Materials Literature
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This paper reports a dimethyl sulfoxide (DMSO) phase offered by a coordination polymer gel that consists of metal ions and a calixarene that has multiple binding sites. This metallogel, virtually 98% of which is DMSO, has high stability in aqueous solution over a wide range of pH (1−13), even at 100 °C, rejects ions (…
Ageing of insulation materials and systems may well be detected by quantitative measurements of their dielectric response. Such measurements can be performed in the frequency or time domain. In this contribution, a novel type of equipment based on relaxation current measurements is introduced which is designed for on-…
A very important aspect in chip design in flip chip technology is the heat dissipation. As the surfaces of the heat sink, the heat spreader and the chip are rough there are imperfect contacts leading to higher thermal resistance due to the contact resistance. A method to decrease this contact resistance is by the use…
Liquid crystals: main types and classification distribution functions and order parameters physical properties of liquid crystals nematic liquid crystals nematic liquid crystals - elastostatics and nematodynamics smectic liquid crystals liquid crystals of disc-like molecules polymer liquid crystals chiral liquid cryst…
We investigated near-infrared-to-blue upconversion from thulium (Tm3+) doped in tellurite glasses upon continuous wave excitation near 800 nm. We observed an enhancement of over two orders of magnitude of the upconverted emission at ∼480 nm when neodymium (Nd3+) ions were codoped with Tm3+ ions. For comparison, using…
This paper provides a review of thermoelectric cooling and its application to the cooling of electronic equipment. A background discussion of thermoelectric cooling is provided briefly citing early history, current developments, and the defining thermoelectric heat pumping equations. Several examples are provided of e…
Ultrathin 2-nm-thick carbon coatings are needed to increase the storage density in magnetic hard disks. We show how x-ray reflectivity, surface Brillouin scattering, resonant Raman scattering, and electron energy loss spectroscopy can measure consistently the structural and mechanical properties of these thin films. 2…
Piezoelectric constant and temperature vs dielectric constant measurements have been performed on the 〈001〉 and 〈011〉 oriented Pb(Mg1/3Nb2/3)O3–PbTiO3 crystals in the rhombohedral phase with compositions near the morphotropic phase boundary under different poling fields. The investigations have revealed that the diele…
A new technology is developed and demonstrated that couples anaerobic digestion of food scraps with production of biodegradable thermoplastics, polyhydroxyalkanoates (PHAs). The food wastes were digested in an anaerobic reactor producing four major organic acids. The concentrations of acetic, propionic, butyric, and l…
An electrical model for a Peltier cell, based on the analogy between thermal and electrical variables, is proposed. The use of thermal models allows the global performance of thermocooling circuit and signal system to be checked by using electrical circuit analysis programs such as SPICE. The maximum error in the stea…
A series of nonanuclear lanthanide oxo-hydroxo complexes of the general formula [Ln(9)(mu(4)-O)(2)(mu(3)-OH)(8)(mu-BA)(8)(BA)(8)](-)[HN(CH(2)CH(3))(3)](+).(CH(3)OH)(2)(CHCl(3)) (BA = benzoylacetone; Ln = Sm, 1; Eu, 2; Gd, 3; Dy, 4; Er, 5) were prepared by the reaction of hydrous lanthanide trichlorides with benzoylace…
The measurements of hardness and elastic modulus have been conducted on the (0001) and (101̄1) faces of B4.3C single crystals using nanoindentation. The results are in good agreement with the corresponding values obtained using a conventional microhardness technique on polycrystalline ceramics. Raman microspectroscopy…
Zinc oxide (ZnO) is a wide-band gap semiconductor that has attracted tremendous interest for optical, electronic, and mechanical applications. First-principles calculations by [C. G. Van de Walle, Phys. Rev. Lett. 85, 1012 (2000)] have predicted that hydrogen impurities in ZnO are shallow donors. In order to determine…
A class of multiferroic, three-phase particulate composites of Tb–Dy–Fe alloy, lead–zirconate–titanate (PZT), and polymer are investigated, in which a small volume fraction f of Tb–Dy–Fe alloy particles are dispersed in a PZT/polymer mixture. The measured dielectric, piezoelectric, and magnetoelectric properties demon…
The low temperature behavior of Pr$_{1-x}$Ca$_{x}$MnO$_{3}$ manganites are known to undergo a transition at $x\sim$0.3, from an insulating ferromagnetic state, at low Ca concentration, to an insulating antiferromagnetic state. Above the onset concentration for the charge-ordering effect ($x\sim 0.3$), a metal-insulato…
In this work we perform an ab-initio study of CdTiO3 perovskite in its orthorhombic phase using FLAPW method. Our calculations help to decide between the different cristallographic structures proposed for this perovskite from X-Ray measurements. We compute the electric field gradient tensor (EFG) at Cd site and obtain…
We have explored in situ synthesis of noble metal nanoparticles in ultrathin TiO 2 −gel films, in view of the increasing importance of such nanoparticle-containing thin films. The two-step procedure consists of ion exchange in the ultrathin matrix and subsequent reduction of metal ions to nanoparticles by low-temperat…
S-doped ZnO (ZnO:S) film was fabricated by supplying ZnS species from laser ablation of a ZnS target during ZnO growth. Variations of lattice constants and band gaps with respect to S content did not follow Vegard’s law. The ZnO:S film showed semiconducting behavior with lower activation energy and resistivity than th…
Dissipative particle dynamics (DPD) is a mesoscopic simulation method for studying hydrodynamic behavior of complex fluids. Ideally, a mesoscopic model should correctly represent the thermo- and hydrodynamic properties of a real system beyond certain length and time scales. Traditionally defined DPD quite successfully…
Block copolymer micelles have shown high potential as hydrophobic drug carriers. The loading efficiency, partition coefficient, and release profile all play critical roles in micellar drug delivery. As part of a series of studies on these polycaprolactone- block -poly(ethylene oxide) (PCL - b -PEO) micelles in drug de…