Behanna、Kanya Rajangam、Samuel I. Stupp2006-12-22Journal of the American Chemical Society

This paper describes the fluorescence of bimolecular coassemblies that form one-dimensional nanostructures. One molecule is a fluorescent peptide amphiphile containing its branched stilbene chromophore covalently linked to the hydrophilic end of the amphiphile, and the second molecule is a shorter, nonfluorescent pept…

Luminescence and Fluorescent MaterialsSupramolecular Self-Assembly in MaterialsPolydiacetylene-based materials and applications

Influence of functional silanes on hydrophobicity of MCM-41 synthesized from rice husk

Siriluk Chiarakorn、Thanita Areerob、Nurak Grisdanurak2006-12-22Science and Technology of Advanced Materials

Mesoporous molecular sieve MCM-41 was synthesized from rice husk and rice husk ash, called RH-MCM-41 and RHA-MCM-41. The sol–gel mixtures were prepared with molar composition of 1.0 SiO2: 1.1 NaOH: 0.13 CTAB: 0.12 H2O. After calcination, the polarity of MCM-41 still remained on its surface due to the existence of some…

Zeolite Catalysis and SynthesisMesoporous Materials and CatalysisAerogels and thermal insulation

Structural properties of simulated liquid and amorphous TiO2

Vo Van Hoang2006-12-22physica status solidi (b)

Abstract Structural properties of liquid and amorphous TiO 2 have been studied in a model containing 3000 particles under periodic boundary conditions with the pairwise interatomic potentials proposed by Matsui and Akaogi. Models have been obtained by cooling from the melt via molecular dynamics (MD) simulation. Struc…

Phase Equilibria and ThermodynamicsMaterial Dynamics and PropertiesThermal and Kinetic Analysis

PLGA nanometer surface features manipulate fibronectin interactions for improved vascular cell adhesion

Derick C. Miller、Karen M. Haberstroh、Thomas J. Webster2006-12-22Journal of Biomedical Materials Research Part A

The largest cause of mortality in the Western world is atherosclerotic vascular disease. Many of these diseases require synthetic vascular grafts; however, their patency rate is only 30% in small (<6 mm) diameter vascular grafts after 5 years of implantation. In an effort to increase small diameter vascular graft succ…

Electrospun Nanofibers in Biomedical ApplicationsPolymer Surface Interaction StudiesTissue Engineering and Regenerative Medicine

Studies on the Influence of Phasins on Accumulation and Degradation of PHB and Nanostructure of PHB Granules inRalstoniaeutrophaH16

Kenny Kuchta、Lifeng Chi、Harald Fuchs 等 5 位作者2006-12-22Biomacromolecules

Phasins play an important role in the formation of poly(3-hydroxybutyrate) [PHB] granules and affect their size and number in the cells. Recent studies on the PHB granule proteome and analysis of the complete genomic DNA sequence of Ralstonia eutropha H16 have identified three homologues of the phasin protein PhaP1. I…

Enzyme Catalysis and Immobilizationbiodegradable polymer synthesis and propertiesElectrospun Nanofibers in Biomedical Applications

Facile synthesis of high-quality nano-sized CdS hollow spheres and their application in electrogenerated chemiluminescence sensing

Zhihui Dai、Jie Zhang、Jianchun Bao 等 5 位作者2006-12-22Journal of Materials Chemistry

CdS hollow spheres of about 25 nm average diameter and about 5 nm shell thickness can be easily synthesized in an aqueous solution of polyglycol. It was found that the polyglycol had a significant influence on the formation of the CdS hollow spheres, because when the experiments were carried out in the absence of poly…

Advanced Photocatalysis TechniquesQuantum Dots Synthesis And PropertiesChalcogenide Semiconductor Thin Films

Enhancement of Relaxivity Rates of Gd–DTPA Complexes by Intercalation into Layered Double Hydroxide Nanoparticles

Zhi Ping Xu、Nyoman D. Kurniawan、Perry F. Bartlett 等 4 位作者2006-12-22Chemistry - A European Journal

In this paper we report the preparation and characterization of [Gd(dtpa)](2-) intercalated layered double hydroxide (LDH) nanomaterials. [Gd(dtpa)](2-) (gadolinium(III) diethylene triamine pentaacetate) was transferred into LDH by anionic exchange. The intercalation of [Gd(dtpa)](2-) into LDH was confirmed by X-ray d…

Lanthanide and Transition Metal ComplexesLayered Double Hydroxides Synthesis and ApplicationsInorganic Chemistry and Materials

Formation Mechanism for Monodispersed Mesoporous Silica Spheres and Its Application to the Synthesis of Core/Shell Particles

Tadashi Nakamura、Mamoru Mizutani、Hiroshi Nozaki 等 5 位作者2006-12-22The Journal of Physical Chemistry C

A formation mechanism for monodispersed mesoporous silica spheres was investigated from the viewpoint of both particle growth and the progress of the condensation of the silica precursor. The particle growth of monodispersed mesoporous silica spheres was studied by TEM observation. The development of the mesopores was…

Catalytic Processes in Materials ScienceZeolite Catalysis and SynthesisMesoporous Materials and Catalysis

Photostability of Colloidal PbSe and PbSe/PbS Core/Shell Nanocrystals in Solution and in the Solid State

Jan W. Stouwdam、Jingning Shan、Frank C. J. M. van Veggel 等 6 位作者2006-12-22The Journal of Physical Chemistry C

The photostability of semiconductor PbSe nanocrystals (NCs) under different storage conditions and the photoluminescence of PbSe NC films on Si substrates under vacuum and under different atmospheres were investigated. The NCs show a small blue shift in both the emission and absorption spectra when stored in solution.…

Quantum Dots Synthesis And PropertiesChalcogenide Semiconductor Thin FilmsNanocluster Synthesis and Applications

Self-Assembly of Small Gold Colloids with Functionalized Gold Nanorods

Sébastien Pierrat、Inga Zins、Aaron Breivogel 等 4 位作者2006-12-22Nano Letters

We present a general strategy to stabilize gold nanorod suspensions with mono- and bifunctional polyethylene glycol (PEG) and to attach a controlled number of nanoparticles or biomolecules. Characterization by gel electrophoresis, transmission electron microscopy (TEM), and optical dark-field microscopy show the speci…

Nanoparticle-Based Drug DeliveryGold and Silver Nanoparticles Synthesis and ApplicationsNanocluster Synthesis and Applications

Clear Experimental Signature of Charge-Orbital density wave in Nd$_{1-x}$Ca$_{1+x}$MnO$_{4}$:Heat Capacity and Magnetization study

Sher Alam、A. T. M. N. Islam、T. Nagai 等 7 位作者2006-12-22arXiv

Single Crystals of Nd$_{1-x}$Ca$_{1+x}$MnO$_{4}$ have been prepared by the traveling floating-zone method, and possible evidence of a charge -orbital density wave in this material presented earlier [PRB68,092405 (2003)] using High Resolution Electron Microscopy [HRTEM] and Electron Diffraction [ED]. In the current not…

Materials ScienceStrongly Correlated Electrons

In-Situ Synthesis of Soluble Poly(3-hexylthiophene)/Multiwalled Carbon Nanotube Composite: Morphology, Structure, and Conductivity

Biplab Kumar Kuila、Sudip Malik、Sudip K. Batabyal 等 4 位作者2006-12-22Macromolecules

Soluble poly(3-hexylthiophene) (P3HT)−multiwalled carbon nanotube (MWNT) nanocomposites (PCNCs) are prepared by the in-situ oxidative polymerization of 3-hexylthiophene (3HT) in a dispersion of MWNT in CHCl 3 . The MWNT−P3HT nanocomposite produces blackish-brown solution in chloroform, making it an easily processable…

Organic Electronics and PhotovoltaicsCarbon Nanotubes in CompositesConducting polymers and applications

Heisenberg model on a space with negative curvature: topological spin textures on the pseudosphere

L. R. A. Belo、N. M. Oliveira-Neto、W. A. Moura-Melo 等 5 位作者2006-12-22arXiv

Heisenberg-like spins lying on the pseudosphere (a 2-dimensional infinite space with constant negative curvature) cannot give rise to stable soliton solutions. Only fractional solutions can be stabilized on this surface provided that at least a hole is incorporated. We also address the issue of `in-plane' vortices, in…

Materials ScienceStrongly Correlated Electrons

In Situ Synthesis of Gold Nanoparticles Using Molecular Gels and Liquid Crystals from Vitamin-C Amphiphiles

Praveen Kumar Vemula、Unaiza Aslam、V. Ajay Mallia 等 4 位作者2006-12-22Chemistry of Materials

Various organic self-assembled systems such as low-molecular-weight gels and liquid crystals have been utilized as efficient hosts for in situ synthesis and stabilization of gold nanoparticles using vitamin-C-based amphiphiles.

Gold and Silver Nanoparticles Synthesis and ApplicationsSurfactants and Colloidal SystemsPickering emulsions and particle stabilization

Excess-entropy-based anomalies for a waterlike fluid

Jeffrey R. Errington、Thomas M. Truskett、Jeetain Mittal2006-12-22The Journal of Chemical Physics

Many thermodynamic and dynamic properties of water display unusual behavior at low enough temperatures. In a recent study, Yan et al. [Phys. Rev. Lett. 95, 130604 (2005)] identified a spherically symmetric two-scale potential that displays many of the same anomalous properties as water. More specifically, for select p…

Phase Equilibria and ThermodynamicsMaterial Dynamics and PropertiesAdvanced Thermodynamics and Statistical Mechanics

The Movement of a Water Droplet on a Gradient Surface Prepared by Photodegradation

Yoshihiro Ito、Mojgan Heydari、Ayako Hashimoto 等 8 位作者2006-12-22Langmuir

A hydrophobic to hydrophilic gradient surface was prepared using the tuned photodegradation of an alkylsilane self-assembled monolayer (SAM) using irradiation of vacuum ultraviolet light (wavelength=172 nm). The water contact angle on the photodegraded SAM surface was adjusted using the intensity and time photoirradia…

Surface Modification and SuperhydrophobicityNanofabrication and Lithography TechniquesElectrowetting and Microfluidic Technologies

Controlled Synthesis of Icosahedral Gold Nanoparticles and Their Surface-Enhanced Raman Scattering Property

Kihyun Kwon、Kang Yeol Lee、Young Wook Lee 等 7 位作者2006-12-22The Journal of Physical Chemistry C

The aqueous-phase synthesis of icosahedral gold nanoparticles with controlled diameters ranging from 10 to 90 nm is reported. The nanoparticles were prepared by a seed-mediated growth approach. Citrate-capped 3.5 nm gold nanoparticles, prepared by reduction of HAuCl 4 with sodium borohydride, are used as seeds. Cetylt…

Nanoparticles: synthesis and applicationsGold and Silver Nanoparticles Synthesis and ApplicationsLaser-Ablation Synthesis of Nanoparticles

Geometry-induced smoothing of van Hove singularities in capped carbon nanotubes

D. V. Kolesnikov、V. A. Osipov2006-12-22arXiv

The electronic states of capped semi-infinite nanotubes are studied within the phenomenological gauge field-theory model. A single manifold for the description of both the nanotube and the cap region (considered as nearly a half of either Ih or I fullerene) is suggested. The wavefunctions and the density of states (Do…

Materials Science