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Valence-band offset of epitaxial ZnO∕MgO (111) heterojunction determined by x-ray photoelectron spectroscopy

Yongfeng Li、Bin Yao、You Lü 等 11 位作者2008-05-12Applied Physics Letters

The valence-band offset of ZnO∕MgO (111) heterojunction has been directly measured by x-ray photoelectron spectroscopy. Excluding the strain effect, the valence-band offset is determined to be 0.87±0.20eV, and the conduction-band offset ΔEC is deduced to be −3.59±0.20eV, indicating that ZnO∕MgO heterojunction has a ty…

ZnO doping and propertiesCopper-based nanomaterials and applicationsGa2O3 and related materials

Chitosan phosphate: A new way for production of eco-friendly flame-retardant cotton textiles

Khaled El‐Tahlawy2008-05-12Journal of the Textile Institute

An increase in the health and environment legislation awareness pushed the textile manufacturers to develop their strategies to produce eco-friendly flame-retardant textiles with competitive cost. Chitosan is added during the phosphorylation process as a nitrogen source that has synergistic effect with phosphorus. Inc…

Nanocomposite Films for Food PackagingFlame retardant materials and propertiesDyeing and Modifying Textile Fibers

Magnetic control of negative permeability metamaterials based on liquid crystals

Fuli Zhang、Qian Zhao、Lei Kang 等 7 位作者2008-05-12Applied Physics Letters

We report on the tunability, by a magnetic field, of a negative permeability metamaterial consisting of stacked arrays of broadside-coupled split ring resonators infiltrated with liquid crystals (LCs). The resonant frequency shift was numerically assessed by a rigorous anisotropic analysis of the reorientation of LC m…

Metamaterials and Metasurfaces ApplicationsLiquid Crystal Research AdvancementsAdvanced Antenna and Metasurface Technologies

Heterogeneous catalysis: Enigmas, illusions, challenges, realities, and emergent strategies of design

John Meurig Thomas2008-05-12The Journal of Chemical Physics

Predominantly this article deals with the question of how to design new solid catalysts for a variety of industrial and laboratory-orientated purposes. A generally applicable strategy, illustrated by numerous examples, is made possible based on the use of nanoporous materials on to the (high-area) inner surfaces of wh…

Electrocatalysts for Energy ConversionCatalytic Processes in Materials ScienceCatalysis and Hydrodesulfurization Studies

Observation of spin-glass behavior in antiperovskite Mn3GaN

Bo Song、Jikang Jian、Huiqiang Bao 等 8 位作者2008-05-12Applied Physics Letters

The dc magnetization, ac susceptibility, and isothermal remanent magnetization measurements are carried out for antiperovskite Mn3GaN. Strong indication for a frozen state with freeing temperature of Tf at ∼133K is found, determined from the difference between field-cooled and zero-field-cooled magnetizations. The ac…

Ferroelectric and Piezoelectric MaterialsAdvanced Battery Materials and TechnologiesThermal Expansion and Ionic Conductivity

Temperature acceleration of structural relaxation in amorphous Ge2Sb2Te5

Daniele Ielmini、Simone Lavizzari、D. K. Sharma 等 4 位作者2008-05-12Applied Physics Letters

The structural relaxation (SR) process in an amorphous chalcogenide material (Ge2Sb2Te5) is studied by electrical measurements on phase-change memory devices. SR induces a change in the conduction regime from Poole to Poole–Frenkel transport, evidencing a temperature accelerated defect-annihilation process. Based on a…

Liquid Crystal Research AdvancementsPhase-change materials and chalcogenidesNonlinear Optical Materials Studies

Surface modification of nanoporous alumina membranes by plasma polymerization

Dušan Lošić、Martin Cole、Björn Christian Dollmann 等 5 位作者2008-05-12Nanotechnology

The deposition of plasma polymer coatings onto porous alumina (PA) membranes was investigated with the aim of adjusting the surface chemistry and the pore size of the membranes. PA membranes from commercial sources with a range of pore diameters (20, 100 and 200 nm) were used and modified by plasma polymerization usin…

Surface Modification and SuperhydrophobicityPolymer Surface Interaction StudiesAnodic Oxide Films and Nanostructures

Flame retardancy study on magnesium hydroxide associated with clays of different morphology in polypropylene matrix

B. B. Marosfői、S. Garas、Brigitta Bodzay 等 5 位作者2008-05-12Polymers for Advanced Technologies

Abstract Fire retardancy behavior of polypropylene–magnesium hydroxide–clay composites of different morphologies is presented. Layer‐ and needle‐like clay nanoparticles in natural and organically surface modified form have been compared. Fire retardant performance of the composites was evaluated by conical combustor a…

Polymer Nanocomposites and PropertiesFlame retardant materials and propertiesMagnesium Oxide Properties and Applications

Macrophage physiological function after superparamagnetic iron oxide labeling

Jong‐Kai Hsiao、Hunghao Chu、YH Wang 等 8 位作者2008-05-12NMR in Biomedicine

Our goal was to analyze the changes in morphology and physiological function (phagocytosis, migratory capabilities, humoral and cellular response, and nitric oxide secretion) of murine macrophages after labeling with a clinically used superparamagnetic iron oxide (SPIO), ferucarbotran. In SPIO-treated macrophages, nan…

Nanoparticle-Based Drug DeliveryNeonatal Respiratory Health ResearchInhalation and Respiratory Drug Delivery

A molecular view of heterogeneous catalysis

Claus H. Christensen、Jens K. Nørskov2008-05-12The Journal of Chemical Physics

The establishment of a molecular view of heterogeneous catalysis has been hampered for a number of reasons. There are, however, recent developments, which show that we are now on the way towards reaching a molecular-scale picture of the way solids work as catalysts. By a combination of new theoretical methods, detaile…

Electrocatalysts for Energy ConversionCatalytic Processes in Materials ScienceSurface Chemistry and Catalysis

A Possible Ground State and Its Electronic Structure of a Mother Material (LaOFeAs) of New Superconductors

Shoji Ishibashi、Kiyoyuki Terakura、Hideo Hosono2008-05-12Journal of the Physical Society of Japan

The electronic and magnetic properties of the mother material LaOFeAs of new superconductors have been carefully studied using first-principles electronic structure calculations based on the generalized gradient approximation in the density functional theory. The present calculation predicts that the ground state of L…

Rare-earth and actinide compoundsIron-based superconductors researchInorganic Chemistry and Materials

Giant magnetocaloric effect in the Ising antiferromagnet DySb

Weijin Hu、Juan Du、B. Li 等 5 位作者2008-05-12Applied Physics Letters

The magnetic phase transitions and the magnetocaloric effect in the Ising antiferromagnet DySb have been studied. A field-induced sign change of the magnetocaloric effect has been observed which is related to a first-order field-induced metamagnetic transition from the antiferromagnetic to the ferromagnetic states at/…

Magnetic and transport properties of perovskites and related materialsAdvanced Condensed Matter Physics

Thermal conductivity reduction in oxygen-deficient strontium titanates

Choongho Yu、Matthew L. Scullin、Mark Huijben 等 5 位作者2008-05-12Applied Physics Letters

We report significant thermal conductivity reduction in oxygen-deficient lanthanum-doped strontium titanate (Sr1−xLaxTiO3−δ) films as compared to unreduced strontium titanates. Our experimental results suggest that the oxygen vacancies could have played an important role in the reduction. This could be due to the natu…

Ferroelectric and Piezoelectric MaterialsAdvanced Thermoelectric Materials and DevicesElectronic and Structural Properties of Oxides

Electric field control of the magnetic state in BiFeO3 single crystals

Seoungsu Lee、William Ratcliff、S-W. Cheong 等 4 位作者2008-05-12Applied Physics Letters

Single crystals of multiferroic BiFeO3 were investigated using neutron scattering. Application of an electric field reversibly switches ferroelastic domains, inducing changes in the magnetic structure which follows rotation of the structural domains. In addition, electric fields can be used to control the populations…

Ferroelectric and Piezoelectric MaterialsMultiferroics and related materialsUnderwater Acoustics Research

Enhancement of charge and energy storage in sol-gel derived pure and La-modified PbZrO3 thin films

Jayanta Parui、S. B. Krupanidhi2008-05-12Applied Physics Letters

Antiferroelectric lanthanum-modified PbZrO3 thin films with La contents between 0 and 6at.% have been deposited on Pt(111)∕Ti∕SiO2∕Si substrate by sol-gel route. On the extent of La-modification, maximum polarization (Pmax) and recoverable energy density (W) have been enhanced followed by their subsequent reduction. A…

Ferroelectric and Piezoelectric MaterialsMultiferroics and related materialsDielectric materials and actuators

Exchange coupled perpendicular media

D. Suess、J. Lee、J. Fidler 等 4 位作者2008-05-12arXiv

The potential of exchange spring bilayers and graded media is reviewed. An analytical model for the optimization of graded media gives an optimal value of the magnetic polarization of Js = 0.8 T. The optimum design allows for thermally stable grains with grain diameters in the order of 3.3 nm, which supports ultra hig…

Materials Science

Quantum transitions of the XY model with long-range interactions on the inhomogenous periodic chain

J. P. de Lima、L. L. Goncalves2008-05-12arXiv

The isotropic XY model $(s=1/2)$ in a transverse field, with uniform long-range interactions among the transverse components of the spins, on the inhomogeneous periodic chain, is studied. The model, composed of $N$ segments with $n$ different exchange interactions and magnetic moments, is exactly solved by introducing…

Materials Sciencecond-mat.stat-mech

Novel strain-induced low dimensional confinement structures

Nadir Sekkal、V. R. Velasco2008-05-12arXiv

We propose new confinement structures similar to heterostructures and superlattices. The new heteostructures can be obtained by applying strain to a single material in a periodic or aperiodic way. The conversion of an indirect gap into an optical active direct or quasi-direct gap problem has also been investigated tog…

Materials Science

Modification of the electronic structure in a carbon nanotube with the charge dopant encapsulation

Woon Ih Choi、Jisoon Ihm、Gunn Kim2008-05-12Applied Physics Letters

We present the first-principles study of effects of the charge dopants such as cesium and iodine encapsulated on the electronic structure of carbon nanotubes (CNTs). An encapsulated cesium atom donates an electron to the nanotube and produces donorlike states below the conduction bands. In contrast, an iodine trimer (…

Carbon Nanotubes in CompositesGraphene research and applicationsBoron and Carbon Nanomaterials Research