Materials Literature
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Alkaline earth metal nitrate coordination compounds with hexamethylenetetramine, []], have been synthesized and characterized by elemental and thermal analysis, IR spectroscopy, and X-ray crystallography. Introduction of hmta to the outer coordination sphere allows changing of the inner coordination sphere giving the…
Here, we demonstrated the involvement of the domains in Arabidopsis high-light responsive serine/arginine-rich (SR) and SR-like proteins, atSR30 and atSR45a, respectively, in subcellular and subnuclear distribution using a series of structural domain-deleted mutants. Judging from the localization of the transiently ex…
Abstract Molecular dynamics calculations can reveal the physical and chemical properties of various carbon nanostructures or can help to devise the possible formation pathways. In our days the most well‐known carbon nanostructures are the fullerenes, the nanotubes, and the graphene. The fullerenes and nanotubes can be…
Long-range intraprotein interactions play important roles in protein folding. In the present study, we use two variants of the B domain of protein A (BdpA F14W/G30A and BdpA_ds) and two variants of the Trp cage (TC5b_P1 and TC5b_P2) as models to investigate how long-range hydrophobic interactions affect protein tertia…
Abstract. To improve the model prediction for the formation of H2SO4 and methanesulfonic acid (MSA), aerosol-phase reactions of gaseous dimethyl sulfide (DMS) oxidation products [e.g., dimethyl sulfoxide (DMSO)] in aerosol have been included in the DMS kinetic model with the recently reported gas-phase reactions and t…
Abstract The type-III ELMy H-mode might be the solution for an integrated ITER operation scenario fulfilling the fusion power amplification factor (output fusion power to input heating power) of Q = 10 with simultaneous acceptable steady-state and transient power loads to the plasma-facing components. This highly radi…
In this work, we show that vertical, high aspect-ratio (HAR) photonic crystals (PhCs), consisting of periodic arrays of 5 µm wide gaps with depth of 50 µm separated by 3 µm thick silicon walls, fabricated by electrochemical micromachining, can be used as three-dimensional microincubators, allowing cell lines to be sel…
In this Letter we report a comparative study, in the infrared regime, of surface plasmon polariton (SPP) propagation in epitaxially grown Ag films and in polycrystalline Ag films, all grown on Si substrates. Plasmonic resonance features are analyzed using extraordinary optical transmission (EOT) measurements, and SPP…
We numerically investigate the mechanism of super rebounds (rebounds in which the restitution coefficient is larger than unity) for head-on collisions between nanoclusters. It is confirmed that the temperature and the entropy of the nanocluters decrease after the super rebounds by our molecular dynamics simulations. I…
A symmetric ultracapacitor CNT_CNT and an asymmetric ultracapacitor CNT_hRuO(2) of mini size have been prepared with patterned carbon nanotubes (CNT) and hydrous ruthenium dioxide. Galvanostatic charge/discharge results indicate that CNT_hRuO(2) is the superior one in both power and energy densities. In a potential wi…
Abstract Iron‐mediated atom transfer radical polymerizations with activators generated by electron transfer of methyl methacrylate in N,N‐dimethylformamide solution in the presence and absence of a limited amount of air, using FeCl3·6H2O as the catalyst, ethyl 2‐bromoisobutyrate (EBiB) as the initiator, vitamin C as t…
Ultrasonic-measurement-integrated (UMI) simulation of blood flow is used to analyze the velocity and pressure fields by applying feedback signals of artificial body forces based on differences of Doppler velocities between ultrasonic measurement and numerical simulation. Previous studies have revealed that UMI simulat…
We report a fundamentally new approach to enhance fluorescence in which surface adsorbed fluorophore-tagged biomolecules are excited on a photonic crystal surface that functions as a narrow bandwidth and tunable mirror of an external cavity laser. This scheme leads to ∼10× increase in the electromagnetic enhancement f…
Abstract Diblock copolymers consisting of a multibranched polymethacrylate segment with densely grafted poly[2‐(2‐methoxyethoxy)ethyl vinyl ether] pendants and a poly(N‐isopropylacrylamide) segment were synthesized by a combination of living cationic polymerization and RAFT polymerization. A macromonomer having both a…
Abstract Several mixed oxide catalysts were prepared by coprecipitation for dimethyl carbonate (DMC) synthesis from methyl carbamate and methanol. During the batch process, the DMC yield was below 35 %. In order to minimize the unfavorable thermodynamic equilibrium and side reactions for the DMC synthesis, a fixed‐bed…
Abstract A 3 kV electron-beam irradiation of a C60 film gives rise to formation of one-dimensional (1D) uneven peanut-shaped C60 polymer with a cross-linked structure close to that of the P08 C120 stable isomer obtained from the general Stone–Wales rearrangement. In this study, we examined the evolution of infrared (I…
Abstract A simple strategy for the synthesis and functionalization of polyurethanes is described. Anionic ring‐opening polymerization was combined with ‘click’ chemistry to synthesize polyols with fluorescent properties. This route allows the incorporation of a wide range of functionalities in the polyols with an easy…
The systematic misindexing caused by pseudo-symmetry Kikuchi diffraction patterns in automated Electron Backscatter Diffraction analysis has been studied in a 9Cr-1Mo ferritic steel. Grains with its [1 1 1] directed towards detector centre were found to be prone to misindexing, and the solutions exhibit a relative ori…
This study provides a detailed charge density distribution analysis supported by comprehensive energetic investigations. The nature of the intermolecular interactions existing in the 9-methyladenine:1-methylthymine cocrystal structure with respect to those specific for the corresponding monocomponent crystals is explo…
We report a simple, fast and selective colorimetric assay of adenosine triphosphate (ATP) using unmodified gold nanoparticles (AuNPs) as probes and metal ions as cross-linkers. ATP can be assembled onto the surface of AuNPs through interaction between the electron-rich nitrogen atoms and the electron-deficient surface…