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Discotic liquid crystals of transition metal complexes, 31: establishment of mesomorphism and thermochromism of bis[1,2-bis(4-n-alkoxyphenyl)ethane-1,2-dithiolene]nickel complexes

Hiroko Horie、Akira Takagi、Hiroshi Hasebe 等 5 位作者2001-01-01Journal of Materials Chemistry

Two series of bis[1,2-bis(4-n-alkylphenyl)ethane-1,2-dithiolene]nickel, Cn–Ni (n = 1–12), and bis[1,2-bis(4-n-alkoxyphenyl)ethane-1,2-dithiolene]nickel, CnO–Ni(n = 1–12, 14, 16, 18), have been synthesized. Their mesomorphism, thermochromism, supramolecular structures and π-acceptor property have been investigated by u…

Magnetism in coordination complexesPorphyrin and Phthalocyanine ChemistryPhotochromic and Fluorescence Chemistry

Why stripes? Spontaneous formation of inhomogeneous structures due to elastic interactions

D. I. Khomskiǐ、K. I. Кugel2001-01-01University of Groningen research database (University of Groningen / Centre for Information Technology)

We argue that elastic interactions between ions in different valence states can play an essential role in the stabilization of stripes (or 2D "sheets" ) in doped oxides. These interactions are in general long range and an iso tro pic (attractive in certain directions and repulsive in others). This can naturally give r…

Magnetic and transport properties of perovskites and related materialsAdvanced Condensed Matter PhysicsElectronic and Structural Properties of Oxides

A Study on Surface State during the Pretreatment of Electroless Nickel Plating on Magnesium Alloys

Yanghui Xiang、Wenbin Hu、Xinkuan Liu 等 5 位作者2001-01-01Transactions of the IMF

SUMMARYChanges of the surface state during the pretreatment of electroless nickel plating on magnesium alloys were studied using the weight loss method. scanning electron microscopy (SEM) and X-ray photoelectron spectroscopy (XPS). The results showed that due to the formation of Mg(OH), and MgF,films on the surface. a…

Corrosion Behavior and InhibitionElectrodeposition and Electroless Coatings

Organogel or polymer gel; facilitated gelation of a sugar-based organic gel by the addition of a boronic acid-appended polymer

Hideki Kobayashi、Masato Amaike、Jong Hwa Jung 等 6 位作者2001-01-01Chemical Communications

The combination of boronic acid-appended poly(L-lysine) 1 and sugar-based gelator 2 yields a novel organo-polymer gel, consisting of vesicles held together by polymer molecules.

Glycosylation and Glycoproteins ResearchSupramolecular Self-Assembly in MaterialsPolydiacetylene-based materials and applications

Rapid, energetic metathesis routes to crystalline metastable phases of zirconium and hafnium dioxide

Edward G. Gillan、Richard B. Kaner2001-01-01Journal of Materials Chemistry

Rapid, exothermic metathesis (exchange) reactions between ZrCl4 and Na2O result in crystalline ZrO2 in seconds. Thermal analysis and in situ reaction temperature measurements show that the reaction initiates near the sublimation point of ZrCl4, rapidly reaches temperatures above 1350 °C, and generates a molten NaCl fl…

Advanced ceramic materials synthesisNuclear Materials and PropertiesInorganic Chemistry and Materials

Growth of highly transparent nanocrystalline diamond films and a spectroscopic study of the growth

Li–Chyong Chen、Padmakar Kichambare、Kuei‐Hsien Chen 等 6 位作者2001-01-01Journal of Applied Physics

A series of nanocrystalline diamond films with grain size ranged from 4 nm to a few hundreds of nanometers were grown by microwave plasma enhanced chemical vapor deposition. Effects of the substrate pretreatment and the methane fraction in the source gas on the microstructure, surface roughness, and optical transmitta…

Metal and Thin Film MechanicsDiamond and Carbon-based Materials ResearchAdvanced materials and composites

Plasma lithography — thin-film patterning of polymeric biomaterials by RF plasma polymerization I: Surface preparation and analysis

Andreas Goessl、Michael D. Garrison、Jean-Benoı̂t Lhoest 等 4 位作者2001-01-01Journal of Biomaterials Science Polymer Edition

Plasma lithography, combining plasma deposition with photolithography, is described as a versatile method to manufacture all-polymeric substrates with thin-film patterns for applications in biomedical engineering. Patterns of a hydrophobic fluorocarbon plasma polymer with feature sizes between 5 and 100 microm were de…

Surface Modification and SuperhydrophobicityPolymer Surface Interaction StudiesNanofabrication and Lithography Techniques

Free volume and viscosity of polymer-compressed gas mixtures during extrusion foaming

L. A. Utracki、Robert Simha2001-01-01Journal of Polymer Science Part B Polymer Physics

Extrusion foaming of molten polystyrene (PS) with three physical foaming agents (PFAs), carbon dioxide (CO2), 1,1,1,2-tetrafluoroethane, and 1-chloro-1,1-difluoroethane, is considered. The concentration of injected PFA was W = 0–5 wt % for CO2 and W = 0–15 wt % for the other agents. The aim of this work is to connect…

Phase Equilibria and ThermodynamicsInjection Molding Process and PropertiesPolymer Foaming and Composites

Transmissive liquid crystal cell parameters measurement by spectroscopic ellipsometry

Shu-Tuen Tang、Hoi Sing Kwok2001-01-01Journal of Applied Physics

A powerful method for liquid crystal (LC) cell twist angle and retardation measurement is presented. This method is based on the spectroscopic ellipsometry. By varying the polarizer and analyzer angles only, a transmission spectrum containing null transmission at some particular wavelengths can be obtained. Analytical…

Liquid Crystal Research AdvancementsOptical Polarization and Ellipsometry

Impact fracture behavior of molecularly orientated polycarbonate sheets

Zhiyong Xia、Hung‐Jue Sue、Alex J. Hsieh2001-01-01Journal of Applied Polymer Science

The impact fracture behavior of molecularly orientated polycarbonate (PC) sheets was investigated. The molecular orientation was achieved via a newly developed equal channel angular extrusion (ECAE) process. Improvement in impact fracture propagation resistance was observed in the ECAE processed PC sheets. The improve…

Mechanical Behavior of CompositesPolymer crystallization and propertiesPolymer Nanocomposites and Properties

Cation-induced assembly of the first mixed molybdenum–vanadium hexadecametal host shell cluster anions

Yan Xu、Dunru Zhu、Zijian Guo 等 6 位作者2001-01-01Journal of the Chemical Society Dalton Transactions

Two novel hexadecametal–oxygen cluster compounds, {Ni[(NH2)2(C2H4)2NH]2}3[PMoVI5MoV3VIV8O44]·[(NH2)2(C2H4)2NH]·H2O 1 and {Co[(NH2)2(C2H4)2NH]2}2Na[PMoVI6MoV2VIV8O44]·8H2O 2 are synthesized by a hydrothermal method, and characterized by X-ray crystallography, showing that the anion of 1 has a novel tetra-capping mode,…

Metal-Organic Frameworks: Synthesis and ApplicationsPolyoxometalates: Synthesis and ApplicationsVanadium and Halogenation Chemistry

Electronic Conductivity of ZrO[sub 2]-CeO[sub 2]-YO[sub 1.5] Solid Solutions

Yueping Xiong、Katsuhiko Yamaji、Natsuko Sakai 等 6 位作者2001-01-01Journal of The Electrochemical Society

The temperature and the oxygen partial pressure dependencies of the electronic conductivity of step) solid solutions were measured by dc polarization using a Hebb-Wagner's ion-blocking cell. The main charge carrier was electron for ceria-containing compositions in a whole range of measured oxygen partial pressure to 3…

Advancements in Solid Oxide Fuel CellsCatalysis and Oxidation ReactionsElectronic and Structural Properties of Oxides

Characterisation of the active copper species for the NOx removal on Cu/Mg/Al mixed oxides derived from hydrotalcites: an in situ XPS/XAES study

Fausto Pedro Garcı́a Márquez、A.E. Palomares、Fernando Rey 等 4 位作者2001-01-01Journal of Materials Chemistry

In situ X-ray photoelectron spectroscopy was used to characterise Cu/Mg/Al mixed oxides derived from hydrotalcites (catalyst used for the NOx removal reaction). The active sites are the copper centres: (i) Cu(0) for NO decomposition and (ii) Cu(0) and/or Cu(I) for NO reduction with a hydrocarbon. The ability of these…

Catalytic Processes in Materials ScienceLayered Double Hydroxides Synthesis and ApplicationsMagnesium Oxide Properties and Applications

Memory operations of 1T2C-type ferroelectric memory cell with excellent data retention characteristics

Sung‐Min Yoon、Hiroshi Ishiwara2001-01-01IEEE Transactions on Electron Devices

A novel FET-type ferroelectric memory cell with one-transistor, and two-capacitor (1T2C) structure was fabricated and characterized, in which the generation of depolarization field in ferroelectric film during data retention was suppressed by polarizing two ferroelectric capacitors in opposite directions. It was demon…

Ferroelectric and Piezoelectric MaterialsElectronic and Structural Properties of OxidesFerroelectric and Negative Capacitance Devices

Evaluation of the dielectric parameters from TSDC spectra: application to polymeric systems

Roberto Neagu、Eugen R. Neagu、Ioannis M. Kalogeras 等 4 位作者2001-01-01Materials Research Innovations

The Thermally Stimulated Discharge Current (TSDC) technique is widely used for the study of main and secondary dielectric relaxations in polymers. The TSD current is described by different equations that can be arranged in a unique three-parameters (the activation energy W, A and B) general form. The physical meaning…

Polymer Nanocomposites and PropertiesHigh voltage insulation and dielectric phenomenaDielectric materials and actuators

MICROWAVE-ASSISTED SYNTHESIS OF 5,10,15,20-TETRAARYL PORPHYRINS

S. M. S. Chauhan、Bishwabhusan Sahoo、K. A. Srinivas2001-01-01Synthetic Communications

Clean and eco-friendly microwave-assisted cyclocondensation of different aryl aldehydes with pyrrole forms 5,10,15,20-tetraaryl porphyrins in 20 to 43% yields in very low amount of propionic acid in one step is presented.

Porphyrin and Phthalocyanine ChemistryFluorine in Organic ChemistrySynthesis and Biological Evaluation

Formation of the icosahedral quasicrystalline phase in Zr70Pd30binary glassy alloy

Junji Saida、M. Matsushita、Akihisa Inoue2001-01-01Philosophical Magazine Letters

It is found that a single icosahedral quasicrystalline phase is formed as a primary precipitation phase in the melt-spun Zr70Pd30 binary glassy alloy with a two-stage crystallization process. The onset temperature of the transformation from the amorphous to the icosahedral phase is 701 K at the heating rate of 0.67 K…

Material Dynamics and PropertiesMetallic Glasses and Amorphous AlloysPhase-change materials and chalcogenides

A new heptadentate tripodal ligand leading to a gadolinium complex with an improved relaxation efficiency

Yann Bretonnière、Marinella Mazzanti、Jacques Pécaut 等 5 位作者2001-01-01Chemical Communications

The new heptadentate tripodal ligand tpaa containing three pyridinecarboxylate binding units reacts with Gd(III) in water to give a thermodynamically stable complex which displays high relaxivity.

Advanced MRI Techniques and ApplicationsMagnetism in coordination complexesLanthanide and Transition Metal Complexes

The early stage of the morphology development of immiscible polymer blends during melt blending: Compatibilized vs. uncompatibilized blends

Huxi Li、Guo‐Hua Hu2001-01-01Journal of Polymer Science Part B Polymer Physics

The early stage of the morphology development has been studied for the blending of two immiscible polymers. Controlled experiments were carried out in a batch mixer in such a way that the rate of melting was low enough to follow up the morphology development of dilute and concentrated systems. For a dilute or semidilu…

Polymer crystallization and propertiesPolymer Nanocomposites and Propertiesbiodegradable polymer synthesis and properties

Thermoelectric properties of highly textured (ZnO)5In2O3 ceramics

Toshihiko Tani、Shinya Isobe、Won‐Seon Seo 等 4 位作者2001-01-01Journal of Materials Chemistry

Textured bulk ceramics of the layer-structured homologous compound (ZnO)5In2O3 were fabricated by the reactive templated grain growth (RTGG) technique and the thermoelectric properties evaluated. Plate-like ZnSO4·3Zn(OH)2 particles were mixed with In2O3 powders and the mixture was tape cast to form a sheet, such that…

ZnO doping and propertiesAdvanced Thermoelectric Materials and DevicesPhase Change Materials Research