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Effect of Pressure on Activation–Deactivation Equilibrium Constants for ATRP of Methyl Methacrylate

Joachim Morick、Michael Buback、Krzysztof Matyjaszewski2012-09-17Macromolecular Chemistry and Physics

Abstract Atom transfer radical polymerization (ATRP) rate for methyl methacrylate (MMA) in acetonitrile solution has been measured up to 2500 bar. The increase in rate, by up to two orders of magnitude for the CuBr/Me6TREN system, is not compromised by an increase in dispersity. Activation–deactivation equilibrium con…

Polymer crystallization and propertiesAdvanced Polymer Synthesis and CharacterizationFuel Cells and Related Materials

Scale effects in convoluted thermal/spatial statistics of plasticity initiation in small stressed volumes during nanoindentation

T. L. Li、Hongbin Bei、James R. Morris 等 5 位作者2012-09-17Materials Science and Technology

The elastic–plastic transition of crystals at small length scales can be quantitatively evaluated by sudden discontinuities (pop-ins) on nanoindentation load–displacement curves. For defect free crystals under nanocontacts, pop-in stress fluctuations result purely from the thermally activated process of homogeneous di…

Microstructure and mechanical propertiesMetal and Thin Film MechanicsIntermetallics and Advanced Alloy Properties

Efficient broadband energy transfer via momentum matching at hybrid junctions of guided-waves

Charles Lin、Herman M. K. Wong、Benedict Lau 等 5 位作者2012-09-17Applied Physics Letters

Momentum matching at hybrid junctions is examined for efficient broadband energy transfer between internal reflection guided waves and evanescence-based plasmonic-gap guided waves. We demonstrate a nanoscale orthogonal junction coupler between 50 nm air-filled plasmonic slot waveguides (PSWs) and 450 nm silicon rib wa…

Plasmonic and Surface Plasmon ResearchPhotonic and Optical DevicesOptical Coatings and Gratings

Effect of Mg interlayer on perpendicular magnetic anisotropy of CoFeB films in MgO/Mg/CoFeB/Ta structure

Q. L.、Satoshi Iihama、Takahide Kubota 等 7 位作者2012-09-17Applied Physics Letters

The effects of Mg metallic interlayer on the magnetic properties of thin CoFeB films in MgO/Mg (tMg)/CoFeB (1.2 nm)/Ta structures were studied in this letter. Our experimental result shows that the CoFeB film exhibits perpendicular magnetic anisotropy (PMA) when the CoFeB and MgO layers are separated by a metallic Mg…

Magnetic properties of thin filmsMagnetic Properties and ApplicationsMagnetic Properties of Alloys

Anomalous Swelling Behavior of Poly(N-vinylimidazole)-l-Poly(tetrahydrofuran) Amphiphilic Conetwork in Water Studied by Solid-State NMR and Positron Annihilation Lifetime Spectroscopy

Attila Domján、Csaba Fodor、Szabolcs Kovács 等 6 位作者2012-09-17Macromolecules

Poly( N -vinylimidazole) homopolymer (PVIm) and poly( N -vinylimidazole)- l -poly(tetrahydrofuran) (PVIm- l -PTHF), a novel amphiphilic polymer conetwork (APCN), were synthesized to compare their solid state structure and investigate the swelling behavior of this unique conetwork in water. A short-range ordered struct…

Dielectric materials and actuatorsSynthesis and properties of polymersMuon and positron interactions and applications

Donor–Acceptor Semiconducting Polymers Containing Benzodithiophene with Bithienyl Substituents

Ruvini S. Kularatne、Prakash Sista、Hien Nguyen 等 6 位作者2012-09-17Macromolecules

Synthesis and photovoltaic properties of two donor–acceptor polymers containing benzodithiophene with 3,3′,5-trihexylbithienyl substituents are reported. Benzo[ c ][1,2,5]thiadiazole and 5-hexylthieno[3,4- c ]pyrrole-4,6-dione were used as acceptor building blocks for the synthesis of donor–acceptor polymers. The phot…

Organic Electronics and PhotovoltaicsPerovskite Materials and ApplicationsConducting polymers and applications

Papaya Fruit Quality Management during the Postharvest Supply Chain

Dharini Sivakumar、Marisa M. Wall2012-09-17Food Reviews International

Papayas are popular in tropical and subtropical regions and are being exported in large volumes to Europe, the United States, and Japan. The fruit has a sweet, exotic flavor and is rich in vitamins A and C and antioxidants. However, due to its highly perishable nature, it has not emerged as a major traded fruit. Papay…

Postharvest Quality and Shelf Life ManagementNanocomposite Films for Food PackagingBanana Cultivation and Research

Mass Spectrometric Investigations of Nano‐Size Cluster Ions Produced by High Pressure Magnetron Sputtering

Marina Ganeva、Tilo Peter、Sven Bornholdt 等 8 位作者2012-09-17Contributions to Plasma Physics

Abstract A comparison of quadrupole mass spectrometric (QMS) and transmission electron microscopic (TEM) characterization of silver nano‐cluster deposition produced by a nano‐cluster source consisting of a planar DC magnetron sputter source in a high pressure gas aggregation chamber is presented and discussed. Cluster…

Nanoparticles: synthesis and applicationsIon-surface interactions and analysisnanoparticles nucleation surface interactions

Nanoparticle magnetization measurements by a high sensitive nano-superconducting quantum interference device

R. Russo、C. Granata、E. Esposito 等 6 位作者2012-09-17Applied Physics Letters

A high sensitive nano superconducting quantum interference device (nanoSQUID) operating as a magnetic flux to critical current transducer with a suitable feedback circuit is employed to measure the magnetization of ferrimagnetic iron oxide nanoparticles. An improved SQUID responsivity has been obtained by using a loop…

Magnetic properties of thin filmsMagnetic Properties and ApplicationsCharacterization and Applications of Magnetic Nanoparticles

Microscopic model of a phononic refrigerator

Liliana Arrachea、Eduardo R. Mucciolo、Claudio Chamon 等 4 位作者2012-09-17Physical Review B

We analyze a simple microscopic model to pump heat from a cold to a hot reservoir in a nanomechanical system. The model consists of a one-dimensional chain of masses and springs coupled to a back gate through which a time-dependent perturbation is applied. The action of the gate creates a moving phononic barrier by lo…

Thermal properties of materialsAdvanced Thermodynamics and Statistical MechanicsThermal Radiation and Cooling Technologies

Recovery improvement of graphene-based gas sensors functionalized with nanoscale heterojunctions

Il‐Suk Kang、Hye‐Mi So、Gyeong-Sook Bang 等 6 位作者2012-09-17Applied Physics Letters

We report a development of reduced graphene oxide (rGO)-based gas sensors with a practical recovery by facile functionalization with tin dioxide nanoclusters. Upon the introduction of UV illumination to this nanostructure, the reaction on surfaces of tin dioxide nanoclusters was activated and thereby the nanoscale het…

Gas Sensing Nanomaterials and SensorsTransition Metal Oxide NanomaterialsAnalytical Chemistry and Sensors

External Heavy-Atomic Construction of Photosensitizer Nanoparticles for Enhanced in Vitro Photodynamic Therapy of Cancer

Lin Zhou、Shaohua Wei、Xuefeng Ge 等 6 位作者2012-09-17The Journal of Physical Chemistry B

Introduction of heavy atoms around photosensitizers (PSs) generally facilitates intersystem crossing (ISC) and improves their quantum yield of singlet oxygen ((1)O(2)) generation ability, which is a key species in photodynamic therapy (PDT). Here, we report Pt(IV)- and Au(III)-modified silica nanoparticles (SN) as the…

Nanoplatforms for cancer theranosticsPorphyrin and Phthalocyanine ChemistryPhotodynamic Therapy Research Studies

Molecular gradient for second-order Møller-Plesset perturbation theory using the divide-expand-consolidate (DEC) scheme

Kasper Kristensen、Poul Jørgensen、Branislav Jansı́k 等 5 位作者2012-09-17The Journal of Chemical Physics

We demonstrate that the divide-expand-consolidate (DEC) scheme--which has previously been used to determine the second-order Møller-Plesset (MP2) correlation energy--can be applied to evaluate the MP2 molecular gradient in a linear-scaling and embarrassingly parallel manner using a set of local Hartree-Fock orbitals.…

Advanced Chemical Physics StudiesNonlinear Optical Materials ResearchSpectroscopy and Quantum Chemical Studies

Origin of strong magnetic anisotropy in L10-FeNi probed by angular-dependent magnetic circular dichroism

Masato Kotsugi、Masaki Mizuguchi、Shigeki Sekiya 等 12 位作者2012-09-17Journal of Magnetism and Magnetic Materials

We investigated the origin of strong magnetic anisotropy energy (MAE) in L10-type ordered FeNi phase by angular-dependent magnetic circular dichroism. Our findings showed that the orbital magnetic moment of Fe has a significant angular dependence that exhibits a maximum value at the [001] direction corresponding perpe…

Magnetic properties of thin filmsMagnetic Properties and ApplicationsMagnetic Properties of Alloys

Acoustic velocities of pure and iron‐bearing magnesium silicate perovskite measured to 25 GPa and 1200 K

Julien Chantel、D. J. Frost、Catherine McCammon 等 5 位作者2012-09-17Geophysical Research Letters

Ultrasonic interferometry measurements in conjunction with in situ X‐ray techniques have been used to measure compressional and shear wave velocities and densities of MgSiO3perovskite (Mg‐Pv) and Mg0.95Fe0.042+Fe0.013+SiO3perovskite ((Mg, Fe)‐Pv) in the multianvil at pressures up to 25 GPa and temperatures to 1200 K.…

Geological and Geochemical AnalysisHigh-pressure geophysics and materialsCrystal Structures and Properties

Performance and polarization effects in (112¯2) long wavelength light emitting diodes grown on stress relaxed InGaN buffer layers

Ingrid Koslow、Matthew T. Hardy、Po Shan Hsu 等 11 位作者2012-09-17Applied Physics Letters

Long wavelength (525–575 nm) (112¯2) light emitting diodes were grown pseudomorphically on stress relaxed InGaN buffer layers. Basal plane dislocation glide led to the formation of misfit dislocations confined to the bottom of the InGaN buffer layer. This provided one-dimensional plastic relaxation in the film interio…

Semiconductor Quantum Structures and DevicesZnO doping and propertiesGaN-based semiconductor devices and materials

Coating of conductive yarns for electro-textile applications

R. Alagirusamy、Julian Eichhoff、Thomas Gries 等 4 位作者2012-09-17Journal of the Textile Institute

Conductive yarns are used for integration of sensors and other electronic devices with textile fabrics through weaving, knitting, braiding or embroidery processes. In the lifetime of the textile also several washing cycles might occur. These processes involve rubbing which may lead to displacement of conductive fibres…

Advanced Sensor and Energy Harvesting MaterialsConducting polymers and applicationsTextile materials and evaluations

Factors influencing the ballistic impact resistance of elastomer-coated metal substrates

C. M. Roland、D. Fragiadakis、Raymond M. Gamache 等 4 位作者2012-09-17The Philosophical Magazine A Journal of Theoretical Experimental and Applied Physics

An experimental study was carried out of various factors affecting the ballistic penetration resistance of elastomer/steel bilayers. For blunt penetrators, the contribution of the coating to performance is optimized using the hardest substrates, front surface placement of the elastomer, and (when normalizing by added…

Energetic Materials and CombustionHigh-Velocity Impact and Material BehaviorStructural Response to Dynamic Loads

Correlating local structure with inhomogeneous elastic deformation in a metallic glass

Jun Ding、Yongqiang Cheng、E. Ma2012-09-17Applied Physics Letters

The elastic response of metallic glasses (MGs) is inhomogeneous, due to the wide variation of local structural arrangements. Here, we present molecular dynamics simulations on a one-million-atoms sample of a Cu64Zr36 model MG, correlating the atomic strain and non-affine displacement with short-range order. Cu atoms i…

Material Dynamics and PropertiesGlass properties and applicationsMetallic Glasses and Amorphous Alloys

Toward high performance inverted polymer solar cells

Xiong Gong2012-09-17Polymer

Bulk heterojunction (BHJ) polymer solar cells (PSCs) that can be fabricated by solution processing techniques are under intense investigation in both academic institutions and industrial companies because of their potential to enable mass production of flexible and cost-effective alternative to silicon-based solar cel…

Organic Electronics and PhotovoltaicsThin-Film Transistor TechnologiesConducting polymers and applications