Materials Literature
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Initiated chemical vapor deposition (iCVD) of poly(glycidyl methacrylate) from supersaturated monomer vapor is reported. Rapid film growth rates, up to 600 nm/min, were observed. Films grown from supersaturated monomer exhibited distinct surface undulations. The temporal evolution of surface features during film growt…
Uniform quaternary Cu(2)FeSnS(4) (CITS) nanotubes of outer diameter 400-800 nm and thickness 100-200 nm have been synthesized for the first time by a simple, rapid and easily scaled-up microwave nonaqueous route using benzyl alcohol as the microwave absorbing solvent. An interesting in situ generated one-dimensional C…
Porous silica-supported metallic Pd catalysts were prepared in three steps: (1) synthesis of oleylamine-capped Pd nanoparticles, (2) silica polymerization around the oleylamine-capped Pd in a water-in-oil microemulsion system and (3) removal of the capping agent through calcination. With the characterization of transm…
The synthesis of a series of novel core-modified and fused-ring-expanded tetraphenylporphyrins is reported. Theoretical calculations and magnetic circular dichroism (MCD) and fluorescence spectroscopic measurements were used to analyze the effect of core modification with Group 16 oxygen, sulfur, selenium, and telluri…
Abstract A periodic mesoporous organosilica (PMO) with chiral cyclohexyldiamine‐based nickel(II) complexes incorporated within the silica framework was prepared through a co‐condensation of (1R,2R)‐cyclohexyldiamine‐derived silane and Ph‐bridged silane followed by complexation of nickel(II) bromide in the presence of…
A reliable and reproducible surface-enhanced Raman scattering (SERS) measurement utilizing Au nanoparticle-encapsulated hydrogels as a substrate has been demonstrated. A hydrogel matrix was adopted to: (i) take advantage of its excellent water uptake capacity for facile access of an analyte into the substrate and (ii)…
ZnO quantum dots with tunable size in the range of 2.0–7.8 nm were synthesized through a facile sol–gel route. Photoluminescence and photoluminescence excitation spectral examinations revealed that two types of transition mechanisms might occur under control during excitation regulation corresponding to the coexistenc…
Multidrug resistance (MDR) is one of the factors in the failure of anticancer chemotherapy. In order to enhance the anticancer effect of P-glycoprotein (P-gp) substrates, inhibition of the P-gp efflux pump on MDR cells is a good tactic. We designed novel multifunctional drug-loaded alpha-tocopheryl polyethylene glycol…
This work proposes a thermally rotatable grating that is based on hybrid-aligned cholesteric liquid crystals (HBA-cholesteric LCs). Experiments reveal that the HBA-cholesteric texture has a uniformly striped domain, which forms a grating, when the ratio of the cell gap to the helical pitch (d/p) is in the range of 2≤d…
contrast agents are small molecule chelates of gadolinium [Gd(III)] that affect bound water proton relaxivity. Both the small size and monomeric nature of these agents ultimately limits the image resolution enhancement that can be achieved for both contrast enhancement and pharmacokinetic/biodistribution reasons. The…
Dynamically oleophobic surfaces for alkane liquids, such as n-decane, n-dodecane and n-hexadecane, were successfully prepared using a simple sol–gel mixture containing 3,3,3-trifluoropropyltrimethoxysilane (FAS3) and tetramethoxysilane (TMOS). Due to the enhancement of the motion of functional groups by addition of TM…
The purely hexagonal phase of ultrasmall (~10 nm) NaYF(4) nanocrystals (NCs), containing different Eu concentrations, has been obtained by a modified co-thermolysis method. Detailed investigations of the excitation and relaxation mechanisms of the Eu ions in such NCs are reported. Based on the photoluminescence excita…
Metal corrosion is an electrochemical reaction between the environment and a metal, in which microbes are thought to play a very important role. The rates at which various types of metals corrode are dependent upon environmental conditions as well as on the type of metals. The most well studied bacteria involved in bi…
Semiconductor-metal nanocomposite materials composed of ZnS-AgInS 2 solid solution (ZAIS) nanoparticles and SiO 2 -coated Au particles were prepared, the particle distance between ZAIS and Au being precisely adjusted in nanometer scale by changing the thickness of the SiO 2 coating layer on Au core particles. The SiO…
Bodipy laser dyes are highly efficient but degrade rapidly in solution by reacting with in situ generated singlet oxygen ((1)O(2)). To increase the lasing lifetimes of these dyes, we have designed and synthesised two different congeners of the widely studied Pyrromethene 567 (PM567) by substitution at the boron centre…
The structural and optoelectronic properties of ZnO nanopillars (ZnO-NPs) grown on Si substrates by the vapor transport deposition method were investigated. In particular, by varying the deposition duration and hence the morphology of the vertically aligned ZnO-NPs, the resultant field emission characteristics were sy…
Responsive nanohelices can be self-assembled via asymmetric coordination bonding between AgNO3 and melamine. Silver nanochains composed of nanoparticles can be synthesized simply by photo-reduction of the above complex.
Phenanthroline-based hexadentate ligands L(1) and L(2) bearing two achiral semicarbazone or two chiral imine moieties as well as the respective mononuclear complexes incorporating various lanthanide ions, such as La(III), Eu(III), Tb(III), Lu(III), and Y(III) metal ions, were synthesized, and the crystal structures of…
The intermetallic compound ZnSb is an electron poor (II–V) semiconductor with interesting thermoelectric properties. Electrical resistivity, thermopower and thermal conductivity were measured on single crystalline and various polycrystalline specimens. The work establishes the presence of impurity band conduction as a…
Herein we report a green approach for the synthesis of metal/metal oxide nanoparticle decorated multiwalled carbon nanotubes using focused solar radiation. The synthesis method demonstrates a large scale, cost effective and spontaneous production of carbon nanotube supported metal/metal oxide nanoparticles for energy…