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ChemInform Abstract: Experimental and Computational Study of a New Wheel‐Shaped {[W5O21]3 [(UVIO2)2(μ‐O2)] 3}30‐ Polyoxometalate.

Pere Miró、Jie Ling、Jie Qiu 等 6 位作者2012-10-11ChemInform

Abstract Na6Li24{[W5O21]3 [(UO2)2(O2)]3} is synthesized by slow evaporation of an aqueous solution containing UO2(NO3)2, H3PW12O40, H2O2, LiOH, and NaOH (initial pH 8.8, 8% yield).

Radioactive element chemistry and processingMetal-Organic Frameworks: Synthesis and ApplicationsPolyoxometalates: Synthesis and Applications

ChemInform Abstract: Minimisation of E‐Factor in the Synthesis of N‐Hydroxylamines: The Role of Silver(I)‐Based Coordination Polymers.

Mehdi Sheykhan、Zohreh Rashidi Ranjbar、Ali Morsali 等 4 位作者2012-10-11ChemInform

Abstract Nano‐rods of silver complexed N,N′‐bis(4‐pyridyl formamide)‐1,4‐benzene bearing different anions are synthesized and applied as highly efficient catalysts in the partial oxidation of primary amines (I) and (III) with urea hydrogen peroxide to afford the corresponding hydroxylamines (II) and (IV).

Polyoxometalates: Synthesis and ApplicationsChemical Synthesis and ReactionsMetal-Organic Frameworks: Synthesis and Applications

ChemInform Abstract: Modular Three‐Component Organocatalytic Synthesis of 3,4‐Disubstituted Pyrroles by a One‐Pot Domino Reaction.

Cecilia Martín‐Santos、Carlos Jarava‐Barrera、Alejandro Parra 等 6 位作者2012-10-11ChemInform

Abstract A new organocatalytic synthesis of 3,4‐disubstituted pyrroles is presented, involving the one‐pot, two‐step reaction of aldehydes, e.g. (I), with gem‐bromonitroalkenes, e.g. (II), and amines, e.g. (III).

Synthesis and Characterization of PyrrolesPorphyrin and Phthalocyanine ChemistryAsymmetric Synthesis and Catalysis

ChemInform Abstract: Fragmenting Gadolinium: Mononuclear Polyoxometalate‐Based Magnetic Coolers for Ultra‐Low Temperatures.

María‐José Martínez‐Pérez、Oscar Montero、Marco Evangelisti 等 7 位作者2012-10-11ChemInform

Abstract Compounds (III) and (V), which both have a single Gd3+ ion per molecular unit are characterized by magnetic measurements down to 2 K and heat capacity measurements down to 0.35 K.

Crystal Structures and PropertiesCatalysis and Oxidation ReactionsMagnetic and transport properties of perovskites and related materials

ChemInform Abstract: Spiropyrans and Spirooxazines. Part 8. 5′‐(1,3‐Benzothiazol‐2‐yl)‐Substituted Spiro[indoline‐2,3′‐naphthopyrans]: Synthesis and Spectral and Photochromic Properties.

Н. А. Волошин、Anatoly V. Chernyshev、А. В. Метелица 等 5 位作者2012-10-11ChemInform

Abstract Novel photochromic spiropyrans (I) (7 examples) possessing luminescence properties in both cyclic and merocyanine form are synthesized and characterized.

Photochromic and Fluorescence ChemistrySynthesis of Indole DerivativesPhotoreceptor and optogenetics research

ChemInform Abstract: Ultrasonic‐Assisted Surfactant‐Free Synthesis of Highly Magnetized FeCo Alloy Nanocrystallite from Ferric and Cobalt Salt.

Xian‐Wen Wei、Konglin Wu、Guoxing Zhu 等 9 位作者2012-10-11ChemInform

Abstract Crystalline Fe64Co36 (44% yield), Fe59Co41 (80% yield), and Fe37Co63 (86% yield) nanoparticles with diameters of 5—12 nm are synthesized by addition of N2H4 and NaOH to aqueous solutions of CoCl2 and FeCl3 with various Fe3+:Co2+ ratios at room temperature (Ar, ultrasonication, 343 K, 3 h).

Magnetic properties of thin filmsMagnetic Properties and Synthesis of FerritesMetallic Glasses and Amorphous Alloys

ChemInform Abstract: 4H‐Dithieno[2,3‐b:3′,2′‐e][1,4]thiazines — Synthesis and Electronic Properties of a Novel Class of Electron‐Rich Redox Systems.

Catherine Dostert、Claudia Wanstrath、Walter Frank 等 4 位作者2012-10-11ChemInform

Abstract In the case where electron‐poor aromatic amines are used the yield can be increased by dielectric heating at 160 °C.

Organic Chemistry Cycloaddition ReactionsPorphyrin and Phthalocyanine ChemistryPhotochemistry and Electron Transfer Studies

ChemInform Abstract: Mesoporous Three‐Dimensional Network of Crystalline WO3 Nanowires for Gas Sensing Application.

Yuxiang Qin、Fei Wang、Wanjiang Shen 等 4 位作者2012-10-11ChemInform

Abstract A three‐dimensional network of crystalline WO3 nanowires is prepared by impregnation of a three‐dimensional SBA‐15 silica template with a solution of silicotungstic acid in EtOH for 6 h at room temperature followed by mineralization (300 °C for 1 h in air and 600 °C for 4 h in air) and template removal (HF so…

Transition Metal Oxide NanomaterialsGas Sensing Nanomaterials and SensorsAnalytical Chemistry and Sensors

ChemInform Abstract: A Liquid—Liquid Biphasic Homogeneous Organocatalytic Aldol Protocol Based on the Use of a Silica Gel Bound Multilayered Ionic Liquid Phase.

Elisa Montroni、Marco Lombardo、Arianna Quintavalla 等 6 位作者2012-10-11ChemInform

Abstract Key feature of the title protocol is the use of a cis‐ion‐tagged proline dissolved in a liquid film on a multilayered ionic liquid covalently bound to silica. The resulting catalytically active material is soaked in cyclohexanone and water to form a semi‐transparent gel which then reacts with the aldehyde.

Mesoporous Materials and CatalysisSurfactants and Colloidal SystemsIonic liquids properties and applications