Materials Literature
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Blue (<480 nm) emitting Cd-free quantum dots (QDs) are in great demand for various applications. However, their synthesis has been challenging. Here we present blue emitting InP/ZnS core/shell QDs with a band edge emission of 475 nm and a full width at half maximum of 39 nm (215 meV) from their quantum confined states…
Abstract Few‐layer graphene‐like sheets of MoS2, WS2, MoSe2 and WSe2 were prepared by employing two methods. The first method uses microwave synthesis in ethylene glycol or water medium and the second method involves laser irradiation of the bulk samples dispersed in dimethylformamide. The few‐layer dichalcogenide sam…
A new type of acceptor-donor(2) dyad system containing two magnesium porphyrin molecules and a fullerene molecule is much more stable than the magnesium porphyrin itself. When it is fabricated into a binary system using imidazole carboxylic acid as a linker to indium tin oxide, the molecule effects efficient photocurr…
Electrochemically functional graphene nanocomposites have been directly prepared by one-step liquid-phase exfoliation of natural flake graphite with methylene blue (MB). UV-visible spectra of the obtained aqueous dispersions of graphene-methylene blue (G-MB) nanocomposite at different exfoliation time indicate that th…
Colossal permittivity (ε′ = 301,484 at room temperature and 1 kHz) of barium titanate was induced in ceramics synthesized using the microwave sintering method. Three different sintering processes (conventional, spark plasma, and microwave) were performed to better understand colossal permittivity in sintered barium ti…
Enhanced local electric fields are created by nanoparticles when pumped at wavelengths corresponding to Localised Surface Plasmon Resonance (LSPR) modes, leading to Metal Induced Fluorescence Enhancement (MIFE). This paper describes the fluorescent enhancement due to reproducible and tuneable Au nanostructures on glas…
Abstract After purification by Fenton treatment, commercial diamond nanoparticles (NPs) are a suitable solid support for the deposition of Cu nanoparticles. Heating at 500 °C under hydrogen proved to be a convenient annealing process for Fenton‐purified diamond NPs that decreased the population of surface carboxylic a…
Magnetite nanoparticles (MNPs) coated with poly(acrylic acid-co-maleic acid) polyelectrolyte (PAM) have been prepared with the aim of improving colloidal stability of core-shell nanoparticles for biomedical applications and enhancing the durability of the coating shells. FTIR-ATR measurements reveal two types of inter…
Resonant inelastic X-ray scattering (RIXS) experiments require special sets of near-backscattering spherical diced analyzers and high-resolution monochromators for every distinct absorption-edge energy and emission line. For the purpose of aiding the design and planning of efficient RIXS experiments, comprehensive lis…
Anisotropic microparticles adsorbed at fluid–fluid interfaces create interface deformations and interact because of capillarity. Thus far, much of the work related to this phenomenon has focused on capillary attraction, which is ubiquitous in the far field for microparticles at interfaces. In this paper, we explore ca…
We study the electrolyte-gate-induced conductance at the surface of SrTiO(3)(001). We find two distinct transport regimes as a function of gate voltage. At high carrier densities, a percolative metallic state is induced in which, at low temperatures, clear signatures of a Kondo effect are observed. At lower carrier de…
This paper proposes a novel methodology to improve noncollisional photochemical reactions such as Förster resonance energy transfer on solid surfaces. Since an excited guest molecule densely adsorbed on the solid surfaces is quenched by an unfavorable interaction between guests in general, the photochemical reactions…
A variety of nanoparticles have been proposed for several biomedical applications. To gauge the therapeutic potential of these nanoparticles, in vivo biodistribution is essential and mandatory. In the present study, ceria nanoparticles (5 nm average particle size) were labeled with (18)F to study their in vivo biodist…
Combining different experimental techniques, investigations in hexagonal $P{6}_{3}/mmc$ Er${}_{2}$Fe${}_{17}$ show remarkable magnetovolume anomalies below the Curie temperature, ${T}_{C}$. The spontaneous magnetostriction reaches $1.6\ifmmode\times\else\texttimes\fi{}{10}^{\ensuremath{-}2}$ at 5 K and falls to zero w…
In March 2012, a group of researchers met to discuss emerging topics in ceramic science and to identify grand challenges in the field. By the end of the workshop, the group reached a consensus on eight challenges for the future:—understanding rare events in ceramic microstructures, understanding the phase‐like behavio…
A heterospin dinuclear complex [Dy(0.87)Yb(1.13)(H(2)cht)(2)Cl(4)(H(2)O)(MeCN)]·MeCN shows shifts of the relaxation barriers with respect to the barriers observed in homospin Dy(2) and Yb(2) isostructural complexes. The origin of slow relaxation in the latter two compounds was elucidated by ab initio calculations.
Controls over the atomic dispersity and particle shape of noble metal catalysts are the major qualities determining their usability in industrial runs, but they are usually difficult to be simultaneously realized. Inspired from the Deacon catalyst in which RuO(2) can form epitaxial layers on the surfaces of Rutile TiO…
We study the collective dynamics of interacting paramagnetic colloids transported via a magnetic ratchet effect above a modulated periodic potential. Upon increasing the modulation frequency, the particles undergo a series of dynamic transitions, from a continuous smectic flow to a disorder flow, and later enter into…
Scatterometry is a well-established, fast and precise optical metrology method used for the characterization of sub-lambda periodic features. The Fourier scatterometry method, by analyzing the Fourier plane, makes it possible to collect the angle-resolved diffraction spectrum without any mechanical scanning. To improv…
A sequence of seven nematic phases has been observed in chiral mesogenic dimers, having odd number of carbon atoms in the spacer, thus a bent shape. The highest temperature phase is a chiral nematic (cholesteric) phase on heating or blue phases on cooling. The lowest temperature nematic phase expels the chiral twist a…