Materials Literature
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Fluorescence piezo-spectroscopy (PS) was applied to evaluate the residual stress fields stored in a multilayered Al(2)O(3)/3Y-TZP (3 mol% Y(2)O(3)-stabilized ZrO(2)) composite using the chromophoric fluorescence spectra of Al(2)O(3). The PS results were compared with a theoretical stress distribution in the laminate,…
A new zwitterionic monolayer film of sulfobetaine was constructed by grafting novelly designed N,N-dimethyl (beta-hydroxyethyloxyethyl) ammonium propanesulfonate (DHAPS) to hydroxyl groups of glass in the presence of hexamethylene diisocyanate (HDI) as a coupling agent and dibutyltin dilaurate (DBTDL) as a catalyst. E…
Abstract The continuous production of ultra‐high‐molecular‐weight polyethylene (UHMWPE) filaments was studied by the direct roll forming of nascent reactor powders followed by subsequent multistage orientation drawing below their melting points. The UHMWPE reactor powders used in this study were prepared by the polyme…
Abstract Aqueous acrylic–polyurethane hybrid emulsions were prepared by the semibatch emulsion copolymerization of methyl methacrylate and butyl acrylate in the presence of eight polyurethane dispersions. The polyurethane dispersions were synthesized with isophorone diisocyanate, 1000 and 2000 molecular weight polyest…
Abstract Diatoms are photosynthetic unicellular, eukaryotic, microorganisms (algae) that are distinguished by their silicified (SiO 2 ‐nH 2 O) cell walls. They have often been employed to assess salinity, pH, and nutrient conditions. Our data suggest that, they may also be used to assess suspended solid levels in stre…
The synthesis of a novel ligand, based on N-methyl-diethylenetriaminetetraacetate and containing a diphenylcyclohexyl serum albumin binding group (L1) is described and the coordination chemistry and biophysical properties of its Gd(III) complex Gd-L1 are reported. The Gd(III) complex of the diethylenetriaminepentaacet…
Abstract Microwave plasma treatments were applied to lightweight cotton fabric with oxygen, nitrogen, and argon at various microwave power levels and exposure times. The results showed significant effects from the type of plasma, microwave power, and treatment time on the fabric weight loss. Oxygen plasma treatment ge…
Abstract Poly( L ‐lactic acid) (PLLA) was blended with poly(ethylene‐ co ‐vinyl alcohol) (EVOH) in the presence of an esterification catalyst to induce reaction between the hydroxyl groups of EVOH and the terminal carboxylic group of PLLA. Nascent low‐molecular‐weight PLLA, obtained from a direct condensation polymeri…
Abstract A new approach is described for utilizing the swelling characteristics of montmorillonite (MMT) to compensate for polymerization‐induced shrinkage in unsaturated polyester. The naturally sorbed sodium cation, at the lamellar interface of the mineral, was exchanged with the onium salt of 12‐aminolauric acid to…
Abstract Diamond synthetic single crystals exhibiting a high and reliable quality would find many applications in different areas such as optics, mechanics, or electronic devices. In this study, thick high quality homoepitaxial diamond films were grown on synthetic substrates using Micro‐Wave Plasma Assisted Chemical…
Abstract The water absorption and hygrothermal aging behavior of organomontmorillonite (OMMT) reinforced polyamide 6/polypropylene (PA6/PP ratio = 70/30), with and without maleated PP (MAH‐ g ‐PP), was studied at three different temperatures (30, 60, and 90°C). The water absorption and hygrothermal aging response of t…
Durch Einschluss eines paramagnetischen Verschiebungsreagens (SR) für Wasserprotonen in Liposomen wird die Empfindlichkeit von CEST-Agentien (CEST: chemical exchange saturation transfer) erheblich verbessert. Die chemische Verschiebung von Wasser in den Liposomen gegenüber der von freiem Wasser hängt von der Natur und…
Fully aromatic polyimide films containing uniformly oriented Ag nanorods (see Figure) have been prepared by a simple method consisting of thermal curing and uniaxial drawing of submicrometer-scale phase-separated polyimide-blend films containing dissolved AgNO3. The films exhibit outstanding optical dichroism, over 20…
In Gegenwart eines zweizähnigen Phosphanliganden reagieren Silbercarboxylate mit einer Mischung von S(tBu)SiMe3 und S(SiMe3)2 zu den sphäroiden Clustern [Ag123S35(StBu)50] (1) und [Ag344S124(StBu)96] (2; siehe Bild: Ag+ blau, S-Atome der StBu-Gruppen rot, S2− gelb, C grau) mit maximalen Durchmessern von 2.5 bzw. 3.7 n…
Boron nitride nanohorns (BNNHs) are synthesized in large scale. Their morphology and structure were investigated by scanning electron microscopy and transmission electron microscopy. The hollow conical structure and particular aggregation behavior are revealed. Cathodoluminescence measurement is performed and ultravio…
Abstract Summary: Hydrophilic polymeric films based on blends of hydroxyethylcellulose and maleic acid‐ co ‐methyl vinyl ether were produced by casting from aqueous solutions. The physicochemical properties of the blends have been assessed using Fourier transform infrared spectroscopy, thermal gravimetric analysis, di…
Surface-enhanced micro-Raman spectroscopy (micro-SERS) was used to detect traces of the hazardous pollutant polycyclic aromatic hydrocarbons (PAHs) pyrene and benzo[c]phenanthrene deposited onto a calix[4]arene-functionalized Ag colloidal surface. High spectral reproducibility and very low molecular detection limits (…
It is well-known that hydrodynamic pressures in a thin draining liquid film can cause inversion of the curvature of a drop or bubble surface as it approaches another surface, creating a so-called "dimple". Here it is shown that a more complicated rippled shape, dubbed a "wimple", can be formed if a fluid drop that is…
Abstract For the synthesis of aromatic polyesters with defined molecular weights and narrow molecular weight distributions (MWDs), we investigated the chain‐growth polycondensation of active amide derivatives of 4‐hydroxybenzoic acid, 1a and 1b , having an octyl or 4,7‐dioxaoctyl side chain, respectively. To suppress…
Abstract A new intumescent flame retardant (PSiNII), which contains silicon, phosphorus, and nitrogen elements, has been synthesized and incorporated into polypropylene (PP). Its effect on the properties of PP is investigated based on flame retardancy, thermal properties, mechanical properties, and morphologies. The f…