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Random matrices and quantum chaos in weakly disordered graphene nanoflakes

Adam Rycerz2012-06-13Physical Review B

Statistical distribution of energy levels for Dirac fermions confined in a quantum dot is studied numerically on the examples of triangular and hexagonal graphene flakes with random electrostatic potential landscape. When increasing the disorder strength, level distribution evolves from Poissonian to Wigner, indicatin…

Graphene research and applicationsQuantum and electron transport phenomenaQuantum optics and atomic interactions

Synthesis of Hyperbranched Poly(phenylacetylene)s Containing Pendant Alkyne Groups by One-Pot Pd-Catalyzed Copolymerization of Phenylacetylene with Diynes

Zhongmin Dong、Zhibin Ye2012-06-13Macromolecules

We report in this article the convenient synthesis of a class of hyperbranched poly(phenylacetylene)s (HBPPAs) containing various branching densities and different contents of pendant alkyne groups through one-pot chain-growth copolymerization of phenylacetylene (PA) with a diyne comonomer (1,3- or 1,4-diethynylbenzen…

Advanced Polymer Synthesis and CharacterizationSynthetic Organic Chemistry MethodsDendrimers and Hyperbranched Polymers

Preliminary Evaluation of a 99mTc Labeled Hybrid Nanoparticle Bearing a Cobalt Ferrite Core: In Vivo Biodistribution

Dimitrios Psimadas、Giovanni Baldi、Costanza Ravagli 等 8 位作者2012-06-13Journal of Biomedical Nanotechnology

Magnetic nanoparticles have become important tools for imaging a wide range of diseases, improving drug delivery and applying hyperthermic treatment. Iron oxide based nanoparticles have been widely examined, unlike cobalt ferrite based ones. Herein, monodisperse and stable CoFe2O4 nanoparticles have been produced, coa…

Protein Structure and DynamicsNanoparticle-Based Drug DeliveryIron Metabolism and Disorders

Magnetoelectric effects in single crystals of the cubic ferrimagnetic helimagnet Cu 2 OSeO 3

M. Belesi、Ioannis Rousochatzakis、M. Abid 等 6 位作者2012-06-13Physical Review B

We present magnetodielectric measurements in single crystals of the cubic spin-1/2 compound Cu${}_{2}$OSeO${}_{3}$. A magnetic-field-induced electric polarization ($\mathbf{P}$) and a finite magnetocapacitance (MC) is observed at the onset of the magnetically ordered state (${T}_{c}=59$ K). Both $\mathbf{P}$ and MC ar…

Magnetic and transport properties of perovskites and related materialsMultiferroics and related materialsAdvanced Condensed Matter Physics

Hydrophobic Collapse of a Stearic Acid Film by Adsorbed l -Phenylalanine at the Air–Water Interface

Elizabeth C. Griffith、Ellen M. Adams、Heather C. Allen 等 4 位作者2012-06-13The Journal of Physical Chemistry B

The surface morphology of atmospheric aerosol particles can influence the particle's overall effect on climate through enhancing or impeding its ability to uptake and evaporate water. In the work presented here, complementary surface-sensitive information from π-A isotherms, Brewster angle microscopy (BAM), and infrar…

Atmospheric chemistry and aerosolsSurface Modification and SuperhydrophobicityOil Spill Detection and Mitigation

Production and properties of electrosprayed sericin nanopowder

Najmeh Hazeri、Hossein Tavanai、Ali Reza Moradi2012-06-13Science and Technology of Advanced Materials

Sericin is a proteinous substrate that envelops fibroin (silk) fiber, and its recovery provides significant economical and social benefits. Sericin is an antibacterial agent that resists oxidation and absorbs moisture and UV light. In powder form, sericin has a wide range of applications in food, cosmetics and drug de…

Surface Modification and SuperhydrophobicityElectrospun Nanofibers in Biomedical ApplicationsSilk-based biomaterials and applications

Herbicide-Intercalated Zinc Layered Hydroxide Nanohybrid for a Dual-Guest Controlled Release Formulation

Mohd Zobir Hussein、Nor Shazlirah Shazlyn Abdul Rahman、Siti Halimah Sarijo 等 4 位作者2012-06-13International Journal of Molecular Sciences

Herbicides, namely 4-(2,4-dichlorophenoxy) butyrate (DPBA) and 2-(3-chlorophenoxy) propionate (CPPA), were intercalated simultaneously into the interlayers of zinc layered hydroxide (ZLH) by direct reaction of zinc oxide with both anions under aqueous environment to form a new nanohybrid containing both herbicides lab…

Mesoporous Materials and CatalysisLayered Double Hydroxides Synthesis and ApplicationsPolymer-Based Agricultural Enhancements

Viscoelastic Properties of Water Suspensions of Polymer Nanofibers Synthesized via RAFT-Mediated Emulsion Polymerization

Wenjing Zhang、Bernadette Charleux、Philippe Cassagnau2012-06-13Macromolecules

We report on the rheological properties of water suspensions of poly(methacrylic acid - co - poly(ethylene oxide) methyl ether methacrylate) - b - polystyrene and poly(methacrylic acid - co - poly(ethylene oxide) methyl ether methacrylate) - b - poly(methyl methacrylate) self-assembled amphiphilic block copolymer nano…

Advanced Sensor and Energy Harvesting MaterialsPolymer Nanocomposites and PropertiesDielectric materials and actuators

Porous Polysaccharide‐Based Scaffolds for Human Endothelial Progenitor Cells

Mélanie Lavergne、M. Derkaoui、Catherine Delmau 等 6 位作者2012-06-13Macromolecular Bioscience

Human ECFCs contribute to vascular repair. For this reason, they are considered as valuable cell therapy products in ischemic diseases. Porous scaffolds are prepared that are composed of natural polysaccharides, pullulan and dextran, by chemical crosslinking without use of organic solvents. These porous scaffolds, whi…

Angiogenesis and VEGF in CancerElectrospun Nanofibers in Biomedical ApplicationsTissue Engineering and Regenerative Medicine

Multilayers at Interfaces of an Oppositely Charged Polyelectrolyte/Surfactant System Resulting from the Transport of Bulk Aggregates under Gravity

Richard A. Campbell、Marianna Yanez Arteta、Anna Angus-Smyth 等 5 位作者2012-06-13The Journal of Physical Chemistry B

We show conclusively that multilayers at interfaces of an oppositely charged polyelectrolyte/surfactant system can result from the transport under gravity of bulk aggregates with internal molecular structure. This process was demonstrated by measurements of poly(diallyldimethylammonium chloride)/sodium dodecyl sulfate…

Surfactants and Colloidal SystemsPolymer Surface Interaction StudiesElectrostatics and Colloid Interactions

Novel Copper (Cu) Loaded Core–Shell Silica Nanoparticles with Improved Cu Bioavailability: Synthesis, Characterization and Study of Antibacterial Properties

Pavithra Maniprasad、Swadeshmukul Santra2012-06-13Journal of Biomedical Nanotechnology

We report synthesis of a novel core-shell silica based antimicrobial nanoparticles where the silica shell has been engineered to accommodate copper (Cu). Synthesis of the core-shell Cu-silica nanoparticle (C-S CuSiO2NP) involves preparation of base-hydrolyzed Stöber silica "seed" particles first, followed by the acid-…

Nanoparticles: synthesis and applicationsGold and Silver Nanoparticles Synthesis and ApplicationsAdvanced Drug Delivery Systems

High Thermoelectric Performance of Nanostructured In 2 O 3 ‐Based Ceramics

Jinle Lan、Yuanhua Lin、Yong Liu 等 5 位作者2012-06-13Journal of the American Ceramic Society

Nanostructured Zn and Ce co‐doped In 2 O 3 ‐based ceramics were fabricated using co‐precipitation and Spark plasma sintering. It is shown that the nanograins in Zn and Ce co‐doped In 2 O 3 ‐based ceramics can lead to 50% reduction in the thermal conductivity of the sample with a 50 nm grain size and meanwhile keep goo…

Advanced Thermoelectric Materials and DevicesGas Sensing Nanomaterials and SensorsThermal Radiation and Cooling Technologies

Surface Functionalization of Hydrophobic Nanocrystals with One Particle per Micelle for Bioapplications

Mingliang Deng、Nina Tu、Feng Bai 等 4 位作者2012-06-13Chemistry of Materials

A facile and general strategy was successfully developed for the surface modification of kinds of hydrophobic inorganic nanomaterials with various chemical compositions, shapes, and sizes. Via this ultrasonication assistant encapsulation technology, these hydrophobic inorganic nanocrystals were successfully encapsulat…

Quantum Dots Synthesis And PropertiesNanoplatforms for cancer theranosticsNanocluster Synthesis and Applications

On How Surfactant Depletion during Foam Generation Influences Foam Properties

Julia Boos、Wiebke Drenckhan、Cosima Stubenrauch2012-06-13Langmuir

Although it is known that foaming a surfactant solution results in a depletion of the surfactant in the bulk phase, this effect is often overlooked and has never been quantified. Therefore, the influence of surfactant depletion on foam properties using solutions of the two nonionic surfactants, n-dodecyl-β-D-maltoside…

Enhanced Oil Recovery TechniquesSurfactants and Colloidal SystemsPickering emulsions and particle stabilization

Dynamic Interactive Membranes with Pressure‐Driven Tunable Porosity and Self‐Healing Ability

Prashant Tyagi、André Deratani、Denis Bouyer 等 10 位作者2012-06-13Angewandte Chemie International Edition

When pressure is applied to dynamic interactive membranes consisting of micelles composed of a triblock copolymer, their morphologies can be fine-tuned. Membranes with a range of porosities are accessible which can regulate and thereby control filtration performance and also display effective autonomous healing.

Advanced Sensor and Energy Harvesting MaterialsAdvanced Polymer Synthesis and CharacterizationPolymer composites and self-healing

Effective lattice stabilization of gadolinium aluminate garnet (GdAG) via Lu3+doping and development of highly efficient (Gd,Lu)AG:Eu3+red phosphors

Jinkai Li、Ji‐Guang Li、Ji-Guang Li 等 10 位作者2012-06-13Science and Technology of Advanced Materials

The metastable garnet lattice of Gd3Al5O12 is stabilized by doping with smaller Lu3+, which then allows an effective incorporation of larger Eu3+ activators. The [(Gd1−xLux)1−yEuy]3Al5O12 (x = 0.1–0.5, y = 0.01–0.09) garnet solid solutions, calcined from their precursors synthesized via carbonate coprecipitation, exhi…

Luminescence Properties of Advanced MaterialsRadiation Detection and Scintillator TechnologiesLanthanide and Transition Metal Complexes

Surface Interactions Affect the Toxicity of Engineered Metal Oxide Nanoparticles toward Paramecium

Kungang Li、Ying Chen、Ying Chen 等 8 位作者2012-06-13Chemical Research in Toxicology

To better understand the potential impacts of engineered metal oxide nanoparticles (NPs) in the ecosystem, we investigated the acute toxicity of seven different types of engineered metal oxide NPs against Paramecium multimicronucleatum, a ciliated protozoan, using the 48 h LC(50) (lethal concentration, 50%) test. Our…

Nanoparticles: synthesis and applicationsMercury impact and mitigation studiesAdvanced Nanomaterials in Catalysis

Potential of Gold Nanoparticles for Oxidation in Fine Chemical Synthesis

Tamás Mallát、Alfons Baiker2012-06-13Annual Review of Chemical and Biomolecular Engineering

In recent years supported gold nanoparticles have emerged as efficient catalysts with considerable synthetic potential for liquid-phase oxidation reactions based on molecular oxygen as oxidant. Here we critically review the most attractive applications related to the selective oxidation of functional groups containing…

Catalytic Processes in Materials ScienceOxidative Organic Chemistry ReactionsNanomaterials for catalytic reactions

Substrate effects on the thermal conductivity of epitaxial graphene nanoribbons

Zhi‐Xin Guo、Jianwen Ding、Xin-Gao Gong2012-06-13Physical Review B

We study the effect of SiC substrate on thermal conductivity of epitaxial graphene nanoribbons (GNRs) using the nonequilibrium molecular dynamics method. We show that the substrate has strong interaction with single-layer GNRs during the thermal transport, which largely reduces the thermal conductivity. The high therm…

Carbon Nanotubes in CompositesGraphene research and applicationsThermal properties of materials

Strain Paint: Noncontact Strain Measurement Using Single-Walled Carbon Nanotube Composite Coatings

Paul Withey、Venkata S. M. Vemuru、Sergei M. Bachilo 等 5 位作者2012-06-13Nano Letters

Composite coatings have been developed that reveal strains in underlying structural elements through noncontact optical measurement. Dilute individualized single-walled carbon nanotubes are embedded in a polymeric host and applied to form a thin coating. Strain in the substrate is transmitted through the polymer to th…

Carbon Nanotubes in CompositesForce Microscopy Techniques and ApplicationsMechanical and Optical Resonators