Materials Literature
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The magnetic properties of a series of YBa2Cu3O7−x/La2/3Ca1/3MnO3 (YBCO/LC1/3MO) superlattices grown by dc sputtering at high oxygen pressures (3.5 mbar) show the expected ferromagnetic behavior. However, field-cooled hysteresis loops at a low temperatures show the unexpected existence of exchange bias effect associat…
An n-channel accumulation-type field-effect transistor (FET) has been fabricated utilizing a KTaO3 single crystal as an active element and a sputtered amorphous Al2O3 film as a gate insulator. The device demonstrated an ON/OFF ratio of 104 and a field-effect mobility of 0.4 cm2/V s at room temperature, both of which a…
The pyrochlore antiferromagnet Tb2Ti2O7 has proven to be an enigma to experimentalists and theorists working on frustrated magnetic systems. The experimentally determined energy level structure suggests a local <111> Ising antiferromagnet at low temperatures, T < 10 K. An appropriate model then predicts a long-range o…
We studied through Monte Carlo simulations, the kinetics of the two-species diffusion-limited reaction model with same species excluded volume interaction in substrates embedded on a square lattice ranging in occupancy from a fractal percolating structure to the compact limit. We study the time evolution of the concen…
Interparticle forces in a nematic liquid-crystal colloid have been directly observed by the dual beam laser trapping method with pN sensitivity. We introduce two different types of spatial distributions of forces, detected between the particles accompanied by hyperbolic hedgehog defects. These force distributions lead…
Thermal engineering of many nanoscale sensors, actuators, and high-density thermomechanical data storage devices, as well as the self-heating in deep submicron transistors, are largely influenced by thermal conduction in ultrathin silicon layers. The present study measures the lateral thermal conductivity of single-cr…
The relationships between microstructure, mechanical behaviour and magnetic properties of completely pearlitic steels have been investigated, with the objective of determining the applicability of magnetic measurements to non-destructive evaluation of the properties of high-strength pearlitic steels. High-carbon steel…
Although magnetic wound cores have simple geometries, their magnetic properties vary in a complex manner depending on many factors such as core geometry, dimensions and interlaminar air flux between adjacent wound layers. These can set up internal stress which seriously affects internal flux distribution and hence per…
The microhardness H of multilayered poly(ethylene terephthalate) (PET)/polycarbonate (PC) films, produced by continuous layer multiplying coextrusion has been determined. These materials present rather uniform laminates up to thousands of layers in the micrometre and submicrometre range. The micromechanical properties…
Noncatalytic partial oxidation of methane has been studied over a wide temperature range from 823 to 1531 K using two flow reactors. Highly diluted fuel-rich CH4/O2/N2 mixtures were reacted in uncoated tubular flow reactors at 1.2 atm. Residence time was varied from 1 to 164 s. Major and minor products of the partial…
The effect of wetting layers on the strain and electronic structure of InAs self-assembled quantum dots grown on GaAs is investigated with an atomistic valence-force-field model and an empirical tight-binding model. By comparing a dot with and without a wetting layer, we find that the inclusion of the wetting layer we…
Spin dynamics of a metallic ferromagnetic film imbedded between normal metal layers is studied using the spin-pumping theory of Tserkovnyak et al. [Phys. Rev. Lett. 88, 117601 (2002)]. The scattering matrix for this structure is obtained using a spin-dependent potential with quantum well in the ferromagnetic region. O…
Abstract The crystal structure of the gallium hydrogen phosphate hydrate, Ga 3 (H 3 O)H 8 (PO 4 ) 6 · 6 H 2 O, has been determined from X-ray powder diffraction data. The structure is trigonal, space group P 31 c (No. 159), with unit cell dimensions a = 9.0227(1) Å, c = 16.6389(3) Å, V = 1173.08(3) Å 3 , Z = 2, and D…
전산모사를 이용하여 특성을 정확하게 모사하기 위해서는 전지 내부에서 발생하는 다양한 물리적, 화학적 현상을 고려하여야 한다. 이를 위해, 본 연구에서는 다양한 전지 내부 현상에 대한 변수를 고려할 수 있는 전산유체 상용코드인 CFD-ACE+를 이용하여 평판형 고체산화물 연료전지의 작동 특성을 분석하였다. 단위 스택에서 발생하는 물질전달과 열전달 및 전기화학 반응에 의한 전하이동을 복합적으로 고려하여, 작동조건 하에서 각 공정적, 구조적 변수 변화에 따른 전지특성을 예측하였다. 이러한 전산모사 방법을 통하여 확산과 유동에 의한 전지 내 반응물과 생성물의 mass fr…
Systematic studies of the transport properties of La(0.67)Ca(0.33)Mn(1-x)Fe(x)O3 (x=0-0.3) systems showed that with increasing Fe-doping content x the resistance increases and the insulator-metal transition temperature moves to lower temperature. For small doping content, the transport property satisfies metal transpo…
EPDM sulphur-cure compounds that are mouldable and curable in acceptable times at relatively low temperatures have recently been developed and patented. Besides the associated reduced manufacturing energy, and hence reduced environmental costs, technical benefits are derived. Essential constituents in these processabl…
Abstract 2‐Hydroxy‐1.4‐naphthaquinone (HNQ) was selectively synthesized from catalytic oxidation of 2‐naphthol by molecular oxygen over tetra(4‐methoxyl‐phenyl)porphyrinate iron(III) chloride (TMOPPFeCl) catalyst in an alkali methanol solution under mild conditions. The influences of solvents, temperature, time, as we…
The fluorescence of rare-earth ions RE3+ = Pr3+, Er3+ and Tm3+ has been compared in the transition-metal fluoride glass (36 mol% PbF2–24 mol% ZnF2–35 mol% GaF3–5 mol% YF3–2Al mol% F3) doped with either REF3 or RECl3. For the phonon-sensitive radiative transition, the lifetime is prolonged at low RECl3 concentrations b…
The perturbation formulas of the electron paramagnetic resonance (EPR) parameters g ∥ , g ⊥ , A ∥ and A ⊥ for a 4f 3 (Nd 3+ ) ion in tetragonal symmetry are established in this work. In these formulas, the contributions to the EPR parameters arising from the second-order perturbation terms and the admixtures of differ…
An advanced analysis code, ARKAS_cellule, has been developed to determine the core distortion and the mechanical behavior of fast reactors. In this code, each hexagonal subassembly duct is represented by a folded thin plate structure divided into a user-specified number of shell elements so that the interduct contact…