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Newsprint paper waste as a fiber reinforcement in rubber composites

D. E. El. Nashar、S. L. Abd‐El‐Messieh、Altaf H. Basta2004-01-16Journal of Applied Polymer Science

Abstract The investigation of the economical use of lignocellulose waste, which is one of the environmental problems facing third‐world nations, is ongoing. In this study, we intended to increase the use of newsprint fibers in the rubber industry. For this reason, we treated newsprint fibers with sodium silicate and m…

Natural Fiber Reinforced CompositesAdvanced Cellulose Research StudiesRecycling and Waste Management Techniques

Deterioration behavior of cellulose acetate films in acidic or basic aqueous solutions

Yoichiro Yamashita、Takeshi Endo2004-01-16Journal of Applied Polymer Science

Abstract The deterioration behavior of cellulose acetate (CA) films (degree of substitution = 2.5) was examined in hydrochloric acid (HCl) and sodium hydroxide (NaOH) solutions of various concentrations to determine acid and base catalytic effects in heterogeneous systems at room temperature. With concentrations of 0.…

Surface Modification and SuperhydrophobicityAdvanced Cellulose Research StudiesLignin and Wood Chemistry

Effect of steric hindrance on hydrogen‐bonding interaction between polyesters and natural polyphenol catechin

Bo Zhu、Jianchun Li、Yong He 等 7 位作者2004-01-16Journal of Applied Polymer Science

Abstract The phase behaviors for the blends of poly(3‐hydroxypropionate) (PHP), poly( L ‐lactide) (PLLA), poly( D ‐lactide) (PDLA), and poly( D,L ‐lactide) (PDLLA) with catechin were investigated by differential scanning calorimetry. In PLLA/catechin, PDLA/catechin, and PDLLA/catechin blends, two glass transitions wer…

Nanocomposite Films for Food Packagingbiodegradable polymer synthesis and propertiesTea Polyphenols and Effects

Reduced Transaminase B (IlvE) Activity Caused by the Lack ofyjgFIs Dependent on the Status of Threonine Deaminase (IlvA) inSalmonella entericaSerovar Typhimurium

George E. Schmitz、Diana M. Downs2004-01-16Journal of Bacteriology

The YjgF/YER057c/UK114 family is a highly conserved class of proteins that is represented in the three domains of life. Thus far, a biochemical function demonstrated for these proteins in vivo or in vitro has yet to be defined. In several organisms, strains lacking a YjgF homolog have a defect in branched-chain amino…

Microbial Metabolic Engineering and BioproductionEndoplasmic Reticulum Stress and DiseaseEnzyme Structure and Function

Vibrational Spectroscopy of a Keggin Polyoxometalate on Metal Electrode Surfaces

Craig M. Teague、Xiao Li、Mary Ellen Biggin 等 6 位作者2004-01-16The Journal of Physical Chemistry B

Polarization modulation infrared reflection−absorption spectroscopy and surface-enhanced Raman spectroscopy are used to interrogate the behavior of the Keggin-type polyoxometalate α-[SiW 12 O 40 ] 4- on Ag and Au electrode surfaces. Assignment of specific vibrational modes and their behavior as a function of potential…

Metal-Organic Frameworks: Synthesis and ApplicationsPolyoxometalates: Synthesis and ApplicationsAdvanced Nanomaterials in Catalysis

The Role of Weakly Bound On-Top Oxygen in the Catalytic CO Oxidation Reaction over RuO2(110)

Stefan Wendt、Marcus Knapp、Herbert Over2004-01-16Journal of the American Chemical Society

RuO(2)-based catalysts are much more active in the oxidation of CO than related metallic Ru catalysts. This high catalytic activity (or low activation barrier) is attributed to the weak oxygen surface bonding of bridging O atoms on RuO(2)(110) in comparison with the strongly chemisorbed oxygen on Ru(0001). Since the R…

Advanced Chemical Physics StudiesCatalytic Processes in Materials ScienceCatalysis and Oxidation Reactions

Water quality assessment using diatom assemblages and advanced modelling techniques

Muriel Gevrey、Frédéric Rimet、Young‐Seuk Park 等 6 位作者2004-01-16Freshwater Biology

Summary 1. Two types of artificial neural networks procedures were used to define and predict diatom assemblage structures in Luxembourg streams using environmental data. 2. Self‐organising maps (SOM) were used to classify samples according to their diatom composition, and multilayer perceptron with a backpropagation…

Hydrological Forecasting Using AIDiatoms and Algae ResearchWater Quality Monitoring and Analysis

Carbaporphyrinoid Chemistry Has a Silver Lining! Silver(III) Oxybenzi-, Oxynaphthi-, Tropi-, and Benzocarbaporphyrins

Timothy D. Lash、Jane M. Rasmussen、Katrina M. Bergman 等 4 位作者2004-01-16Organic Letters

[structure: see text] Carbaporphyrinoid systems with semiquinone, cycloheptatriene, or indene subunits react under mild conditions with silver(I) acetate to give stable silver(III) organometallic derivatives.

Porphyrin and Phthalocyanine ChemistryMetal-Catalyzed Oxygenation MechanismsPorphyrin Metabolism and Disorders

Rational Design of Macrocellular Silica Scaffolds Obtained by a Tunable Sol–Gel Foaming Process

Florent Carn、Annie Colin、M. F. Achard 等 6 位作者2004-01-16Advanced Materials

A technique that uses a non‐static patterning method has been employed for rational design toward macrocellular silica scaffolds (see Figure). The technique allows complete control over the width, length, and curvature of the plateau borders of the silica foam. Furthermore, this macroscale void space structuration is…

Surface Modification and SuperhydrophobicityMesoporous Materials and CatalysisPickering emulsions and particle stabilization

Preparation of water‐soluble chitosan

Lü Shaojie、Xuefeng Song、Deyong Cao 等 5 位作者2004-01-16Journal of Applied Polymer Science

Abstract An improved method of preparing water soluble chitosan was studied by N ‐acetylation with acetic anhydride. Its merits were a simple processing technique, very short reaction time, little agent, high molecular weight of the product, and good water solubility. This article not only discusses the effect of seve…

Nanocomposite Films for Food PackagingConducting polymers and applicationsBiopolymer Synthesis and Applications

Logic Control of the Fluorescence of a New Dyad, Spiropyran‐Perylene Diimide‐Spiropyran, with Light, Ferric Ion, and Proton: Construction of a New Three‐Input “AND” Logic Gate

Xuefeng Guo、Deqing Zhang、Daoben Zhu2004-01-16Advanced Materials

The fluorescence of a novel dyad with spiropyran and perylene diimide units can be significantly enhanced only under the combined actions of UV light, protons, and ferric ions (see Figure). This behavior corresponds to a new “AND” gate with three inputs.

Photochromic and Fluorescence ChemistryPhotoreceptor and optogenetics researchbioluminescence and chemiluminescence research

Phase Segregation in Gradient Copolymer Melts

Michelle D. Lefebvre、Mónica Olvera de la Cruz、Kenneth R. Shull2004-01-16Macromolecules

Local segregation in melts of copolymers with composition gradients along their backbones is analyzed. The transition to a lamellar periodic structure as the effective degree of incompatibility χ N increases is studied for symmetric copolymers with various composition gradients. A numerical self-consistent mean-field…

Polymer crystallization and propertiesAdvanced Polymer Synthesis and CharacterizationBlock Copolymer Self-Assembly

Direct Evidence for Vertical Diffusion and Exchange Processes of Polyanions and Polycations in Polyelectrolyte Multilayer Films

Philippe Lavall�e、Valérie Vivet、Jean‐Pierre Jessel 等 7 位作者2004-01-16Macromolecules

ADVERTISEMENT RETURN TO ISSUEPREVNoteNEXTDirect Evidence for Vertical Diffusion and Exchange Processes of Polyanions and Polycations in Polyelectrolyte Multilayer FilmsPhilippe Lavalle, Valérie Vivet, Nadia Jessel, Gero Decher, Jean-Claude Voegel, Philippe J. Mesini, and Pierre SchaafView Author Information Institut N…

Surfactants and Colloidal SystemsPolymer Surface Interaction StudiesBlock Copolymer Self-Assembly

Sub-micrometer Conducting Polyaniline Tubes Prepared from Polymer Fiber Templates

Hong Dong、Sudhindra Prasad、Verrad Nyame 等 4 位作者2004-01-16Chemistry of Materials

Polyaniline tubes have been prepared using sub-micrometer polymer fibers as templates. The core fibers were fabricated by a nonmechanical electrostatic process known as electrospinning. Conductive polyaniline (PANi) was coated on the surface of preformed polymer nanofibers through in situ deposition. The removal of th…

Supercapacitor Materials and FabricationAdvanced Sensor and Energy Harvesting MaterialsConducting polymers and applications

Mechanical and thermal properties of talc and calcium carbonate filled polypropylene hybrid composites

Wai Yie Leong、Z. A. Mohd Ishak、A. Ariffin2004-01-16Journal of Applied Polymer Science

Abstract The main aim of this work was to study and compare the mechanical and thermal properties of hybrid polypropylene (PP) composites and single‐filler PP composites. With two main types of mineral fillers—calcium carbonate (CaCO 3 ) and talc—PP composites of different filler weight ratios (talc/CaCO 3 ) were comp…

Polymer Nanocomposites and PropertiesNatural Fiber Reinforced Compositesbiodegradable polymer synthesis and properties

Preparation of Nanocomposites by Exfoliation of ZnAl Layered Double Hydroxides in Nonpolar LLDPE Solution

Wei Chen、Feng Li、Baojun Qu2004-01-16Chemistry of Materials

The exfoliated ZnAl hydroxide sheets of LLDPE/ZnAl LDH exfoliated nanocomposite with 20 wt % loading of Zn3Al(DS) are dispersed in a disordered fashion in the LLDPE matrix. The thickness and the width/length of the individual exfoliated Zn3Al(DS) layers (combined with DS ions) are determined to be 1.5−2.5 and 15−20 nm…

Polymer Nanocomposites and PropertiesLayered Double Hydroxides Synthesis and ApplicationsSilicone and Siloxane Chemistry

Thermal conductivity of thermoelectric clathrates

Anders Bentien、Mogens Christensen、J. Daniel Bryan 等 8 位作者2004-01-16Physical Review B

Transport properties of ${\mathrm{Ba}}_{8}{\mathrm{Ga}}_{16}{\mathrm{Ge}}_{30}$ single-crystalline samples prepared with an excess of Ga are presented. The excess Ga does not only produces p-type transport properties but also a thermal conductivity (\ensuremath{\kappa}) that, unlike in any other ${\mathrm{Ba}}_{8}{\ma…

Advanced Thermoelectric Materials and DevicesTopological Materials and PhenomenaThermal properties of materials

Fabrication of Stimulus-Responsive Nanopatterned Polymer Brushes by Scanning-Probe Lithography

Marián Kaholek、Woo‐Kyung Lee、Bruce LaMattina 等 5 位作者2004-01-16Nano Letters

Stimulus-responsive, surface confined poly( N -isopropylacrylamide) (pNIPAAM) brush nanopatterns were prepared on gold-coated silicon substrates in a “grafting-from” approach that combines “nanoshaving”, a scanning probe lithography method, with surface-initiated polymerization using atom transfer radical polymerizati…

Polymer Surface Interaction StudiesForce Microscopy Techniques and ApplicationsNanofabrication and Lithography Techniques

Curing and mechanical characterization of a soy‐based epoxy resin system

Jiang Zhu、K. Chandrashekhara、V. Flanigan 等 4 位作者2004-01-16Journal of Applied Polymer Science

Abstract A potentially inexpensive alternative epoxy resin system based on soybean oil has been developed for polymer composite applications. Epoxidized methyl soyate (EMS) and epoxidized allyl soyate (EAS) have been synthesized at the University of Missouri–Rolla. These materials consist of mixtures of epoxidized fat…

Polymer composites and self-healingSilicone and Siloxane ChemistryPhotopolymerization techniques and applications

Moisture Absorption and Absorption Kinetics in Polyelectrolyte Films: Influence of Film Thickness

Bryan D. Vogt、Christopher L. Soles、Hae‐Jeong Lee 等 5 位作者2004-01-16Langmuir

Specular X-ray reflectivity (XR) and quartz crystal microbalance (QCM) measurements were used to determine the absorption of water into thin poly(4-ammonium styrenesulfonic acid) films from saturated vapor at 25 degrees C. The effect of film thickness on the absorption kinetics and overall absorption was investigated…

Surface Modification and SuperhydrophobicityAdvanced Sensor and Energy Harvesting MaterialsPolymer Surface Interaction Studies