Materials Literature
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In this work, conducting polymers poly(3,4-ethylenedioxythiophene) (PEDOT), polyaniline (PANi), and polypyrrole (PPy) were directly coated on the surface of reduced graphene oxide (RGO) sheets via an in situ polymerization process to prepare conducting-polymer-RGO nanocomposites with different loadings of the conducti…
Platinum (Pt) is an outstanding catalyst for many important industrial products. Because of its high cost and scarce reserves, it is very important to improve the performance of Pt catalysts. As the metal nanocrystals (NCs) with high-index surfaces usually show very good catalytic activity because of their high densit…
A facile, green strategy is explored to synthesize mesoporous Au/Li(4)Ti(5)O(12) spheres based on in situ conversion of titanium glycolate in LiOH aqueous solution. Compared with TiO(2) precursors, titanium glycolate possesses some strengths: (i) fast and easy preparation; (ii) direct reaction with LiOH without introd…
Semiconducting nanowires have unique properties that are distinct from their bulk counterparts, but realization of their full potential will be ultimately dictated by the ability to control nanowire structure, composition, and size with high accuracy. Here, we report a simple, yet versatile, approach to modulate in si…
Fundamental insights into the molecular mechanisms that determine the breathing behavior of the jungle-gym-type DMOF-1 metal-organic framework upon adsorption of benzene and isopropyl alcohol are gained from computer simulations. In all cases, good agreement is obtained between the calculated and experimental structur…
Self-assembly of melem C(6)N(7)(NH(2))(3) in hot aqueous solution leads to the formation of hydrogen-bonded, hexagonal rosettes of melem units surrounding infinite channels with a diameter of 8.9 Å. The channels are filled with strongly disordered water molecules, which are bound to the melem network through hydrogen…
Conventional thin film batteries are fabricated based on planar current collector designs where the high contact resistance between the current collector and electrodes impedes overall battery performance. Hence, current collectors based on 3D architectures and nanoscale roughness has been proposed to dramatically inc…
Osteophilic modular nanostructured multilayers containing hydroxyapatite nanoparticles complexed with a natural polymer chitosan create an osteoconductive surface for mesenchymal stem cells (MSCs). Coupled with the sustained release of physiological amounts of osteoinductive bone morphogenetic protein over several day…
A temperature-dependent photoluminescent thin film of Al(0.94)Ga(0.06)N doped with Er(3+) is used to measure the temperature of lithographically prepared gold nanodots. The gold nanodots and thin film are excited simultaneously with a continuous wave (CW) Nd:YAG 532 nm laser. The gold nanodot is submersed under water,…
Exploring exciting and exotic physics, scientists are pursuing practical device applications for topological insulators. The Dirac-like surface states in topological insulators are protected by the time-reversal symmetry, which naturally forbids backscattering events during the carrier transport process, and therefore…
In this paper, a theoretical analysis of an axial magnetic coupling is presented, leading to new closed-form expressions for the magnetic axial force and torque. These expressions are obtained by using a 2-D approximation of the magnetic coupling geometry (mean radius model). The analytical method is based on the solu…
Dye sensitized solar cells (DSSCs) have received a tremendous amount of attention since the first report of a 7% efficient cell in 1991. Confirmed record efficiencies are now 11.2% for small cells and 9.9% for submodules, and low-cost production methods are enabling manufacturing of DSSC products for a variety of mark…
Recently, copper (Cu) in its metallic form has regained interest for its antimicrobial properties. Use of metallic Cu surfaces in worldwide hospital trials resulted in remarkable reductions in surface contaminations. Yet, our understanding of why microbes are killed upon contact to the metal is still limited and diffe…
Ring-opening copolymerization of cyclohexene oxide with alicyclic anhydrides containing different ring strain (succinic anhydride, cyclopropane-1,2-dicarboxylic acid anhydride, and phthalic anhydride) was performed applying metal salen chloride complexes, (salen)MCl (M = Al, Cr, Co; salen = N,N -bis(3,5-di- tert -buty…
Furfural was prepared in high yields (75 %) from the reaction of xylose in a water-tetrahydrofuran biphasic medium containing AlCl(3)·6H2O and NaCl under microwave heating at 140 °C. The reaction profile revealed the formation of xylulose as an intermediate en route to the dehydration product (furfural). The reaction…
High-quality anatase TiO2 nanocages with anisotropic shapes, homogeneous shells and tunable sizes can be fabricated by templating against Cu2O polyhedra under hydrothermal conditions. The interiors of these TiO2 nanocages can be functionalized easily with Au nanoparticles. The promising use of these TiO2 nanocages as…
Structure and magnetic proprieties of ball-milled Sm(Fe,Mo) 12 compounds were carried out under an Ar atmosphere. Milled powders were subsequently annealed at a temperature ranging from 700°C up to 1200°C. The effects of heat treatment, on structure and magnetic property changes, have been investigated by means of x-r…
The influence of Na doping upon orbital and charge ordering in Nd 0.5 Sr 0.5 MnO 3 manganites has been investigated combining magnetic measurements with X-ray powder diffraction at room temperature. It is shown that Na doping induces or reinforces the ferromagnetic metallic state, and destroys the charge ordering one…
The title compound, strontium diarseniate Sr 2 As 2 O 7 , was prepared by solid-state method. This compound crystallizes in the tetragonal system, space group P4 1 with a = 7.142 (5) Å; c = 25.693 (5) Å and Z = 8. Its structure is composed of SrO 7–9 polyhedra and [As 2 O 7 ] bitetrahedral units. These groups are link…
Sm0.88Dy0.12Fe2 rod composites were fabricated under a compaction pressure of 800 MPa along the rod direction and in a magnetic field of 200 kA/m along the direction, perpendicular to the rod axis. It is found that the magnetostriction λ|| parallel to the rod direction is almost unchanged with increasing the compressi…