Materials Literature
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During the last decade, the exploration of nanoscale device and circuitry based on molecules has gained increasing interest. In parallel with this, considerable effort is being devoted to the development of molecular photonic/electronic materials based on various porphyrin arrays. This involves light as an input/outpu…
The active role of boric acid (H 3 BO 3 ) in enhancing the Eu 2+ photoluminescence; varying persistence times and formation of several crystalline phases of calcium aluminate system is presented. The luminescence characteristics of CaAl 2 O 4 : Eu 2+ , Nd 3+ (CA) phosphor took an immense leap forward with the addition…
The influence of single-atomic-species and oxygen-related defect termination on the electronic properties of silicon nanocrystallites covered with a complete oxide shell are studied by means of density-functional theory and the local-density approximation. The oxide shell is analyzed in more detail to study the influe…
Adsorption characteristics of cross-linked lysozyme crystals of different morphologies (tetragonal, orthorhombic, triclinic and monoclinic) were examined using four anionic dyes (fluorescein, eosin, erythrosin, and rose bengal), one zwitterionic dye (rhodamine B), and one cationic dye (rhodamine 6G). The adsorption is…
Views Icon Views Article contents Figures & tables Video Audio Supplementary Data Peer Review Share Icon Share Twitter Facebook Reddit LinkedIn Tools Icon Tools Reprints and Permissions Cite Icon Cite Search Site Citation Susana García-Martín, Ainhoa Morata-Orrantia, Myriam H. Aguirre, Miguel Á. Alario-Franco; Giant b…
Abstract Novel polyurethane insulating coatings were prepared from the reaction of glycerin‐terminated polyurethane prepolymers (GPUPs) and a blocked isocyanate curing agent (BIC). The GPUPs were prepared from the reaction of one equivalent of polycaprolactone polyol (CAPA 210) with an excess amount of 4,4′‐methylene…
The surface properties of silica particles significantly influence their efficiency in particle-assisted wetting. A series of small particles of controlled surface hydrophobicity was mixed with a nonvolatile oil. These mixtures were applied onto a water surface; the structures formed were subsequently solidified by ph…
Abstract A new formalism allowing solution of the differential equations for kinetic systems comprising three species (ABC) linked by first‐order thermal and/or photochemical reactions is proposed. The approach is developed specifically with photochromic materials in mind, but the formalism developed is shown to be ap…
ADVERTISEMENT RETURN TO ISSUEPREVNoteNEXTThermally Induced Helical Conformational Change in Poly(aryl isocyanide)s with Optically Active Ester GroupsFumie Takei, Kiyotaka Onitsuka, and Shigetoshi TakahashiView Author Information The Institute of Scientific and Industrial Research, Osaka University, 8-1 Mihogaoka, Ibar…
Single-walled carbon nanotubes (SWNTs) are a new class of highly promising nanomaterials for future nano-electronics. Here, we present an initial investigation of the feasibility of using SWNT field effect transistors (SWNT-FETs) formed on silicon-oxide substrates and suspended FETs for radiation dosimetry application…
X-ray diffraction and density measurements have been simultaneously performed to investigate the atomic structure of molten silicon in a wide temperature range including the undercooling region by using the electromagnetic levitation technique. The density was obtained from the mass and the shape of a levitated sample…
Various contributions are distinguished in the experimentally detected dielectric response of organic semiconductor copper phthalocyanine. While a giant dielectric constant of virgin samples is shown to be due to extrinsic effects, the temperature dependence of the intrinsic dielectric constant, being of the order of…
Piezoelectric ultrasonic transducers are often used in well known applications such as ultrasonic cutting or cleaning processes. A novel application is the utilization of transducers in ultrasonic standing wave atomizers. Here, the transducers produce an ultrasonic field resulting in high alternating excess pressures,…
A novel synthesis method was introduced for the nanocomposites of cadmium sulfide and montmorillonite. This method features the combination of an ion exchange process and an in situ hydrothermal decomposition process of a complex precursor, which is simple in contrast to the conventional synthesis methods that compris…
Two facilities for the complete noninvasive measurement of the electrical resistivity of liquid metals above the melting temperature and in the undercooled liquid state below the melting temperature are presented: a ground-based facility that was built up in our laboratory and the microgravity facility TEMPUS. Both fa…
Abstract Summary: The unusual structure of poly(ethylene oxide) (PEO) and Laponite clay in transparent nanocomposite films was investigated using scanning electron, atomic force, and optical microscopy, and X‐ray scattering. Each method is sensitive to different aspects of structural features and together they measure…
A remetalation (a capping group exchange) reaction of the boronantimony-capped iron(II) clathrochelates with zirconium and hafnium(IV) phthalocyanines in CH2Cl2/CH3OH medium afforded the hybrid phthalocyaninoclathrochelates in a practically quantitative yield. The complexes obtained have been characterized both on the…
Views Icon Views Article contents Figures & tables Video Audio Supplementary Data Peer Review Share Icon Share Twitter Facebook Reddit LinkedIn Tools Icon Tools Reprints and Permissions Cite Icon Cite Search Site Citation Y. J. Liu, X. W. Sun, J. H. Liu, H. T. Dai, K. S. Xu; A polarization insensitive 2×2 optical swit…
We study the static properties of cubic blue phases by numerically minimizing the three-dimensional, Landau-de Gennes free energy for a cholesteric liquid crystal close to the isotropic-cholesteric phase transition. Thus we are able to refine the powerful but approximate, semianalytic frameworks that have been used pr…
Er3+ ions located 100nm beneath the surface of silica glass show an enhanced photoluminescence decay rate when the glass is covered with Ag. Correcting for concentration quenching effects, the decay rate is enhanced by 70%, compared to the case without Ag. The data are in agreement with a model that takes into account…