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Surface Structure of Spin-Coated Fluorinated Polymers Films Dominated by Corresponding Film-Formation Solution/Air Interface Structure

Huagang Ni、Xuehua Li、Yanyan Hu 等 9 位作者2012-10-24The Journal of Physical Chemistry C

In this paper, the relationship between the surface structures of spin-coated fluorinated polymer films and their corresponding film-formation solution/air interface structures was investigated. Film-forming poly( n -alkyl methacrylate) end-capped with 2-perfluorooctylethyl methacrylate (FMA; PFMA y -ec-PnAMA x -ec-PF…

Surface Modification and SuperhydrophobicityFluid Dynamics and Thin Filmsnanoparticles nucleation surface interactions

A review on the characteristics of gomuti fibre and its composites with thermoset resins

Adriana Ticoalu、Thiru Aravinthan、Francisco Cardona2012-10-24Journal of Reinforced Plastics and Composites

Gomuti fibre is obtained from Arenga pinnata tree and is known with other names such as sugar-palm fibre, gomutu, ijuk, serat aren and black fibre. This article presents a review on the physical, mechanical, chemical and thermal properties of gomuti fibre in comparison with other common natural fibres. Furthermore, th…

Natural Fiber Reinforced CompositesAgricultural Engineering and MechanizationMechanical Engineering and Vibrations Research

Synthesis and Biological Activity of Organoantimony(III)-Containing Heteropolytungstates

M. Barsukova-Stuckart、L.F. Piedra-Garza、Bimersha Gautam 等 11 位作者2012-10-24Inorganic Chemistry

Three discrete organoantimony(III)-containing heteropolytungstates [(PhSb(III))(4)(A-α-Ge(IV)W(9)O(34))(2)](12-) (1), [(PhSb(III))(4)(A-α-P(V)W(9)O(34))(2)](10-) (2), and [{2-(Me(2)NCH(2)C(6)H(4))Sb(III)}(3)(B-α-As(III)W(9)O(33))](3-) (3) have been synthesized in one-pot reactions in aqueous medium using the appropria…

Metal-Organic Frameworks: Synthesis and ApplicationsPolyoxometalates: Synthesis and ApplicationsVanadium and Halogenation Chemistry

Mechanical properties of polyvinylchloride-coated fabrics processed with Precontraint® technology

Yingying Zhang、Qilin Zhang、Henglin Lv2012-10-24Journal of Reinforced Plastics and Composites

This article presents the mechanical properties of polyvinylchloride-coated fabrics with Precontraint® technology. First, groups of off-axial tests are carried out, and the corresponding strength criteria are discussed. Then, the biaxial tests are carried out on the material without initial loading and the material af…

Mechanical Behavior of CompositesTextile materials and evaluationsStructural Analysis of Composite Materials

Synthesis, molecular structure, and stability of a zirconocene derivative with α-Keggin mono-aluminum-substituted polyoxotungstate

Chika Nozaki Kato、Yuki Makino、Wataru Unno 等 4 位作者2012-10-24Dalton Transactions

The synthesis and crystal structure of a zirconocene derivative with α-Keggin mono-aluminum-substituted polyoxotungstate, [α-PW(11)Al(OH)O(39)ZrCp(2)](2)(6-) (Cp = C(5)H(5)(-)) (1), which was obtained by the reaction of α-Keggin mono-aluminum-substituted polyoxotungstate with a biscyclopentadienylzirconium(IV) complex…

Metal-Organic Frameworks: Synthesis and ApplicationsPolyoxometalates: Synthesis and ApplicationsChemical Synthesis and Reactions

Evolution of Eu 2+ spin dynamics in Ba 1−x Eu x Fe 2 As 2

P. F. S. Rosa、C. Adriano、W. Iwamoto 等 7 位作者2012-10-24Physical Review B

Single crystals of Ba${}_{1\ensuremath{-}x}$Eu${}_{x}$Fe${}_{2}$As${}_{2}$ were studied by magnetic susceptibility, heat capacity, resistivity, and electron spin resonance (ESR) measurements. Spin-density wave (at ${T}_{\text{SDW}}$) and antiferromagnetic (at ${T}_{N}$) phase transitions were mapped as a function of $…

Physics of Superconductivity and MagnetismRare-earth and actinide compoundsIron-based superconductors research

Evolution of the band structure of superconducting NaFeAs from optimally doped to heavily overdoped Co substitution using angle-resolved photoemission spectroscopy

Shengtao Cui、Sanyuan Zhu、A. F. Wang 等 9 位作者2012-10-24Physical Review B

Using angle-resolved photoemission spectroscopy, we studied the evolution of electronic structure of NaFe${}_{1\ensuremath{-}x}$Co${}_{x}$As from an optimally doped superconducting compound ($x=0.028$) to a heavily overdoped nonsuperconducting one ($x=0.109$). As in ``122''-type iron pnictides, our data suggest that t…

Corporate Taxation and AvoidanceIron-based superconductors research

A combined high-field EPR and quantum chemical study on a weakly ferromagnetically coupled dinuclear Mn( iii ) complex. A complete analysis of the EPR spectrum beyond the strong coupling limit

Marius Retegan、Marie‐Noëlle Collomb、Frank Neese 等 4 位作者2012-10-24Physical Chemistry Chemical Physics

The electronic and magnetic properties of polynuclear complexes, in particular the magnetic anisotropy (zero field splitting, ZFS), the leading term of the spin Hamiltonian (SH), are commonly analyzed in a global manner and no attempt is usually made to understand the various contributions to the anisotropy at the ato…

Magnetism in coordination complexesLanthanide and Transition Metal ComplexesElectron Spin Resonance Studies

Control of crystallization in supramolecular soft materials engineering

Jingliang Li、Bing Yuan、Xiangyang Liu 等 5 位作者2012-10-24Soft Matter

As one class of the most important supramolecular functional materials, gels formed by low molecular weight gelators (LMWGs) have many important applications. The key important parameters affecting the in-use performance of a gel are determined by the hierarchical fiber network structures. Fiber networks consisting of…

Hydrogels: synthesis, properties, applicationsLipid Membrane Structure and BehaviorSupramolecular Self-Assembly in Materials

Ferroelectric substrate effects on the magnetism, magnetotransport, and electroresistance of La 0.7 Ca 0.3 MnO 3 thin films on BaTiO 3

A. Alberca、Carmen Munuera、J. Tornos 等 11 位作者2012-10-24Physical Review B

La${}_{0.7}$Ca${}_{0.3}$MnO${}_{3}$ optimally doped epitaxial films were grown on ferroelectric BaTiO${}_{3}$ substrates. Electronic transport (magnetoresistance and electroresistance) and magnetic properties showed important anomalies in the temperature interval between 60 and 150 K, below the metal-insulator transit…

Magnetic and transport properties of perovskites and related materialsMultiferroics and related materialsAdvanced Condensed Matter Physics

A Printed Beam-Shifting Slab Designed Using Tensor Transmission-Line Metamaterials

Gurkan Gok、Anthony Grbic2012-10-24IEEE Transactions on Antennas and Propagation

We present the design and implementation of a beam-shifting slab (a transformation electromagnetics device) using tensor transmission-line metamaterials. A beam-shifting slab is an anisotropic, homogeneous and reflectionless slab which laterally displaces the electromagnetic field transmitted through it. The experimen…

Antenna Design and AnalysisMetamaterials and Metasurfaces ApplicationsAdvanced Antenna and Metasurface Technologies

ALKALI EXTRACTION AND PHYSICOCHEMICAL CHARACTERIZATION OF HEMICELLULOSES FROM YOUNG BAMBOO (PHYLLOSTACHYS PUBESCENS MAZEL)

Qiang Luo、Hong Peng、Mengyang Zhou 等 8 位作者2012-10-24BioResources

Two hemicellulose fractions were obtained by extraction of one-month- old young bamboo (Phyllostachys pubescens Mazel). The fractionation procedure employed 2% NaOH as extractant, followed by filtration, acidification, precipitation, and washing with 70% ethanol solution. The total yield was 26.2%, based on the pentos…

Biofuel production and bioconversionAdvanced Cellulose Research StudiesBamboo properties and applications

Impurity states in multiband s -wave superconductors: Analysis of iron pnictides

Robert Beaird、Ilya Vekhter、Jian‐Xin Zhu2012-10-24Physical Review B

We examine the effect of a single, nonmagnetic impurity in a multiband, extended $s$-wave superconductor allowing for anisotropy of the gaps on the Fermi surfaces. We derive analytic expressions for the Green's functions in the continuum and analyze the conditions for the existence of sharp impurity-induced resonant s…

Iron-based superconductors research

Influence of Cr3+ substitution on the electrical and magnetic properties of Ni0.4Cu0.4Zn0.2Fe2O4 nanoparticles

R.H. Kadam、Asif Karim、A. B. Kadam 等 5 位作者2012-10-24International nano letters.

Abstract The Ni0.4Cu0.2Zn0.4ferrites with different concentrations of Cr3+were synthesized at a low temperature (450°C) using sol–gel auto-combustion method. The X-ray diffraction analysis of the samples confirms the formation of a single-phase cubic spinel structure. The lattice constant decreases from 8.331 to 8.253…

Multiferroics and related materialsMagnetic Properties and Synthesis of FerritesElectromagnetic wave absorption materials

Helium gas barrier and water absorption behavior of bamboo fiber reinforced recycled polypropylene

Hychem Boukehili、Phuong Nguyen‐Tri2012-10-24Journal of Reinforced Plastics and Composites

Helium gas permeability and water absorption behavior of the recycled polypropylene/short bamboo fiber composite membrane were investigated. The effects of short bamboo fiber content and fiber chemical treatment on gas permeability and water absorption properties of composites have been examined. Our research showed t…

Polymer crystallization and propertiesNatural Fiber Reinforced CompositesBamboo properties and applications

Phase Behavior of a Hydrogen-Bonded Polymer with Lamella-to-Cylinder Transition: Complex of Poly(4-vinylpyridine) and Small Dendritic Benzoic Acid Derivative

Shaojie Wang、Yanshuang Xu、Shuang Yang 等 4 位作者2012-10-24Macromolecules

Phase behavior of a supramolecular system based on poly(4-vinylpyridine) (P4VP) and 3,4,5-tris(dodecyloxy)benzoic acid (TDBA) [P4VP(TDBA) x, where x is the molar ratio of TDBA to P4VP repeating unit] was investigated by means of FTIR, differential scanning calorimetry, polarized optical microscopy, and X-ray scatterin…

Liquid Crystal Research AdvancementsAdvanced Polymer Synthesis and CharacterizationSurfactants and Colloidal Systems

Corrole-silica hybrid particles: synthesis and effects on singlet oxygen generation

Joana F. B. Barata、Ana L. Daniel‐da‐Silva、Maria G. P. M. S. Neves 等 5 位作者2012-10-24RSC Advances

The present study describes the first example of hybrid particles composed of amorphous silica and corrole. The hybrid particles were obtained by covalent linking of the gallium(III)(pyridine) complex of 5,10,15-tris(pentafluorophenyl)corrole (GaPFC) at the surface of functionalized silica spheres. The functionalizati…

Porphyrin and Phthalocyanine ChemistryPhotodynamic Therapy Research StudiesPhotochemistry and Electron Transfer Studies

Mixed Crystals in Chiral Organic Systems: A Case Study on (R)- and (S)-Ethanolammonium 3-Chloromandelate

Nikolay Vyacheslavovich Taratin、Heike Lorenz、E. N. Kotelnikova 等 8 位作者2012-10-24Crystal Growth & Design

This work focuses on characterization of chiral organic systems with partial solid solutions. Particularly, behavior of the ( R )- and ( S )-ethanolammonium 3-chloromandelates (E3ClMA) has been investigated experimentally. Partial solid solutions of the series ( R )-E3ClMA–(Rac)-E3ClMA and ( S )-E3ClMA–(Rac)-E3ClMA we…

Crystallography and molecular interactionsAnalytical Chemistry and ChromatographyCrystallization and Solubility Studies

Pressure-induced phase transitions and structure of chemically ordered nanoregions in the lead-free relaxor ferroelectric Na 1/2 Bi 1/2 TiO 3

Melanie Gröting、Igor Kornev、Brahim Dkhil 等 4 位作者2012-10-24Physical Review B

We investigate the phase stability of Na${}_{1/2}$Bi${}_{1/2}$TiO${}_{3}$, a prototype lead-free relaxor material, under pressure. By means of total energy calculations within density functional theory, we study the pressure stability of several structures with polar and antipolar distortions, in-phase and out-of-phas…

Ferroelectric and Piezoelectric MaterialsHigh-pressure geophysics and materialsMultiferroics and related materials

Magnetic nanocomplexes and the physiological challenges associated with their use for cancer imaging and therapy

Eunjung Kim、Kwangyeol Lee、Yong‐Min Huh 等 4 位作者2012-10-24Journal of Materials Chemistry B

Magnetic nanoparticles offer potential advances in cancer treatment. One example is cancer theranostics, which refers to the combination of a diagnostic tool, i.e., magnetic resonance (MR) imaging, and therapeutic entities such as drugs, oligonucleotides, antibodies, and peptides. They can be conjugated with bioactive…

Nanoparticle-Based Drug DeliveryNanoplatforms for cancer theranosticsCharacterization and Applications of Magnetic Nanoparticles