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Fractionation and Characterisation of Propylene‐Ethylene Random Copolymers: Effect of the Comonomer on Crystallisation of Poly(propylene) in the γ‐Phase

Gareth W. Harding、Albert J. van Reenen2006-09-18Macromolecular Chemistry and Physics

Abstract Summary: Three propylene‐ethylene random copolymers, of varying ethylene content, were fractionated using preparative TREF. The TREF fractions were subsequently analysed offline by CRYSTAF, DSC, 13 C NMR spectroscopy, HT‐GPC, and WAXD. The effect of the ethylene comonomer on the crystallisability of the propy…

Polymer crystallization and propertiesbiodegradable polymer synthesis and propertiesThermal and Kinetic Analysis

In-cluster-structured exchange-coupled magnets with high energy densities

X. Rui、Jeffrey E. Shield、Z. Sun 等 5 位作者2006-09-18Applied Physics Letters

In this letter, the authors demonstrate isotropic Fe–Pt exchange-spring nanocomposite permanent magnets with a soft magnetic phase fraction of greater than 0.5 with a coercivity of 6.5kOe, single-phase-like magnetic behavior, and an energy product of 25.1MGOe. Sub-10-nm Fe–Pt clusters are formed with compositions in t…

Magnetic properties of thin filmsHydrogen Storage and MaterialsMagnetic Properties of Alloys

Structural characterization and potential x-ray waveguiding of a small rolled-up nanotube with a large number of windings

Christoph Deneke、Oliver G. Schmidt2006-09-18Applied Physics Letters

The cross-section of an InGaAs∕GaAs rolled-up nanotube with an average inner diameter of 18nm and with a large number of windings is prepared by focused ion beam etching and investigated by transmission electron microscopy. This technique provides useful information about the shape and size of the inner as well as out…

Carbon Nanotubes in CompositesAdvanced MEMS and NEMS TechnologiesMechanical and Optical Resonators

Large negative magnetoresistance and strong localization in highly disordered electrospun pregraphitic carbon nanofiber

Yu Wang、Jorge J. Santiago‐Avilés2006-09-18Applied Physics Letters

A highly disordered pregraphitic carbon nanofiber with the product of its quasi-Fermi wave vector and mean free path close to 1 was fabricated using electrospinning technique. Strong localization made the conductivity vary with temperature as lnσ∝T−1∕2 from 300to5K, suggesting variable range hopping as the conductivit…

Advancements in Battery MaterialsCarbon Nanotubes in CompositesGraphene research and applications

Formation of CdS Nanoparticle Necklaces with Functionalized Dendronized Polymers

Yan-Hong Zhang、Yongming Chen、Haijun Niu 等 4 位作者2006-09-18Small

A one-dimensional assembly of cadmium sulfide (CdS) nanoparticles was prepared by using functionalized polymers with pendant Fréchet-type dendritic wedges of different generation. The novel dendronized polymers acted as both nanoreactors for the formation of CdS nanoparticles and a template to arrange the nanoparticle…

Gold and Silver Nanoparticles Synthesis and ApplicationsRNA Interference and Gene DeliveryDendrimers and Hyperbranched Polymers

Perovskite lead zirconium titanate nanorings: Towards nanoscale ferroelectric “solenoids”?

X. H. Zhu、P. R. Evans、David Byrne 等 10 位作者2006-09-18Applied Physics Letters

Rings of perovskite lead zirconium titanate (PZT) with internal diameters down to ∼5nm and ring thicknesses of ∼5–10nm have been fabricated and structurally, crystallographically, and chemically characterized using an analytical transmission electron microscope. Ring fabrication involved conformal solution deposition…

Ferroelectric and Piezoelectric MaterialsPerovskite Materials and ApplicationsMultiferroics and related materials

Energy absorption capacity of carbon nanotubes under ballistic impact

Kausala Mylvaganam、L. C. Zhang2006-09-18Applied Physics Letters

Carbon nanotubes have great potential applications in making ballistic-resistance materials. This letter analyzes the impact of a bullet on nanotubes of different radii in two extreme cases. For a nanotube with one end fixed, the maximum nanotube enduring bullet speed increases and the energy absorption efficiency dec…

Carbon Nanotubes in CompositesForce Microscopy Techniques and ApplicationsHigh-Velocity Impact and Material Behavior

Synthesis and Characterization of Highly Ordered Cobalt–Magnetite Nanocable Arrays

Brian Daly、Donna C. Arnold、Jaideep S. Kulkarni 等 9 位作者2006-09-18Small

Magnetically tunable, high-density arrays of coaxial nanocables within anodic aluminum oxide (AAO) membranes have been synthesized. The nanocables consist of magnetite nanowires surrounded by cobalt nanotube sheaths and cobalt nanowires surrounded by magnetite nanotube sheaths. These materials are a combination of sep…

Semiconductor materials and devicesNanopore and Nanochannel Transport StudiesAnodic Oxide Films and Nanostructures

Tristate liquid crystal display with memory and dynamic operating modes

Chul Gyu Jhun、Chao Ping Chen、Uk Joo Lee 等 6 位作者2006-09-18Applied Physics Letters

So far, monostable and bistable liquid crystal display (LCD) modes have independently been researched and developed. The authors propose a tristate LCD that can be operated in memory mode as well as dynamic mode. The proposed device has a unique texture of splay, π twist, and bend states with applied voltages and is o…

Photonic and Optical DevicesLiquid Crystal Research AdvancementsSemiconductor Lasers and Optical Devices

Thermoreflectance temperature imaging of integrated circuits: calibration technique and quantitative comparison with integrated sensors and simulations

Gilles Tessier、M-L Polignano、S. Pavageau 等 7 位作者2006-09-18Journal of Physics D Applied Physics

Camera-based thermoreflectance microscopy is a unique tool for high spatial resolution thermal imaging of working integrated circuits. However, a calibration is necessary to obtain quantitative temperatures on the complex surface of integrated circuits. The spatial and temperature resolutions reached by thermoreflecta…

Thermal properties of materialsThermography and Photoacoustic TechniquesAdvanced Sensor Technologies Research

Centrosymmetric and pseudo-centrosymmetric structures refined as non-centrosymmetric

H. D. Flack、G. Bernardinelli、D.A. Clemente 等 5 位作者2006-09-18Acta Crystallographica Section B Structural Science

The behaviour of the Flack parameter for centrosymmetric and pseudo-centrosymmetric crystal structures based on crystal structures published as being non-centrosymmetric is presented. It is confirmed for centrosymmetric structures that the value obtained for the Flack parameter is critically dependent on the Friedel c…

Crystallography and molecular interactionsCrystal Structures and PropertiesX-ray Diffraction in Crystallography

Effect of reactive species on surface crosslinking of plasma-treated polymers investigated by surface force microscopy

Satomi Tajima、K. Komvopoulos2006-09-18Applied Physics Letters

Polymer surface modification by ions, uncharged particles, and photons of inductively coupled Ar plasma was investigated with a surface force microscope. Optical windows consisting of crystals with different cutoff wavelengths and a metal shield were used to deconvolute the effects of the various plasma species on the…

Metal and Thin Film MechanicsDiamond and Carbon-based Materials ResearchIon-surface interactions and analysis

Approach to magnetic losses and their frequency dependence in Mn–Zn ferrites

F. Fiorillo、C. Beatrice、Oriano Bottauscio 等 5 位作者2006-09-18Applied Physics Letters

The frequency dependence of the magnetic energy losses in sintered Mn–Zn ferrites is predicted from the quasistatic regime to the megahertz range. The predicting model is based on the appraisal of the contributions by domain wall (dw) displacements and magnetization rotations and the related relaxation-resonant-type d…

Magnetic properties of thin filmsMagnetic Properties and Synthesis of FerritesMagnetic Properties and Applications

Electronic Conductive Microporous Polymer‐Based Structures

Dinçer Yakisir、Frej Mighri、Mosto Bousmina2006-09-18Macromolecular Rapid Communications

Abstract Summary: This study aims at developing a highly electronic conductive microporous structure from thermoplastic polymers filled with carbon black (CB) and graphite (GR). The matrix was a low viscosity poly(propylene) (PP) and the conductive additives were composed of high specific surface area CB and synthetic…

Polymer Nanocomposites and PropertiesConducting polymers and applicationsPolymer composites and self-healing

Carbon Nanotubes Based Devices and Sensors

Ashok Vaseashta2006-09-18Materials and Manufacturing Processes

The dimensionality of a system has a profound influence on its physical behavior, especially for nanostructured materials where at least one of the dimensions is less than 100 nm and, in many instances, the size is comparable with the size of many fundamental physical quantities. Carbon-based nanostructured materials…

Carbon Nanotubes in CompositesElectrochemical sensors and biosensorsConducting polymers and applications

Dyeing poly(lactic acid) fibres in supercritical carbon dioxide

E. Bach、Dierk Knittel、Eckhard Schollmeyer2006-09-18Coloration Technology

A study has been conducted into the dyeing of poly(lactic acid) fibres in supercritical carbon dioxide. The fibres were completely dyed using disperse dyes at 50 °C as shown by fibre cross‐sections, although high colour depths in dark shades still prove challenging. Dye uptake increased significantly at temperatures ≥…

Carbon dioxide utilization in catalysisPolymer Foaming and CompositesMicrobial Metabolism and Applications

The influence of the ac electrodeposition conditions on the magnetic properties and microstructure of Co nanowire arrays

M. Almasi Kashi、Ahmad Ramazani、A. Khayyatian2006-09-18Journal of Physics D Applied Physics

The effect of electrodeposition frequency and waveform on the magnetic properties and microstructures of Co nanowires were investigated. The results show that depending on the value of the electrodeposition frequency appreciable changes in the crystalline anisotropy can be induced. These changes are attributed to modi…

Electrodeposition and Electroless CoatingsAnodic Oxide Films and NanostructuresNanoporous metals and alloys

Formation of CdTe nanostructures with dot, rod, and tetrapod shapes

Jiayu Zhang、William W. Yu2006-09-18Applied Physics Letters

Colloidal dot-, rod-, and tetrapod-shaped CdTe nanocrystals (NCs) are obtained by varying the precursor concentration and the ligands. Both the dot- and rod-shaped NCs are of zinc-blende phase, whereas the tetrapod-shaped NCs are a mixture of zinc-blende and wurtzite structures. It is proposed that the concentration o…

Quantum Dots Synthesis And PropertiesChalcogenide Semiconductor Thin FilmsNanocluster Synthesis and Applications

Analysis of insulation characteristics of c-C4F8and N2gas mixtures by the Monte Carlo method

BianTao Wu、Dengming Xiao、ZhangSheng Liu 等 5 位作者2006-09-18Journal of Physics D Applied Physics

The motion of electrons in c-C 4 F 8 and N 2 gas mixtures for a pulsed Townsend discharge is simulated by the Monte Carlo method. The effective ionization coefficient, , over the E / N range from 160 to 480 Td is calculated by employing a set of cross sections available in the literature. From the variation curve of w…

High voltage insulation and dielectric phenomenaScientific Measurement and Uncertainty EvaluationAdvanced Sensor Technologies Research

Density functional theory of structural transformations of oxygen-deficient centers in amorphous silica during hole trapping: Structure and formation mechanism of theEγ′center

Takashi Uchino、Toshinobu Yoko2006-09-18Physical Review B

We investigate the hole trapping process of a neutral oxygen vacancy in amorphous silicon dioxide $(a\text{\ensuremath{-}}\mathrm{Si}{\mathrm{O}}_{2})$ using cluster calculations based on the density functional theory (DFT) method. We show that trapping a hole at a neutral oxygen vacancy leads to the formation of seve…

Glass properties and applicationsThin-Film Transistor TechnologiesSilicon Nanostructures and Photoluminescence