Materials Literature
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We discuss here the use of a graphene monolayer to realize the concept of "cloaking by a surface", proposing the thinnest possible mantle cloak with operation in the far-infrared and terahertz (THz) regime. We show that an atomically thin graphene monolayer may drastically suppress the scattering of planar and cylindr…
Through the use of photoelectron spectroscopy in air (PESA), we investigate the size-dependent valence and conduction band-edge energies of CdSe, CdTe, PbS, and PbSe semiconductor quantum dots (QDs). The results are compared to those of previous studies, based on differing experimental methods, and to theoretical calc…
Abstract A series of aliphatic waterborne polyurethane (WPU) dispersions with high ionic concentration were synthesized by prepolymer mixing. The resultant structure–property relationships were investigated. It was revealed that there was a new microphase besides the phase separation between the soft and the hard doma…
Block junctions are the topological constraints of connecting two homopolymers of different species to form diblock copolymers, which make the phase transition behaviors of diblock copolymers deviate from that of parallel polymer blends. We performed dynamic Monte Carlo simulations of these two parallel polymeric syst…
A nonwetting slug placed at the end of a capillary tube is unstable: a small displacement results in the complete extraction of the liquid from the tube. We study two limiting cases, corresponding to a slug viscosity larger or smaller than that of the surrounding liquid. By varying parameters such as the drop and tube…
The Bacillus subtilis acyl lipid desaturase (Δ5-Des) is an iron-dependent integral membrane protein able to selectively introduce double bonds into long-chain fatty acids. In the last decade since its discovery, the molecular mechanism of Δ5-Des expression has been studied extensively. However, the mechanism of desatu…
A study of Polymer Modified Wood Dust Nanocomposite (PMW) was done using a polymer matrix of poly (vinyl alcohol) (PVA) and Modified Wood Dust as reinforcing agent. Composite materials were prepared by effectively dispersing the wood dust within the PVA matrix via a conventional solvent casting technique. The obtained…
Gallium–magnesium (Ga–Mg) core–shell nanoparticles were synthesized by sequential evaporation of gallium and magnesium molecular beams on sapphire substrates. The surface plasmon resonance properties of this novel bimetallic system are demonstrated and investigated in a broad spectral range, from the near-UV to the vi…
Helicobacter pylori is the major etiologic agent of such gastric disorders as chronic active gastritis and gastric carcinoma. Over the past few years, the appearance of antibiotic-resistant bacteria has led to the development of better treatments, such as the use of natural products. This study evaluated the anti-H. p…
A better understanding of the role that nanoscale surface chemical heterogeneities and topographical features play in water droplet formation is necessary to improve design and robustness of nanostructured superhydrophobic surfaces as to make them fit for industrial applications. Lack of an imaging method capable of c…
INTRODUCTION: Nanoscale assemblies are needed that achieve multiple therapeutic objectives, including cellular targeting, imaging, diagnostics and drug delivery. These must exhibit high stability, bioavailability and biocompatibility, while maintaining or enhancing the inherent activity of the therapeutic cargo. Lipos…
The protein resistance of poly(N-isopropylacrylamide) brushes grafted from silicon wafers was investigated as a function of the chain molecular weight, grafting density, and temperature. Above the lower critical solution temperature (LCST) of 32 °C, the collapse of the water-swollen chains, determined by ellipsometry,…
We calculate the magnetostatic energy of synthetic ferrimagnet (SyF) elements, consisting of two thin ferromagnetic layers coupled antiferromagnetically through RKKY coupling. We calculate exact formulas as well as approximate yet accurate ones, which can be used to easily derive energy barriers and anisotropy fields…
Measurements of intrinsic conductivity and X-ray induced conductivity were performed on specially undopped ZnSe samples. The measurements demonstrated that sensors made of ZnSe have minor intrinsic conductivity when heating up to the temperature of 180 °C, and significant X-ray induced conductivity. Dose dependence "d…
Nanomaterials are an active area of research but also an economic sector in full expansion which addresses many applications domains. For instance, french production for the most common nanomaterials (such as silica, titanium dioxide, carbon black) is in the hundreds of thousands of tons. As for any innovation, one mu…
Hydrophobic inorganic films were obtained by direct deposition of copper or silicon onto natural lotus leaves by ion beam sputtering deposition technique. Scanning electron microscopy observations showed a lotus-leaf-like surface structure of the deposited inorganic films. Hydrophobic nature of the inorganic films on…
SUMMARY Although the ultra‐high‐frequency (UHF) method of detecting partial discharge (PD) in gas insulation substations (GISs) is an interesting research topic because of its remarkable anti‐jamming ability, applying inner UHF sensors to detect PD in operational GISs is a difficult task. The structure of GISs and the…
Abstract In a solution state, an oligophenylene prepared by electrochemical oxidation of para ‐methoxy‐toluene exhibited luminescence in the violet‐to‐blue region. However, in a solid state, a clear red shift was observed as a signature of a supramolecular π‐stacking interaction between oligomer chains. In a de‐doped…
A new series of dendronized metalloporphyrin-fullerene conjugates as photosynthetic reaction center mimics was developed in a highly regioselective fashion through tether-controlled synthesis. The microenvironment around the porphyrin core is dependent on the spatial substitution pattern and the nature and generation…
Abstract Properties characteristic of the size, shape, and orientation as well as the rigidity of PMMA end‐grafted to an amorphous silica surface are calculated by use of fully atomistic molecular dynamics simulations with MMA as explicit solvent. Both the number of grafted chains and their tacticity is varied. Firstl…