Materials Literature
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The steady propagation of an air finger into a fluid-filled tube of uniform rectangular cross-section is investigated. This paper is primarily focused on the influence of the aspect ratio, α, on the flow properties, but the effects of a transverse gravitational field are also considered. The three-dimensional interfac…
Energy dispersive X-ray diffraction and X-ray absorption spectra of two CoFe Prussian blue analogues were collected under variable pressure at room temperature: one of them is essentially composed of Co II and Fe III ions and undergoes a Co II −Fe III → Co III −Fe II pressure-induced electron transfer, whereas the oth…
Abstract In step‐growth polymerizations, the molar concentration of reactive linear species (oligomers and polymers) decreases with higher conversions and finally reaches zero at 100% conversion. This self‐dilution favors cyclization at the expense of chain‐growth. Cyclization reduces the average lengths of the linear…
The use of short chain block copolymer melts as nanostructured templates with sub-10 nm domains is often limited by their low segregation strength (χ N ). Since increasing molar mass to strengthen segregation also increases the interdomain spacing of block copolymer melts, it is more desirable to increase the Flory−Hu…
We study the infrared conductivity of graphene at finite chemical potential and temperature taking into account the effect of phonons and disorder due to charged impurities and unitary scatterers, that is, considering all possible single-particle scattering mechanisms. The screening of the long-range Coulomb potential…
A remarkably bent diiron(III) mu-oxobisporphyrin containing a highly flexible ethane linker is reported that authenticates, for the first time, the unprecedented ability of this platform to "open" and "close" its binding pockets, leading to facile syn-anti conformational switching with very high vertical flexibility o…
In contrast to LLA, DLA is converted in toluene solution under mild reaction conditions (50-70 degrees C) using Novozyme 435 (immobilized CALB) to form the corresponding polymer. The influence of several parameters, such as enzyme concentration, temperature and monomer concentration, on the polymerization rate and the…
In this work, we provide theoretical evidence on the existence of energetically stable chiral structures for bare gold clusters. Density functional theory calculations within the generalized-gradient approximation were performed to systematically study structural, vibrational, electronic, and optical properties of the…
A comprehensive first-principles theoretical study of the electronic properties and half-metallic nature of finite zigzag carbon nanotubes is presented. Unlike previous reports, we find that all nanotubes studied present a spin-polarized ground state, where opposite spins are localized at the two zigzag edges in a lon…
Abstract Poly(glycidyl methacrylate) (PGMA) was synthesized by the RAFT method in the presence of 2‐cyanoprop‐2‐yl dithiobenzoate (CPDB) chain transfer agent using different [GMA]/[CPDB] molar ratios. The living radical polymerization resulted in controlled molecular weights and narrow polydispersity indices ( PDI ) o…
No place like kagome: A quaternary amphiphile displays a novel complex liquid-crystalline phase formed by a periodic array combining triangular and hexagonal cylinders, filled with hydrocarbon and fluorinated chains, respectively. This leads to a fluid nanoscale multicompartment structure with kagome geometry. The thi…
The synthesis and evaluation of new dopamine-based catechol anchors coupled to poly(ethylene glycol) (PEG) for surface modification of TiO(2) are reported. Dopamine is modified by dimethylamine-methylene (7) or trimethylammonium-methylene (8) groups, and the preparation of mPEG-Glu didopamine polymer 11 is presented.…
A many-body Green's function approach to the microscopic theory of surface-enhanced Raman scattering is presented. Interaction effects between a general molecular system and a spatially anisotropic metal particle supporting plasmon excitations in the presence of an external radiation field are systematically included…
We report the electric conductivity of three-dimensional (3D) nanoporous gold at low temperatures and in strong magnetic fields. It was found that topologically disordered 3D nanoporosity leads to extremely low magnetoresistance and anomalous temperature dependence as the characteristic length of nanoporous gold is tu…
We present a new method to synthesize ZnO nanorods on zinc spheres to form a core–shell structure. Selective self-assembly growth of a shell with ZnO nanorods on a metallic Zn microsphere core has been accomplished via hydrothermal synthesis. The crystal structure, morphologies and chemical composition were characteri…
A Monte Carlo tool is presented for the simulation of secondary electron (SE) emission in a scanning electron microscope (SEM). The tool is based on the Geant4 platform of CERN. The modularity of this platform makes it comparatively easy to add and test individual physical models. Our aim has been to develop a flexibl…
Pick your polymer: The reactivity ratios, r, of the comonomers can be controlled by the configuration of the active species in the copolymerization of ε-caprolactone (CL) and l,l-lactide (LA; see scheme). Thus, by varying the configuration of the initiator, a broad spectrum of copolymers with different microstructures…
Zweikernige Dysprosium(III)-Einzelmolekülmagnete, deren Magnetisierungsrelaxation auf thermischem Weg oder durch Quantentunneln erfolgen kann, wurden synthetisiert. Hohe Energiebarrieren bis 71 K wurden beobachtet, insbesondere für ein polymeres Komplexnetzwerk, das die größte Energielücke aller Lanthanoidkomplexe und…
Part 1 Introduction: Hydrogen storage technologies Hydrogen futures: Emerging technologies for hydrogen storage and transport Hydrogen containment materials Solid-state hydrogen storage system design. Part 2 Analysing hydrogen interactions: Structural characterisation of hydride materials Neutron scattering techniques…
Global worming: A periodically ordered mesoporous gel demonstrates photoregulated peristaltic motion induced by a nonlinear oscillating Belousov–Zhabotinsky reaction. The amplitude and period of the motion can be controlled by adjusting the intensity of visible light irradiation (see picture). Peristaltic motion of th…