Materials Literature
按标题、摘要、年份、主题和来源检索公开元数据。结果保留作者、摘要、分类与原始来源链接。
The synthesis and anion binding properties of a new family of fluorescent halogen bonding (XB) macrocyclic halo-imidazolium receptors are described. The receptors contain chloro-, bromo-, and iodo-imidazolium motifs incorporated into a cyclic structure using naphthalene spacer groups. The large size of the iodine atom…
The controlled placement of gold nanoparticles (AuNPs) in poly(styrene- b -isoprene- b -styrene) [SIS] triblock copolymer thin films was achieved by tuning the surface chemistry of the AuNPs. Facile thiol ligand exchanges permitted quick and thorough exploration of the surface chemistry effects on AuNP segregation beh…
The thermal decomposition reactions of CH 3 CH 2 C(CH 3 ) 2 COOAg (1) , (CH 3 ) 3 SiCH 2 COOAg ( 2 ), CF 3 COOAg ( 3 ), (CH 3 ) 3 CCOOAg ( 4 ), C 2 H 5 COOAg ( 5 ), C 3 F 7 COOAg ( 6 ), C 6 F 13 COOAg ( 7 ) and (CF 2 ) 3 (COOAg) 2 ( 8 ) were studied in N 2 atmosphere using thermogravimetry (TG), derivative thermogravi…
We demonstrate a unique capability in partially oxidizing the oligoaniline shell on gold nanoparticles to polyaniline. Because of the solubility difference, the unreacted inner shell section can be selectively dissolved by 2-propanol, giving yolk-shell nanostructures and, thus, making it possible for assessing the oxi…
CuxO-TiO2 (x = 1, 2) nanomaterials are synthesized on polycrystalline Ti substrates by a convenient chemical vapor deposition (CVD) approach, based on the initial growth of a CuxO matrix (at 400 and 550 °C for x = 1 and 2, respectively) and the subsequent overdispersion of TiO2 at 400 °C. All CVD processes are carried…
We investigated the structural stability of colloidal PbS nanocrystals (NCs) self-assembled into superlattice (SL) allotropes of either face-centered cubic (fcc) or body-centered cubic (bcc) symmetry. Small-angle X-ray scattering analysis showed that the NC packing density is higher in the bcc than in the fcc SL; this…
Lisinopril was used as the targeting moiety to prepare gold nanoparticle-based functional CT contrast agents. Pure lisinopril, thioctic acid-lisinopril conjugate, and reduced thioctic acid-lisinopril conjugate were used to obtain GNP-Lis, GNP-TA-Lis, and GNP-RTA-Lis, respectively, via ligand exchange reaction on citra…
The growth of large and uniform graphene layers remains very challenging to this day due to the close correlation between the electronic and transport properties and the layer morphology. Here, we report the synthesis of uniform large-scale mono- and bilayers of graphene on off-axis 6H-SiC(0001) substrates. The origin…
Abstract The hygroscopic properties of thermally modified wood have been studied in terms of adsorption and desorption processes. Poplar (Populus spp.) and European beech (Fagus sylvatica L.) were in focus. The obtained isotherms were parameterized with the models of Hailwood-Horrobin, Guggenheim-Anderson-deBoer, gene…
The obligate predator Bdellovibrio bacteriovorus HD100 shows a large set of proteases and other hydrolases as part of its hydrolytic arsenal needed for its predatory life cycle. We present genetic and biochemical evidence that open reading frame (ORF) Bd3709 of B. bacteriovorus HD100 encodes a novel medium-chain-lengt…
Traditional metal SERS-active substrate (Ag or Au) and novel semiconductor SERS-active substrate (TiO 2 ) are combined into the composite system for their synergetic contribution to SERS. A series of assemblies with 4-mercaptobenzoic acid (4-MBA) molecule, TiO 2, and/or Ag (Au) nanoparticles (NPs) have been fabricated…
Recently, entropic descriptors based the Monte Carlo hybrid reconstruction of the microstructure of a binary/greyscale pattern has been proposed (Piasecki 2011 Proc. R. Soc. A 467 806). We try to speed up this method applied in this instance to the reconstruction of a binary labyrinth target. Instead of a random confi…
The idea of generating electricity from ambient heat has significant meanings for both science and engineering. Here, we present an interesting idea of using pencil leads, which are made of graphite and clay, to generate electricity from the thermal motion of ions in aqueous electrolyte solution at room temperature. W…
We compare two approaches to compute a portion of the spectrum of dense symmetric definite generalized eigenproblems: one is based on the reduction to tridiagonal form, and the other on the Krylov-subspace iteration. Two large-scale applications, arising in molecular dynamics and material science, are employed to inve…
Voltage-driven spin transfer torque in a magnetic tunnel junction comprising magnetic insulating electrodes is studied theoretically. In contrast with the conventional magnetic tunnel junctions comprising transition metal ferromagnets, the spin transfer torque presents unconventional bias dependencies, related to the…
A unique ability of semiconductor nanocrystals (NCs) is the generation and accommodation of multiple excitons through either optical or electric current pumping. The development and improvement of NC-based optoelectronic devices that utilize multiple excitons requires the understanding of multiple exciton dynamics and…
Nanoparticles (NPs) are characterized by their small size (less than 100 nm) and large surface area, which confer specific physicochemical properties as strength, electrical, and optical features. NPs can be derived from natural or anthropic sources, such as engineered or unwanted/incidental NPs. The composition, dime…
NiO/Co 3 O 4 composite nanosheets have been synthesized via a facile method at low temperature for the first time. The as prepared materials were characterized by X-ray powder diffraction (XRD) and transmission electron microscopy (TEM), and the performance of Li-ion batteries (LIBs) as anode materials were also studi…
We theoretically investigate a widely-used plasmonic structure composed of a nano-slit aperture surrounded by surface corrugations. A systematical semi-analytical theory in form of two nested coupled-mode models is developed to provide intuitive physical pictures. Based on the theory, figures of merit (FoMs) of the st…
AIMS: Impaction grafting restores bone defects in hip arthroplasty. Defects are reconstructed with bone particles (BoP) as substitute materials with adequate mechanical and biological properties are not yet available. Ceramic particles (CeP) have mechanical drawbacks as opposed to porous titanium particles (TiP). In t…