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Quantitative analysis of chromate (CrVI) by normal Raman spectroscopy and surface-enhanced Raman spectroscopy using poly(diallyldimethylammonium) chloride-capped gold nanoparticles

Jun Xiao、Yaoyong Meng、P. L. Zhang 等 6 位作者2012-09-03Laser Physics

Chromate (CrVI) has emerged as a widespread environmental contaminant found in groundwater and surface water, and there is a great need for rapid detection and monitoring of this contaminant. Normal Raman scattering (NRS) spectroscopy with a detection limit of CrVI at concentrations of 0.2 g/L was attached. And surfac…

Gold and Silver Nanoparticles Synthesis and ApplicationsAnalytical chemistry methods developmentElectrochemical Analysis and Applications

Mössbauer study of the ‘11’ iron-based superconductors parent compound Fe1+xTe

A Błachowski、K Ruebenbauer、P Zajdel 等 5 位作者2012-09-03Journal of Physics Condensed Matter

(57)Fe Mössbauer spectroscopy was applied to investigate the superconductor parent compound Fe(1+x)Te for x = 0.06, 0.10, 0.14, 0.18 within the temperature range 4.2-300 K. A spin density wave (SDW) within the iron atoms occupying regular tetrahedral sites was observed, with the square root of the mean square amplitud…

Physics of Superconductivity and MagnetismMagnetic and transport properties of perovskites and related materialsIron-based superconductors research

Differentiation of Highly Anisotropic TbIII and DyIII with 57Fe Mössbauer Spectroscopy

Valeriu Mereacre2012-09-03Angewandte Chemie International Edition

Using (57)Fe Mössbauer spectroscopy, three examples of coordination compounds with different topologies containing Fe(III) and Ln(III) ions (Dy(III) and Tb(III); see diagram; insets: clusters cores) were analyzed. In the same crystal field environment, Dy and Tb ions show different degrees of anisotropy, which can be…

Metal-Organic Frameworks: Synthesis and ApplicationsMagnetism in coordination complexesLanthanide and Transition Metal Complexes

Significantly reduced fluorination time needed for suppression of space charge in polyethylene by increasing the fluorination temperature

Zhenlian An、Xuan Chen、Chenxia Liu 等 5 位作者2012-09-03Journal of Physics D Applied Physics

Abstract Polyethylene samples were surface fluorinated using a F 2 /N 2 mixture under 0.1 MPa at 35, 70 or 95 °C for different times. Space charge accumulation was found to show four basic types for each fluorination temperature with increasing fluorination time. But the fluorination times needed for the formation of…

Surface Modification and SuperhydrophobicityAdvanced Sensor and Energy Harvesting MaterialsHigh voltage insulation and dielectric phenomena

Synthesis and terahertz transmission properties of nano-porous vanadium dioxide films

Qiwu Shi、Wanxia Huang、Yinghao Xu 等 8 位作者2012-09-03Journal of Physics D Applied Physics

Abstract Vanadium dioxide (VO 2 ) films were prepared by the sol–gel method on high-purity silicon substrates, in which cetyltrimethyl ammonium bromide (CTAB) was used as a functional additive to form nano-porous structure in the VO 2 films. The morphology, crystalline structure and stoichiometry of the films were inv…

Gas Sensing Nanomaterials and SensorsPhotonic Crystals and ApplicationsTransition Metal Oxide Nanomaterials

Selectively probing vibrations in a plasmonic supracrystal

Pierre‐Adrien Mante、Hung-Ying Chen、Meng-Hsien Lin 等 6 位作者2012-09-03Applied Physics Letters

The coupling of plasmonic resonances with the multiple phonon modes of a plasmonic supracrystal is studied. Ultrafast optical pump-probe spectroscopy with variable wavelength allows the selective detection of the breathing mode, the interparticle vibrations, and the vibration of the whole structure. Thanks to this sel…

Gold and Silver Nanoparticles Synthesis and ApplicationsPlasmonic and Surface Plasmon ResearchNonlinear Optical Materials Studies

Hierarchical Supramolecular Spinning of Nanofibers in a Microfluidic Channel: Tuning Nanostructures at a Dynamic Interface

Munenori Numata、Yusuke Takigami、Momoko Takayama 等 5 位作者2012-09-03Chemistry - A European Journal

One of the fundamental problems in supramolecular chemistry, as well as in material sciences, is how to control the self-assembly of polymers on the nanometer scale and how to spontaneously organize them towards the macroscopic scale. To overcome this problem, inspired by the self-assembly systems in nature, which fea…

Supramolecular Self-Assembly in MaterialsAdvanced Materials and MechanicsPickering emulsions and particle stabilization

The influence of Cu on the electrochemical behaviour of 304 stainless steel in 0.1M H 3 PO 4 solution

Haiwen Luo、Xiaogang Li、Chaofang Dong 等 4 位作者2012-09-03Surface and Interface Analysis

The effect of different Cu addition on the electrochemical and passivation behaviour of the 304 series stainless steel in 0.1 M phosphoric acid solution was evaluated by the potentiodynamic measurements and electrochemical impedance spectrum (EIS). The effect of Cu on chemical composition of the passive film formed in…

Corrosion Behavior and InhibitionHydrogen embrittlement and corrosion behaviors in metalsConcrete Corrosion and Durability

Room Temperature Solid‐State Synthesis of a Conductive Polymer for Applications in Stable I2‐Free Dye‐Sensitized Solar Cells

Byeonggwan Kim、Jong Kwan Koh、Jeonghun Kim 等 8 位作者2012-09-03ChemSusChem

A solid-state polymerizable monomer, 2,5-dibromo-3,4-propylenedioxythiophene (DBProDOT), was synthesized at 25 °C to produce a conducting polymer, poly(3,4-propylenedioxythiophene) (PProDOT). Crystallographic studies revealed a short interplane distance between DBProDOT molecules, which was responsible for polymerizat…

TiO2 Photocatalysis and Solar CellsElectrochemical sensors and biosensorsConducting polymers and applications

Spin thermopower and thermoconductance in a ferromagnetic graphene nanoribbon

Shu-guang Cheng2012-09-03Journal of Physics Condensed Matter

The spin thermoelectric properties of a zigzag edged ferromagnetic (FM) graphene nanoribbon are studied theoretically by using the non-equilibrium Green's function method combined with the Landauer-Büttiker formula. By applying a temperature gradient along the ribbon, under closed boundary conditions, there is a spin…

Graphene research and applicationsQuantum and electron transport phenomenaTopological Materials and Phenomena

Plasma Printing and Related Techniques – Patterning of Surfaces Using Microplasmas at Atmospheric Pressure

Michael Thomas、Jochen Borris、Antje Dohse 等 8 位作者2012-09-03Plasma Processes and Polymers

Abstract The interest in applications of atmospheric‐pressure plasmas to solve surface‐technological tasks was originally motivated primarily by the expectation that major cost savings could be achieved if plasma‐based processes, conventionally run below 1 mbar, could now be performed at ambient pressure. However, it…

Surface Modification and SuperhydrophobicityPlasma Applications and DiagnosticsPlasma Diagnostics and Applications

Biodegradable metallic materials for orthopaedic implantations: A review

Kwk Yeung、Karen H.M. Wong2012-09-03Technology and Health Care

Non-degradable metals such as stainless steel, cobalt-chromium-based alloys, titanium and its alloys may lead to stress shielding effect after fractured bone has healed. This complication may attribute to the non-degradability and the mismatch of the mechanical properties between these metallic implants and human bone…

Orthopaedic implants and arthroplastyMagnesium Alloys: Properties and Applications

In Situ HT ‐ ESEM Observation of CeO 2 Grain Growth During Sintering

Renaud Podor、Nicolas Clavier、Johann Ravaux 等 5 位作者2012-09-03Journal of the American Ceramic Society

The CeO 2 sintering and grain growth kinetics were determined from in situ experiments performed using an environmental scanning electron microscope ( ESEM ) equipped with a hot stage in the temperature range 1000°C–1300°C. Videos were recorded during 8 h at various holding temperatures where the grain growth and grai…

Catalytic Processes in Materials ScienceAdvancements in Solid Oxide Fuel CellsNuclear Materials and Properties

Single crystal field-effect transistors containing a pentacene analogue and their application in ethanol vapor detection

Guangyao Zhao、Huanli Dong、Lang Jiang 等 6 位作者2012-09-03Applied Physics Letters

Organic field-effect transistors (OFETs) have attracted attention in the field of organic electronics. The conducting channel of OFETs is highly sensitive to out stimulus, so OFETs can be used as ultrasensitive sensors and actuators. Here, a new kind of OFET containing micro- and nanocrystals of a pentacene analogue i…

Organic Electronics and PhotovoltaicsPerovskite Materials and ApplicationsLuminescence and Fluorescent Materials

Study of semiconductor quantum dots influence on photorefractivity of liquid crystals

A. Anczykowska、Stanisław Bartkiewicz、Marcin Nyk 等 4 位作者2012-09-03Applied Physics Letters

In this paper, we present the results of doping nematic liquid crystals (nLCs) with semiconductor quantum dots (QDs) where we discuss the CdS and CdSe QDs influence on the optical properties of investigated liquid crystal structures, i.e., diffraction efficiency enhancement. We also present the mathematical model desc…

Photonic and Optical DevicesLiquid Crystal Research AdvancementsPhotonic Crystals and Applications

H2O2‐ and pH‐sensitive CdTe quantum dots as fluorescence probes for the detection of glucose

Yinping Li、Baoxin Li、Junli Zhang2012-09-03Luminescence

A novel fluorescence assay system for glucose was developed with thioglycollic acid (TGA)-capped CdTe quantum dots (QDs) as probes. The luminescence quantum yield of the TGA-capped CdTe QDs was highly sensitive to H2 O2 and pH. In the presence of glucose oxidase, glucose is oxidized to yield, gluconic acid and H2 O2 .…

Quantum Dots Synthesis And PropertiesChalcogenide Semiconductor Thin FilmsNanocluster Synthesis and Applications

Defect microstructural evolution in ion irradiated metallic nanofoils: Kinetic Monte Carlo simulation versus cluster dynamics modeling and in situ transmission electron microscopy experiments

Donghua Xu、Brian D. Wirth、Meimei Li 等 4 位作者2012-09-03Applied Physics Letters

Understanding materials degradation under intense irradiation is important for the development of next generation nuclear power plants. Here we demonstrate that defect microstructural evolution in molybdenum nanofoils in situ irradiated and observed on a transmission electron microscope can be reproduced with high fid…

Fusion materials and technologiesNuclear Materials and PropertiesIon-surface interactions and analysis

Mg acceptor doping of In2O3 and overcompensation by oxygen vacancies

Oliver Bierwagen、James S. Speck2012-09-03Applied Physics Letters

Mg-doped indium oxide (In2O3) thin films were grown by plasma-assisted molecular beam epitaxy with Mg-concentrations ranging from 1017 to 6×1020 cm−3. In this concentration range Mg was incorporated into In2O3 without discernable impediment nor formation of secondary phases. Despite the role of Mg as acceptor, the fil…

ZnO doping and propertiesGas Sensing Nanomaterials and SensorsSemiconductor materials and devices

Metal Carbonyl–Gold Nanoparticle Conjugates for Live‐Cell SERS Imaging

Kien Voon Kong、Zhiyong Lam、Wenda Douglas Goh 等 5 位作者2012-09-03Angewandte Chemie

Konjugate aus metallorganischen Osmiumcarbonyl-Clustern und Gold-Nanopartikeln (siehe Bild) zeigen ein starkes Carbonylsignal in der oberflächenverstärkten Raman-Spektroskopie. Die Einfachheit der Biofunktionalisierung sowie die hohe Stabilität und gute Dispergierbarkeit in wässriger Lösung machen diese Konjugate zu e…

Gold and Silver Nanoparticles Synthesis and ApplicationsAdvanced biosensing and bioanalysis techniquesNanocluster Synthesis and Applications

Unusual lattice constant changes and tunable magnetic moment compensation in Mn50−xCo25Ga25+x alloys

G. J. Li、Enke Liu、Hou-bin Zhang 等 8 位作者2012-09-03Applied Physics Letters

We report on unusual lattice parameter changes and tunable magnetic moment compensation in Mn50−xCo25Ga25+x (x = 0-25) Heusler alloys by substituting Ga for Mn. The observed lattice parameter first increases with increasing Ga content x, showing a maximum at x = 12.5, and then abnormally decreases due to the enhanced…

Shape Memory Alloy TransformationsMultiferroics and related materialsHeusler alloys: electronic and magnetic properties