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Computational Design of a Carbon Nanotube Fluorofullerene Biosensor

Tamsyn A. Hilder、Ron J. Pace、Shin‐Ho Chung2012-10-12Sensors

Carbon nanotubes offer exciting opportunities for devising highly-sensitive detectors of specific molecules in biology and the environment. Detection limits as low as 10(-11) M have already been achieved using nanotube-based sensors. We propose the design of a biosensor comprised of functionalized carbon nanotube pore…

Carbon Nanotubes in CompositesMicrofluidic and Capillary Electrophoresis ApplicationsNanopore and Nanochannel Transport Studies

Photocontrolled Phase Transitions and Reflection Behaviors of Smectic Liquid Crystals by a Chiral Azobenzene

Jingjing Guan、Mingzhi Zhang、Birong Li 等 5 位作者2012-10-12ChemPhysChem

The photocontrolled phase transitions and reflection behaviors of a smectic liquid crystal, 4-octyl-4'-cyanobiphenyl (8CB), tuned by a chiral azobenzene, are systematically investigated. For the smectic 8CB doped with the chiral azobenzene (1R)-(-)-4-n-hexyl-4'-menthylazobenzene (ABE), the initial smectic phase can be…

Liquid Crystal Research AdvancementsPhotochromic and Fluorescence ChemistryPhotoreceptor and optogenetics research

Preparation of Finite Particles of Nitrate Forms of Layered Double Hydroxides by pH Adjustment with Anion Exchange Resin

Shota Naito、Konomi Nitoh、A. Ayral 等 4 位作者2012-10-12Industrial & Engineering Chemistry Research

Well-defined finite particles of nitrate forms of layered double hydroxides (MgAl and NiAl types) were successfully synthesized from aqueous solution of metal nitrates by the recently developed pH adjustment method, where hydroxide form ion-exchange resin was used to change a starting acidic solution into basic soluti…

Layered Double Hydroxides Synthesis and ApplicationsInorganic Chemistry and MaterialsMagnesium Oxide Properties and Applications

Isothermal Crystallization Kinetics, Morphology, and Mechanical Properties of Biocomposites Based on Poly(3-hydroxybutyrate-co-4-hydroxybutyrate) and Recycled Carbon Fiber

Hongyan Han、Xiaodong Wang、Dezhen Wu2012-10-12Industrial & Engineering Chemistry Research

The biocomposites of poly(3-hydroxybutyrate- co -4-hydroxybutyrate) [P(3,4HB)] and recycled carbon fiber (RCF) were prepared via a melting extrusion. The crystallization behaviors and kinetics of the P(3,4HB) matrix in composites were exclusively studied under both nonisothermal and isothermal conditions. The correspo…

Polymer crystallization and propertiesbiodegradable polymer synthesis and propertiesFiber-reinforced polymer composites

Theoretical characterization of axial deformation effects on hydrogen storage of Ti decorated armchair (5,5) SWCNT

Ahmad S. Shalabi、A.M. El Mahdy、H.O. Taha2012-10-12Molecular Physics

Theoretical calculations have been performed in the framework of density functional theory to characterize the effect of axial deformation on hydrogen storage of Ti decorated armchair (5,5) SWCNT. The theoretical characterization has been carried out in terms of H2 adsorption energies that are lying in the desirable e…

Hydrogen Storage and MaterialsBoron and Carbon Nanomaterials ResearchMXene and MAX Phase Materials

Design Methodology of Large-Scale Thermoelectric Generation: A Hierarchical Modeling Approach

Min Chen、Junling Gao、Zhengdong Kang 等 4 位作者2012-10-12Journal of Thermal Science and Engineering Applications

A thermoelectric generation system (TEGS) used in the practical industry of waste heat recovery consists of the fluidic heat sources, the external load circuitry, and many thermoelectric modules (TEMs) connected as a battery bank. In this paper, a system-level model is proposed to seamlessly integrate the complete flu…

Advanced Thermoelectric Materials and DevicesInnovative Energy Harvesting TechnologiesThermal Radiation and Cooling Technologies

Engineering Sustainable Construction Material: Hemp-Fiber-Reinforced Composite with Recycled High-Density Polyethylene Matrix

Na Lu、Thomas M. Korman2012-10-12Journal of Architectural Engineering

This paper presents findings from an ongoing research study aimed at increasing the available sustainable construction materials that could possibly be used in the design and construction of civil infrastructure and commercial building projects in the future. At the Sustainable Material and Renewable Technology Labora…

Natural Fiber Reinforced CompositesInnovations in Concrete and Construction MaterialsBamboo properties and applications

Optically pumped lasing from vapor‐grown crystals of methoxy‐substituted thiophene/phenylene co‐oligomer

Hitoshi Mizuno、Hisao Yanagi、Fumio Sasaki 等 4 位作者2012-10-12physica status solidi (a)

Abstract We report on optically pumped lasing from a vapor‐grown crystal of thiophene/phenylene co‐oligomer, 2,5‐bis(4′‐methoxybiphenyl‐4‐yl)thiophene (BP1T‐OMe). By using a pair of parallel facets of a thin sword‐like crystal as a Fabry–Pérot resonator, laser oscillations were obtained in the 0‐2 emission wavelength…

Advanced Fiber Laser TechnologiesLuminescence and Fluorescent MaterialsNonlinear Optical Materials Studies

Impact of surface roughness on the effective dielectric constants and subwavelength image resolution of metal–insulator stack lenses

Shivanand、Alon Ludwig、Kevin J. Webb2012-10-12Optics Letters

The effective parallel and perpendicular dielectric constants for a multilayer metal–insulator stack are obtained from numerical simulations and compared with analytical homogenization results as a function of wavelength and number of periods. The influence of inevitable film surface roughness on the homogenized diele…

Metamaterials and Metasurfaces ApplicationsElectromagnetic Scattering and AnalysisOptical Coatings and Gratings

The Preisach hysteresis model: Error bounds for numerical identification and inversion

Pavel Krejčı́2012-10-12Discrete and Continuous Dynamical Systems - S

A structure analysis of the Preisach model in a variational setting is carried outby means of an auxiliary hyperbolic equation with memory variable playing the role of time,and amplitude of cycles as spatial variable. Using this representation, wepropose an algorithm and derive error estimates for the identification o…

Shape Memory Alloy TransformationsMagnetic Properties and Applications

Determining the strain rate dependence of cortical and cancellous bones of human tibia using a Split Hopkinson pressure bar

Ch. Kranthi Teja、Anoop Chawla、Sudipto Mukherjee2012-10-12International Journal of Crashworthiness

Mechanical properties of tibial bone at compressive strain rates of 50–200/s are obtained through a Split Hopkinson pressure bar. Cylindrical specimens of 12–15 mm diameter and 2–5 mm thickness were prepared. The Young's moduli are calculated from linear portion of stress–strain curves. For both cortical and cancellou…

Orthopedic Surgery and RehabilitationHigh-Velocity Impact and Material BehaviorTraumatic Ocular and Foreign Body Injuries

Enhancing Chemical and Optical Stability of Silver Nanostructures by Low-Temperature Hydrogen Atoms Processing

María Losurdo、Iris Bergmair、Maria M. Giangregorio 等 15 位作者2012-10-12The Journal of Physical Chemistry C

A large variety of applications ranging from plasmonic sensing to plasmonic enhanced solar cells, photonics, and optics can benefit from a reliable method to enhance chemical and time stability of silver-based plasmonic nanostructures and metamaterials. Therefore, here we demonstrate and discuss the effectiveness of a…

Gold and Silver Nanoparticles Synthesis and ApplicationsPlasmonic and Surface Plasmon ResearchCopper-based nanomaterials and applications

Drug distribution in wet granulation: foam versus spray

Melvin X.L. Tan、Thanh H. Nguyen、Karen Hapgood2012-10-12Drug Development and Industrial Pharmacy

Foam granulation technology is a new wet granulation approach for pharmaceutical formulations. This study evaluates the performance of foam and spray granulation in achieving uniform drug distribution using a model formulation. To observe wetting and nuclei formation, single drop/foam penetration experiments were perf…

Drug Solubulity and Delivery SystemsPickering emulsions and particle stabilizationMicroencapsulation and Drying Processes

Synthesis, characterization, and catalytic activity of titanium iminophenoxide complexes in relation to the ring‐opening polymerization of L ‐lactide and ε‐caprolactone

Hsuan‐Ying Chen、Wei‐Yi Lu、Yen‐Jen Chen 等 12 位作者2012-10-12Journal of Polymer Science Part A Polymer Chemistry

Abstract This study synthesized a series of titanium iminophenoxide complexes and investigated their suitability as catalysts for the ring‐opening polymerization of L‐lactide (L‐LA) and ε‐caprolactone (CL). Complexes with bidentate ligands demonstrate higher catalytic activity than their tridentate counterparts since…

Organometallic Complex Synthesis and Catalysisbiodegradable polymer synthesis and propertiesCarbon dioxide utilization in catalysis

Pregnane glycosides interfere with steroidogenic enzymes to down‐regulate corticosteroid production in human adrenocortical H295R cells

Slavko Komarnytsky、Débora Esposito、Alexander Poulev 等 4 位作者2012-10-12Journal of Cellular Physiology

A group of bioactive steroidal glycosides (pregnanes) with anorectic activity in animals was isolated from several genera of milkweeds including Hoodia and Asclepias. In this study, we investigated the effects, structure-activity relationships, and mechanism of action of pregnane glycosides on steroidogenesis in human…

Estrogen and related hormone effectsEndometriosis Research and TreatmentPhytochemistry and Bioactive Compounds

Controlled growth of nickel nanocrystal arrays and their field electron emission performance enhancement via removing adsorbed gas molecules

Jian Wang、Liangming Wei、Liying Zhang 等 7 位作者2012-10-12CrystEngComm

We present the fabrication of Ni nanocone arrays on Ni foil substrate as well as gas exposure field electron emission experiments using them as cold electron cathodes. The self-assembly of nanoscale building blocks into organized conical superstructures is achieved by the assistance of oriented attachment. These Ni na…

Carbon Nanotubes in CompositesMolecular Junctions and NanostructuresNanowire Synthesis and Applications

Synthesis, spectral, and structural characterizations of imidazole oxalato molybdenum( iv / v / vi ) complexes

Quan‐Liang Chen、Hong‐Bin Chen、Zexing Cao 等 4 位作者2012-10-12Dalton Transactions

Substitutions of trans-Na(Him)[Mo(2)O(4)(ox)(2)(H(2)O)(2)]·H(2)O (1) and trans-(Him)(2)[Mo(2)O(4)(ox)(2)(H(2)O)(2)] (2) with imidazole result in the formation of the mixed-ligand molybdenum complexes cis-Na(2)[Mo(2)O(4)(ox)(2)(im)(2)]·4.5H(2)O (3), cis-K(2)[Mo(2)O(4)(ox)(2)(im)(2)]·3H(2)O (4), respectively (H(2)ox = o…

Metal-Organic Frameworks: Synthesis and ApplicationsMagnetism in coordination complexesPolyoxometalates: Synthesis and Applications

Particle Replication in Non-wetting Templates: a Platform for Engineering Shape- and Size-specific Janus Particles

Joseph M. DeSimone、Jie‐Yu Wang、Yapei Wang2012-10-12Royal Society of Chemistry eBooks

Because of their unique anisotropic characteristics, Janus particles have been assessed as attractive building blocks for self-assembly with desirable supramolecular architectures, leading to the creation of novel functional materials.1–5 Janus particles with tunable chemistry and physical propertie...

Advanced Polymer Synthesis and CharacterizationSurfactants and Colloidal SystemsPickering emulsions and particle stabilization

Influence of Solvation and the Persistence of Adsorbed Linkers on the Attachment of CdSe Quantum Dots to TiO2 via Linker-Assisted Assembly

Meghan E. Kern、David F. Watson2012-10-12Langmuir

CdSe quantum dots (QDs) were attached to the surfaces of nanocrystalline TiO(2) films functionalized with 16-mercaptohexadecanoic acid (MHDA). The solvent from which MHDA was adsorbed to TiO(2) determined the amount of adsorbed MHDA, the extent of ordering within monolayers, and the lability of MHDA-TiO(2) interaction…

Quantum Dots Synthesis And PropertiesChalcogenide Semiconductor Thin FilmsPolymer Surface Interaction Studies

LiNa5Mo9O30

Hamadi Hamza、Ines Ennajeh、Mohamed Faouzi Zid 等 4 位作者2012-10-12Acta Crystallographica Section E Structure Reports Online

The tite compound, lithium penta-sodium nona-molybdate, LiNa(5)Mo(9)O(30), was synthesized by solid-state reaction. The three-dimensional [Mo(9)O(30)](6-) framework is built up from MoO(6) octa-hedra and MoO(5) bipyramids, linked together by edges and corners. The framework delimits two types of inter-secting tunnels…

Metal-Organic Frameworks: Synthesis and ApplicationsPolyoxometalates: Synthesis and ApplicationsChemical Synthesis and Characterization