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Band-gap engineering withHfSxSe2−x

Christof Gaiser、Thorsten Zandt、A. Krapf 等 6 位作者2004-02-17Physical Review B

The band gaps of ${\mathrm{HfS}}_{2}$ (1.96 eV) and ${\mathrm{HfSe}}_{2}$ (1.13 eV) cover the range of ideal band gaps for photovoltaic applications which is for a single-junction cell about 1.45 eV and for a two-junction cell about 1.1 eV and 1.8 eV. Additionally, in favor of applications the transition-metal dichalc…

2D Materials and ApplicationsChalcogenide Semiconductor Thin FilmsMXene and MAX Phase Materials

Preparation and properties of silylated PTFE/SiO2 organic–inorganic hybrids via sol–gel process

Yung‐Chih Chen、Chi‐Che Tsai、Yu‐Der Lee2004-02-17Journal of Polymer Science Part A Polymer Chemistry

Abstract A study on poly(tetrafluoroethylene) (PTFE) reinforced with tetraethoxysilanes (TEOS) derived SiO 2 is described. It included the manufacturing process of SiO 2 ‐reinforced PTFE and the effects of silylation agent on the properties of the hybrid material, such as porosity, hydrophobic, thermal resistance, die…

Polymer Nanocomposites and PropertiesDielectric materials and actuatorsSilicone and Siloxane Chemistry

Origin of the excess wing and slowβrelaxation of glass formers: A unified picture of local orientational fluctuations

Hajime Tanaka2004-02-17Physical Review E

Here we consider the relation between the excess wing and the slow beta relaxation, focusing on the degree of the coupling between cooperative rotational motion associated with creation and annihilation of metastable islands (alpha mode) and local rotational jump motion in a cage (slow beta mode). For a strongly coupl…

Material Dynamics and PropertiesTheoretical and Computational PhysicsNonlinear Dynamics and Pattern Formation

Properties of amine‐containing coatings prepared by plasma polymerization

A. Choukourov、Hynek Biederman、И. В. Холодков 等 6 位作者2004-02-17Journal of Applied Polymer Science

Abstract Two monomers, ethylenediamine (EDA) and diaminocyclohexane (DACH), were plasma‐polymerized in continuous‐wave (CW) and pulse modes. The influence of different plasma parameters on the deposition rate and film composition were investigated in detail and the changes in aminofunctionalization with varying pulse…

Surface Modification and SuperhydrophobicityMetal and Thin Film MechanicsDiamond and Carbon-based Materials Research

Sonoluminescence Quenching of Organic Compounds in Aqueous Solution: Frequency Effects and Implications for Sonochemistry

Gareth J. Price、Muthupandian Ashokkumar、Franz Grieser2004-02-17Journal of the American Chemical Society

Solute-induced quenching of sonoluminescence (SL) is reported for aqueous solutions of two homologous series of methyl esters and ketones using low (20 kHz) and high (515 kHz) ultrasound frequencies. SL data at 20 kHz from aqueous solutions containing alcohols and carboxylic acids are also presented to compare with pr…

Ultrasound and Hyperthermia ApplicationsUltrasound and Cavitation PhenomenaPhotoacoustic and Ultrasonic Imaging

Dissipation in foam flowing through narrow channels

Isabelle Cantat、Norbert Kern、Renaud Delannay2004-02-17Europhysics Letters (EPL)

We present measurements on simple foam structures flowing through a narrow channel. Driving pressure and bubble velocity are found to be related by a power law with exponent 2/3, thus extending this relationship from single bubble trains (see Bretherton F. P., J. Fluid Mech. 10 (1961) 166) to more complicated foam str…

Enhanced Oil Recovery TechniquesPickering emulsions and particle stabilizationCharacterization and Applications of Magnetic Nanoparticles

Tuning Polymer Nanocomposite Morphology: AC Electric Field Manipulation of Epoxy–Montmorillonite (Clay) Suspensions

Hilmar Koerner、J. David Jacobs、D. W. Tomlin 等 5 位作者2004-02-17Advanced Materials

AC electric field alignment (see Figure) offers a route to composite films with unusual physical properties, in numerous geometries and applicable to a wide range of organically modified layered silicates. Exchangeable organic cations on the aluminosilicate surface are suspected to cause the induced dipole. Orientatio…

Polymer Nanocomposites and PropertiesSurfactants and Colloidal SystemsElectrowetting and Microfluidic Technologies

Synthesis of TiO2 Nanoparticles Utilizing Hydrated Reverse Micelles in CO2

Kwon Taek Lim、Ha Soo Hwang、Won Ryoo 等 4 位作者2004-02-17Langmuir

Titanium dioxide nanoparticles were produced by the controlled hydrolysis of titanium tetraisopropoxide (TTIP) in the presence of reverse micelles formed in CO2 with the surfactants ammonium carboxylate perfluoropolyether (PFPECOO-+NH4) (Mw = 587) and poly(dimethyl amino ethyl methacrylate-block-1H,1H,2H,2H-perfluoroo…

Catalytic Processes in Materials ScienceCarbon Dioxide Capture TechnologiesCatalysis and Oxidation Reactions

Synthesis of Vinyl Polymer−Silica Colloidal Nanocomposites Prepared Using Commercial Alcoholic Silica Sols

M. J. Percy、Javier I. Amalvy、David P. Randall 等 6 位作者2004-02-17Langmuir

The surfactant-free synthesis of vinyl polymer-silica nanocomposite particles has been achieved in aqueous alcoholic media at ambient temperature in the absence of auxiliary comonomers. Styrene, methyl methacrylate, methyl acrylate, n-butyl acrylate, and 2-hydroxypropyl methacrylate were homopolymerized in turn in the…

Polymer Nanocomposites and Propertiesbiodegradable polymer synthesis and propertiesSilicone and Siloxane Chemistry

Property Influence of Polyanilines on Photovoltaic Behaviors of Dye-Sensitized Solar Cells

Shuxin Tan、Jin Zhai、Bofei Xue 等 8 位作者2004-02-17Langmuir

The influence of polyanilines (PANIs) as hole conductors on the photovoltaic behaviors of dye-sensitized solar cells is studied. The current-voltage (I-V) characteristics and the incident photon to current conversion efficiency (IPCE) curves of the devices are determined as the function of different conductivities and…

TiO2 Photocatalysis and Solar CellsElectrochemical sensors and biosensorsConducting polymers and applications

Thermoplastic olefin/clay nanocomposites: Morphology and mechanical properties

S. Mehta、Francis M. Mirabella、Karl Rufener 等 4 位作者2004-02-17Journal of Applied Polymer Science

Abstract Thermoplastic olefin (TPO)/clay nanocomposites were made with clay loadings of 0.6–6.7 wt %. The morphology of these TPO/clay nanocomposites was investigated with atomic force microscopy, transmission electron microscopy (TEM), and X‐ray diffraction. The ethylene–propylene rubber (EPR) particle morphology in…

Polymer crystallization and propertiesPolymer Nanocomposites and Propertiesbiodegradable polymer synthesis and properties

Shape Memory of Hydrogen-Bonded Polymer Network/Poly(ethylene glycol) Complexes

Guoqin Liu、Xiaobing Ding、Yiping Cao 等 5 位作者2004-02-17Macromolecules

Because of a large difference in storage modulus below and above the glass transition temperature, poly(acrylic acid- co -methyl methacrylate)/poly(ethylene glycol) (P(AA- co -MMA)/PEG) complexes show shape memory properties with a recovery ratio of nearly reach 99%. Before the shape memory testing, it was necessary t…

Hydrogels: synthesis, properties, applicationsAdvanced Polymer Synthesis and CharacterizationPolymer composites and self-healing

Coating Carbon Nanotubes with Rare Earth Oxide Multiwalled Nanotubes

Liangjie Fu、Zhimin Liu、Y. Q. Liu 等 8 位作者2004-02-17Advanced Materials

Using a simple low‐temperature chemical‐solution method , multi‐walled carbon nanotubes (MWCNTs) coated with crystalline multi‐walled europium oxide nanotubes have been successfully synthesized (see Figure). The studies conducted show that such MWCNTs provide an opportunity for synthesising various rare earth oxide na…

Carbon Nanotubes in CompositesGraphene research and applicationsSupercapacitor Materials and Fabrication

Large-scale synthesis of single-walled carbon nanohorns by submerged arc

H Wang、Manish Chhowalla、Noriaki Sano 等 5 位作者2004-02-17Nanotechnology

We report on the synthesis of single-walled carbon nanohorns (SWNHs) by arc discharge between two graphite electrodes submerged in liquid nitrogen. The product in its powder form was found to consist of spherical aggregates with sizes in the range of 50–100 nm. The nanohorns are characterized by transmission electron…

Carbon Nanotubes in CompositesGraphene research and applicationsDiamond and Carbon-based Materials Research

Assembly of Gold Nanoparticles into Fibrous Aggregates Using Thiol‐Terminated Gelators

Mutsumi Kimura、Satoshi KOBAYASHI、Takashi Kuroda 等 5 位作者2004-02-17Advanced Materials

Gold nanoparticles are organized into a three‐dimensional network structure using a newly designed thiol‐terminated organic gelator. Gold nanoparticles have been covalently linked with supramolecular nanoscopic fibers, in which the gelators have been assembled by intermolecular hydrogen bonding. The Figure shows fibro…

Gold and Silver Nanoparticles Synthesis and ApplicationsSupramolecular Self-Assembly in MaterialsNanocluster Synthesis and Applications

Growth and Field-Emission Properties of Vertically Aligned Cobalt Nanowire Arrays

L. Vila、P. Vincent、L. Dauginet-De Pra 等 12 位作者2004-02-17Nano Letters

We present the fabrication of vertically aligned cobalt nanowire arrays on planar surfaces as well as preliminary field-emission (FE) experiments using them as cold electron cathodes. These arrays are obtained by electrodeposition into nanoporous templates on Au/Ti/Si substrates at very low temperature (<100 °C). Afte…

Magnetic properties of thin filmsSemiconductor materials and devicesAnodic Oxide Films and Nanostructures

Tough Nanostructured Metals at Cryogenic Temperatures

Y. M. Wang、E. Ma、Р. З. Валиев 等 4 位作者2004-02-17Advanced Materials

Copper, titanium, and iron with grain sizes of the order of 100 nm were prepared by severe plastic deformation. At 77 K these materials offer very high yield strength coupled with high ductility, uniform tensile strains, and long‐term stability. These properties demonstrate a nanomaterials advantage for science and en…

Microstructure and mechanical propertiesMetallurgy and Material FormingMetal Alloys Wear and Properties

Response of Glass and Liquid Phases in the Vortex lattice to an external AC magnetic field at different frequencies

Massimiliano Polichetti、Maria Giuseppina Adesso、Sandro Pace2004-02-17arXiv

We individuated a method to distinguish a glass phase from a highly viscous liquid phase in a lattice of vortices, established in type-two superconductors. Our analysis is based on the study of the temperature dependence of numerically obtained 1st and 3rd harmonics curves of the AC magnetic susceptibility, by changin…

Materials Sciencecond-mat.stat-mech

Magnetization reversal process and nonlinear magneto-impedance in Cu/NiFe and Nb/NiFe composite wires

A. S. Antonov、N. A. Buznikov、A. B. Granovsky 等 7 位作者2004-02-17arXiv

The magnetization reversal of Cu/NiFe and Nb/NiFe composite wires carrying AC current is studied. The frequency spectrum of a voltage induced in a pick-up coil wound around the wire is analyzed. The frequency spectrum is shown to consist of even harmonics within a wide range of AC current amplitudes and longitudinal D…

Materials Science

Processing carbon nanotubes with holographic optical tweezers

Joseph Plewa、Evan Tanner、Daniel M. Mueth 等 4 位作者2004-02-17arXiv

We report the first demonstration that carbon nanotubes can be trapped and manipulated by optical tweezers. This observation is surprising because individual nanotubes are substantially smaller than the wavelength of light, and thus should not be amenable to optical trapping. Even so, nanotube bundles, and perhaps eve…

Materials ScienceSoft Condensed Matter