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Unconventional Hall effect near charge neutrality point in a two-dimensional electron-hole system

O. É. Raichev、G. M. Gusev、E. B. Olshanetsky 等 7 位作者2012-10-26Physical Review B

The transport properties of the two-dimensional system in HgTe-based quantum wells containing simultaneously electrons and holes of low densities are examined. The Hall resistance, as a function of perpendicular magnetic field, reveals an unconventional behavior, different from the classical N-shaped dependence typica…

Graphene research and applicationsQuantum and electron transport phenomenaTopological Materials and Phenomena

Dyeing of cotton with sulfur dyes using alkaline protease

Priyadarshi Jaruhar、J.N. Chakraborty2012-10-26Textile Research Journal

Sulfur dyes are applied on cotton to produce deep shades at low cost; they provide excellent color fastness, except against chlorinating agents. Sodium sulfide used as a reducing and solubilizing agent in this dyeing process is highly toxic and produces unhygienic hydrogen sulfide. In this study, alkaline protease was…

melanin and skin pigmentationDyeing and Modifying Textile FibersTextile materials and evaluations

Porous cobalt oxide nanowires: Notable improved gas sensing performances

Maixia Ma、Zhiyun Pan、Lin Guo 等 6 位作者2012-10-26Chinese Science Bulletin

The porous Co 3 O 4 nanowires have been successfully synthesized via modified template method. A possible growth mechanism governing the formation of such 1D nanowires is proposed. The as-prepared products have been characterized by X-ray Powder Diffraction (XRD), Extended X-ray Absorption Fine-structure (EXAFS), High…

Gas Sensing Nanomaterials and SensorsTransition Metal Oxide NanomaterialsCopper-based nanomaterials and applications

Chlorohydrination of Allyl Chloride to Dichloropropanol in a Microchemical System

Jisong Zhang、Jing Tan、Kai Wang 等 5 位作者2012-10-26Industrial & Engineering Chemistry Research

A microchemical system, including two micromixers and a delay loop, is specially designed to carry out the chlorohydrination of allyl chloride with chlorine in water. Chlorine is dissolved in water in the first micromixer and then reacts with allyl chloride to produce dichloropropanol in the second micromixer. The rea…

Catalytic Processes in Materials ScienceMicrofluidic and Capillary Electrophoresis ApplicationsInnovative Microfluidic and Catalytic Techniques Innovation

Effects of ion exchange and calcinations on the structure and photocatalytic activity of hydrothermally prepared titanate nanotubes

Min Young Kim、Sang‐Hyun Hwang、Sang Kyoo Lim 等 4 位作者2012-10-26Crystal Research and Technology

Abstract Titanate nanotubes (TiNTs) were prepared by alkaline hydrothermal processing. The TiNTs are thermodynamically unstable and easily transformed to the titania phase by heat or acid treatment. These phase transformations are affected by the preparation conditions. In this study, we investigated the effects of us…

TiO2 Photocatalysis and Solar CellsAdvanced Photocatalysis TechniquesCovalent Organic Framework Applications

Insulin solubility transitions by pH ‐dependent interactions with proinsulin C‐peptide

Michael Landreh、Gunvor Alvélius、Hanna Willander 等 7 位作者2012-10-26FEBS Journal

Proinsulin processing into insulin and C-peptide in the secretory granules of the pancreatic β-cells occurs under mildly acidic conditions and at high peptide concentrations (> 10 mm). Mature insulin has reduced solubility and a propensity to adopt an amyloid-like structure, but is physiologically released as a mixtur…

Alzheimer's disease research and treatmentsPancreatic function and diabetesSupramolecular Self-Assembly in Materials

Reliability of $\hbox{SrRuO}_{3}\hbox{/SrTiO}_{3}\hbox{/SrRuO}_{3}$ Stacks for DRAM Applications

S. Kupke、Steve Knebel、Uwe Schroeder 等 6 位作者2012-10-26IEEE Electron Device Letters

A layer stack of strontium ruthenate/strontium titanate/strontium ruthenate was fabricated by low-rate rf sputtering. A high dielectric permittivity of approximately 200 at a capacitive effective thickness of 0.4 nm in combination with a very low leakage current densityJCof 5 × 10-9A/cm2at 833 kV/cm was achieved.JCis…

Semiconductor materials and devicesElectronic and Structural Properties of OxidesFerroelectric and Negative Capacitance Devices

17O-Dynamic NMR and DFT Investigation of Bis(acyloxy)iodoarenes

Luca Fusaro、Francesca Mocci、Michel Luhmer 等 4 位作者2012-10-26Molecules

Bis(acetoxy)iodobenzene and related acyloxy derivatives of hypervalent I(III) were studied by variable temperature solution-state ¹⁷O-NMR and DFT calculations. The ¹⁷O-NMR spectra reveal a dynamic process that interchanges the oxygen atoms of the acyloxy groups. For the first time, coalescence events could be detected…

Porphyrin and Phthalocyanine ChemistryOxidative Organic Chemistry ReactionsMolecular spectroscopy and chirality

Synthesis of a Novel Ruthenium Sensitizer Bearing an ortho-Dicarboxyphenyl Group as an Anchoring Unit for Dye-sensitized Solar Cells

Hironobu Ozawa、Shohei Oura、Ryōsuke Shimizu 等 4 位作者2012-10-26Chemistry Letters

Abstract A novel ruthenium sensitizer TUS-20, which is a structural analog of black dye, bearing an ortho-dicarboxyphenylterpyridine as an anchoring unit to TiO2 surface has been synthesized. Adsorption rate of TUS-20 was much faster, and the maximum amount of dye adsorption was larger than that of black dye. The dye-…

TiO2 Photocatalysis and Solar CellsAdvanced Photocatalysis TechniquesPolyoxometalates: Synthesis and Applications

Stable lithium-ion cathodes from nanocomposites of VO2nanowires and CNTs

Chunzhu Yan、Zheng Chen、Yiting Peng 等 5 位作者2012-10-26Nanotechnology

A VO(2)(B) nanowire/CNT nanocomposite was fabricated with a stable lithium storage performance resulting in an interpenetrating porous network. This material demonstrated an enhanced Li-ion storage capacity with a significantly improved cycling stability. The capacity of the composite faded by only 6% after 100 cycles…

Advancements in Battery MaterialsSupercapacitor Materials and FabricationTransition Metal Oxide Nanomaterials

Photophysical and DFT Characterization of Novel Pt(II)-Coupled 2,5-Diaryloxazoles for Nonlinear Optical Absorption

Tomas Kindahl、Pål Gunnar Ellingsen、Cesar Lopes 等 6 位作者2012-10-26The Journal of Physical Chemistry A

Several new bis-phosphine platinum(II) complexes with 2,5-diaryl-substituted oxazole-containing alkyne ligands have been synthesized and optically characterized in solution. Measurements of nonlinear absorption showed strong attenuation of laser light at 532 and 600 nm. The light absorption of the Pt complexes was shi…

Photochemistry and Electron Transfer StudiesPhotochromic and Fluorescence ChemistryNonlinear Optical Materials Studies

Spontaneous Formation of Heterogeneous Patches on Polymer–Lipid Core–Shell Particle Surfaces during Self‐Assembly

Carolina Salvador-Morales、Pedro M. Valencia、Weiwei Gao 等 5 位作者2012-10-26Small

Spontaneous formation of heterogeneous patches on the surface of lipid-based nanoparticles (NPs) and microparticles (MPs) due to the segregation of two different functional groups. Patch formation is observed when tracing the functional groups with quantum dots, gold nanoparticles, and fluorescent dyes. This discovery…

Gold and Silver Nanoparticles Synthesis and ApplicationsLipid Membrane Structure and BehaviorPickering emulsions and particle stabilization

Esterification of 2-keto-l-gulonic acid catalyzed by a solid heteropoly acid

Thu Ha Thi Vu、Hang Thi Au、Nguyễn Thị Tuyết 等 6 位作者2012-10-26Catalysis Science & Technology

The efficacy of a potassium 12-phosphotungstate (KPW) catalyst in the synthesis of methyl 2-keto-L-gulonat from 2-keto-L-gulonic acid (2-KLGA) and methanol is investigated. The KPW catalyst gives high yields in short reaction times. The present procedure represents a clean, efficient, practical, simple, mild, time-sav…

Mesoporous Materials and CatalysisCarbohydrate Chemistry and SynthesisCatalysis for Biomass Conversion

Alpha‐Helix Self‐Assembly of Oligopeptides Originated From Beta‐Sheet Keratin

Qianjie Zhang、Bernd Michael Liebeck、Kelu Yan 等 6 位作者2012-10-26Macromolecular Chemistry and Physics

Abstract The structure and characterization of the oligopeptide crystals formed from the feather keratin solution obtained by superheated water treatment are reported. The FTIR spectra and 1H and 13C solid‐state NMR results indicate that the peptides, arranged mostly in a beta‐sheet structure in feather, reorganize in…

Dyeing and Modifying Textile FibersSilk-based biomaterials and applicationsFood Chemistry and Fat Analysis

Theoretical Study on Gilbert Damping of Nonuniform Magnetization Precession in Ferromagnetic Metals

Nobuyuki Umetsu、Daisuke Miura、Akimasa Sakuma2012-10-26Journal of the Physical Society of Japan

We study Gilbert damping in bulk metallic ferromagnets containing magnetic and nonmagnetic impurities in the presence of nonuniform magnetization precession. In this model, a microscopic expression for the Gilbert damping tensor is obtained using the linear response theory with respect to the interaction between magne…

Magnetic properties of thin filmsTheoretical and Computational PhysicsMagnetic Properties and Applications

Low-pass frequency selective surface with wideband high-stop response for shipboard radar

Yuan Yang、Hao Zhou、X.-H. Wang 等 4 位作者2012-10-26Journal of Electromagnetic Waves and Applications

In this paper, a compact frequency selective surface (FSS) with low-pass and wideband high-stop response is presented. The FSS is composed of hexagon rings and placed in hexagon arrangement. At low frequencies below 2.0 GHz, the insertion loss is less than 0.9 dB. While in the stopband 8.0–18.0 GHz, the transmission i…

Antenna Design and AnalysisMetamaterials and Metasurfaces ApplicationsAdvanced Antenna and Metasurface Technologies

Semiconductor‐Insulator Transition in Undoped Rutile, TiO 2 , Ceramics

Yang Liu、Anthony R. West2012-10-26Journal of the American Ceramic Society

The electrical conductivity of undoped rutile ceramics is very dependent on sample processing conditions, especially the temperature and atmosphere during sintering and the subsequent cooling rate. Samples become increasingly semiconducting when quenched from temperatures above ~700°C without the need for a reducing a…

TiO2 Photocatalysis and Solar CellsTransition Metal Oxide NanomaterialsDielectric properties of ceramics

Physicochemical characterization andin vivoevaluation of solid self-nanoemulsifying drug delivery system for oral administration of docetaxel

Qi-Zhe Quan、Dong‐Wuk Kim、Nirmal Marasini 等 8 位作者2012-10-26Journal of Microencapsulation

To formulate a self-nanoemulsifying drug delivery system (SNEDDS) for the oral administration of docetaxel as an alternative to commercial docetaxel-loaded injectable products, it was prepared by spray-drying an aqueous solution containing liquid SNEDDS and colloidal silica. Its physicochemical properties and oral bio…

Nanoparticle-Based Drug DeliveryDrug Solubulity and Delivery SystemsMesoporous Materials and Catalysis

Low frequency electromagnetic radiation from sprite streamers

Jianqi Qin、Sébastien Célestin、Victor P. Pasko2012-10-26Geophysical Research Letters

Sprites are mesospheric discharges that carry significant electrical currents and produce electromagnetic radiation observed typically in the extremely low (ELF) to ultra low (ULF) frequency bands. In this letter, we present the first theoretical estimates of the electromagnetic radiation produced by individual sprite…

High voltage insulation and dielectric phenomenaLightning and Electromagnetic PhenomenaElectromagnetic Compatibility and Noise Suppression

Theoretical basis and practical aspects of small specimen creep testing

Thomas H. Hyde、Christopher Hyde、Wei Sun2012-10-26The Journal of Strain Analysis for Engineering Design

Interest in and the application of small specimen creep test techniques are increasing. This is because it is only possible to obtain small samples of material in some situations, for example, the scoop samples that are removed from in-service components, the heat-affected zones that are created when welds are used to…

Fatigue and fracture mechanicsHigh Temperature Alloys and CreepMaterial Properties and Failure Mechanisms