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Dielectric spectroscopy of liquid crystalline unsymmetrical azomethines with one imine bond: influence of rod length and type of terminal chains

Agnieszka Iwan、Magdalena Włodarska2012-06-06Liquid Crystals

In this work we have studied the dielectric properties of five unsymmetrical azomethine (A1−A5) liquid crystals prepared from different aldehydes or obtained from various amines. The effects of rod length and type of terminal chains on the thermal and mesomorphic behaviours were investigated by dielectric spectroscopy…

Liquid Crystal Research AdvancementsNonlinear Optical Materials ResearchSynthesis and properties of polymers

MODULATION OF FRET THROUGH THE SPECTRAL-OVERLAP STRATEGY

Haibo Yu、Yi Xiao2012-06-06Journal of Innovative Optical Health Sciences

Fluorescence resonance energy transfer (FRET) is an important photophysical mechanism which finds many applications in biophotonics, particularly in biological sensing and imaging. It is well known, there are two major factors that determine the efficiency of FRET. One is the distance between the donor and the accepto…

Advanced biosensing and bioanalysis techniquesLuminescence and Fluorescent MaterialsAnalytical Chemistry and Sensors

Terminal Gold-Oxo Complexes

Rui Cao、Travis M. Anderson、P.M.B. Piccoli 等 18 位作者2012-06-06Journal of the American Chemical Society

ADVERTISEMENT RETURN TO ISSUEPREVAddition/CorrectionNEXTORIGINAL ARTICLEThis notice is a correctionTerminal Gold-Oxo ComplexesRui Cao, Travis M. Anderson, Paula M. B. Piccoli, Arthur J. Schultz, Thomas F. Koetzle, Yurii V. Geletii, Elena Slonkina, Britt Hedman, Keith O. Hodgson, Kenneth I. Hardcastle, Xikui Fang, Mart…

Metal complexes synthesis and propertiesMagnetism in coordination complexesPolyoxometalates: Synthesis and Applications

Nanoparticles to Cross Biological Barriers

Thomas L. Moore、Elizabeth G. Graham、Brandon Mattix 等 4 位作者2012-06-06Biomaterials Science

KEY TERMS: Drug delivery, pulmonary delivery, oral delivery, nasal delivery, transdermal delivery, circulation time, biodistribution, excretion, blood-brain barrier Polymeric nanoparticle delivery systems have the potential to signicantly impact the treatment of cancer. Nanoparticle drug delivery systems offer the abi…

Nanoparticle-Based Drug DeliveryCancer Research and Treatment

Comparative studies on parametric sensitivity analyses using conventional and factorial design methodologies: mathematical modelling of clavulanic acid adsorption on zeolites

Marcus Bruno Soares Forte、Márcio A. Mazutti、Francisco Maugeri Filho 等 4 位作者2012-06-06Journal of Chemical Technology & Biotechnology

Abstract BACKGROUND: The main objective of this work was to evaluate the parametric sensitivity of model parameters of clavulanic acid (CA) adsorption in a stirred‐tank reactor using zeolites. The system sensitivity was evaluated in terms of mass transfer and hydrodynamic parameters using two methodologies. First, the…

Analytical chemistry methods developmentCoagulation and Flocculation StudiesCrystallization and Solubility Studies

Ribbons, Vesicles, and Baskets: Supramolecular Assembly of a Coil–Plate–Coil Emeraldicene Derivative

Mingfeng Wang、Ali Mohebbi、Yanming Sun 等 4 位作者2012-06-06Angewandte Chemie

Selbstassoziate der Titelverbindung 1 ändern sich von definierten Bändern über Vesikel zu Körben (siehe Bild) bei Verringerung der Konzentration in Tetrahydrofuran. Elektronenmikroskopie zeigte eine einzigartige selbstorganisierte Struktur: Körbe werden von gebogenen und eingewickelten nanometerdünnen Bändern gebildet…

Organic Electronics and PhotovoltaicsPorphyrin and Phthalocyanine ChemistrySupramolecular Self-Assembly in Materials

An Fe(CO)5‐Thermolysis‐Based Process for the Preparation of Polymer@Iron Composite Powders with High Corrosion Resistance

Guy Nesher、G. Marom、David Avnir2012-06-06European Journal of Inorganic Chemistry

Abstract A new method for the preparation of metal–polymer composite materials is described. This new approach of doping of metals is based on the thermolysis of a zero‐valent complex. Specifically, several polymer@Fe‐composite powders were prepared and fully characterized. Iron doped with polydimethylsiloxane showed…

Electrocatalysts for Energy ConversionCatalytic Processes in Materials ScienceMesoporous Materials and Catalysis

Influence of high intensity ultrasound treatments on physical properties of sheep milk.

Tomislav Bosiljkov、Branko Tripalo、Damir Ježek 等 6 位作者2012-06-06University of Zagreb University Computing Centre (SRCE)

Ultrasound process parameters had infl uence on the temperature increase as result of wave propagation throughout medium. Cavitation as the most accepted mechanism is based on the implosion of bubbles in surrounding media (Bosiljkov et al., 2011; Brncic et al., 2010; Price et al., 2010; Thiemann et al., 2011). Effi ci…

Meat and Animal Product QualityMicrobial Inactivation MethodsUltrasound and Cavitation Phenomena

Improved and delayed radiative emission response of Eu-doped BaTiO3nanoscale system

M. Borah、Dambarudhar Mohanta、Dirtha Sanyal 等 5 位作者2012-06-06The European Physical Journal Applied Physics

We report on the structural, spectroscopic and radiative emission characteristics of Eu-doped BaTiO3 (BT) nanosystem as compared to the pure BT system. The structural analysis was performed by X-ray diffraction (XRD) studies where the nanoscale BT sample exhibits a perovskite structure with most intense peak along (1…

Luminescence Properties of Advanced MaterialsFerroelectric and Piezoelectric MaterialsGlass properties and applications

Sawhorse‐Type Tetracarbonyldiruthenium Tweezers

Justin P. Johnpeter、John Mohanraj、Nicola Armaroli 等 4 位作者2012-06-06European Journal of Inorganic Chemistry

Abstract Molecular tweezers built from sawhorse‐type dinuclearruthenium units and carboxyphenyl porphyrin derivatives{5‐(4‐carboxyphenyl)‐10,15,20‐triphenyl‐21H,23H‐porphyrin,[5‐(4‐carboxyphenyl)‐10,15,20‐triphenylporphyrin]zinc, 5,10‐bis(4‐carboxyphenyl)‐15,20‐diphenyl‐21H,23H‐porphyrin, and [5,10‐bis(4‐carboxyphenyl…

Advanced Chemical Physics StudiesSupramolecular Chemistry and ComplexesPorphyrin and Phthalocyanine Chemistry

Electronic and magnetic properties in strongly correlated heterostructures

Suguru Ueda、Norio Kawakami、Manfred Sigrist2012-06-06Physical Review B

We present a theoretical study of a model heterostructure for a Mott insulator sandwiched between two band insulators, motivated by SrTiO${}_{3}$/LaTiO${}_{3}$. Particular emphasis is given on the interplay between magnetism and inhomogeneous charge distributions. Our mean-field analysis of the generalized Hubbard mod…

Magnetic and transport properties of perovskites and related materialsAdvanced Condensed Matter PhysicsElectronic and Structural Properties of Oxides

Coumarin‐Based Octopamine Phototriggers and their Effects on an Insect Octopamine Receptor

Janina Schaal、Brigitte Dekowski、Burkhard Wiesner 等 12 位作者2012-06-06ChemBioChem

We have developed and characterized efficient caged compounds of the neurotransmitter octopamine. For derivatization, we introduced [6-bromo-8-(diethylaminomethyl)-7-hydroxycoumarin-4-yl]methoxycarbonyl (DBHCMOC) and {6-bromo-7-hydroxy-8-[(piperazin-1-yl)methyl]coumarin-4-yl}methoxycarbonyl (PBHCMOC) moieties as novel…

Neurobiology and Insect Physiology ResearchPhotochromic and Fluorescence Chemistrybioluminescence and chemiluminescence research

Influence of X-ray opaque BaSO4 nanoparticles on the mechanical, thermal and rheological properties of polyoxymethylene nanocomposites

Issis C. Romero‐Ibarra、Elizabeth Bonilla-Blancas、Antonio Sánchez-Solís 等 4 位作者2012-06-06Journal of Polymer Engineering

Abstract This work evaluates the influence of a radiopaque reinforcement, barium sulfate (BaSO4), on the mechanical, rheological and thermal properties of polyoxymethylene (POM). Nanocomposites of POM containing spherical nanoparticles of BaSO4 (0, 1, 2, 3 phr) were obtained by melt extrusion in a twin-screw equipment…

Polymer Nanocomposites and Propertiesbiodegradable polymer synthesis and propertiesMaterial Properties and Applications

Magnetic structure of quasi-one-dimensional antiferromagnetic TaFe 1+y Te 3

Xianglin Ke、Bin Qian、Huibo Cao 等 6 位作者2012-06-06Physical Review B

We report the magnetic structure of TaFe${}_{1+y}$Te${}_{3}$ single crystals by means of neutron diffraction measurements. TaFe${}_{1+y}$Te${}_{3}$ possesses a layered structure with a formation of two-leg zigzag ladders along the $b$ axis. We find that TaFe${}_{1+y}$Te${}_{3}$ undergoes an antiferromagnetic transitio…

Physics of Superconductivity and MagnetismRare-earth and actinide compoundsIron-based superconductors research

Cooling effect of nanoscale Bi2Te3/Sb2Te3 multilayered thermoelectric thin films

Mardecial Hines、Joshua Lenhardt、Ming Lu 等 5 位作者2012-06-06Journal of Vacuum Science & Technology A Vacuum Surfaces and Films

Managing high heat flux is one of the greatest technical challenges the integrated circuit (IC) industry is facing because the rising temperature limits device minimization and decreases its lifetime. In this paper, we report the characterization of the cooling effect of nanoscale Bi2Te3/Sb2Te3 multilayered thin films…

Advanced Thermoelectric Materials and DevicesAdvanced Thermodynamics and Statistical MechanicsThermal Radiation and Cooling Technologies

Upgrading the adhesion properties of a fast‐curing epoxy using hydrophilic/hydrophobic hyperbranched poly(amidoamine)s

Hisham Essawy、Heba A. Mohamed、Nadia H. Elsayed2012-06-06Journal of Applied Polymer Science

Abstract A homologous series of hyperbranched polymers (HBPs) was prepared following a well‐defined method and their formation in a polymeric form bearing different extents of branching with amine functional groups at the terminals was verified using different techniques such as Fourier Transform Infrared, 1H Nuclear…

Epoxy Resin Curing ProcessesDendrimers and Hyperbranched PolymersSynthesis and properties of polymers

Evolution and Control of Complex Curved Form in Simple Inorganic Precipitation Systems

Matthias Kellermeier、Josef Eiblmeier、Emilio Melero‐García 等 6 位作者2012-06-06Crystal Growth & Design

Crystal architectures delimited by sinuous boundaries and exhibiting complex hierarchical structures are a common product of natural biomineralization. However, related forms can also be generated in purely inorganic environments, as exemplified by the existence of so-called “silica-carbonate biomorphs”. These peculia…

Paleontology and Stratigraphy of FossilsCalcium Carbonate Crystallization and InhibitionDiatoms and Algae Research

Effect of chemical structure and preparation process on the aggregation structure and properties of polyimide film

Ying Wang、Yang Yang、Zhenxing Jia 等 5 位作者2012-06-06Journal of Applied Polymer Science

Abstract In this article, polyimide (PI) films were fabricated via the three‐step method including the reactions of condensation polymerization, chemical imidization, and thermal imidization. In comparison with the conventional two‐step method to produce PI films, there was an additional step in the present method, i.…

Epoxy Resin Curing ProcessesSynthesis and properties of polymersTribology and Wear Analysis

The temperature‐sensitive luminescence of (Y,Gd)VO4:Bi3+,Eu3+ and its application for stealth anti‐counterfeiting

Lei Chen、Yao Zhang、Anqi Luo 等 8 位作者2012-06-06physica status solidi (RRL) - Rapid Research Letters

Abstract Anti‐counterfeiting technologies are desired to protect products far away from the violation of dummy, fake and shoddy goods. The phosphor of (Y,Gd)VO4:Bi3+,Eu3+ was synthesized for the application of this purpose. Its photoluminescence was investigated by exciting with different wavelengths at variant temper…

Luminescence Properties of Advanced MaterialsGas Sensing Nanomaterials and SensorsLuminescence and Fluorescent Materials

Suspended hybrid films assembled from thiol-capped gold nanoparticles

Yuxin Zhang、Ming Huang、Xiaodong Hao 等 6 位作者2012-06-06Nanoscale Research Letters

In this work, we explored the formation processes of suspended hybrid thin films of thiol-capped Au nanoparticles (AuNPs) inside metal oxide tubular structures. We found that a balance between in-film interactions of the AuNPs and boundary interactions with metal oxides is a key in making these special organic-inorgan…

Gold and Silver Nanoparticles Synthesis and ApplicationsQuantum Dots Synthesis And PropertiesNanocluster Synthesis and Applications