Materials Literature
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Materials on the scale of nanoscale have widely been used as research topics because of their interesting characteristics and aspects they bring into the field. Out of the many metal oxides, zinc oxide (ZnO) was chosen to be fabricated as nanofibers using the electrospinning method for potential uses of solar cells an…
The reduction of TiO 2 nanoparticle through interaction with H atom and characterization of resulting defect species with O 2 molecule adsorption were investigated by DFT calculations in a molecular cluster approach. The isolated cluster Ti 8 O 16 was used as a nanoparticle model. It was found that interaction between…
Abstract A series of cobalt‐free perovskite‐type cathode materials La0.6Sr0.4Fe1–xNixO3–δ (0 ≤ x ≤ 0.15) for intermediate temperature solid oxide fuel cells (IT‐SOFCs) are prepared by a citric‐nitrate process. The conductivities of the cathode materials are measured as functions of temperature (300–800 °C) in air by A…
The formation of self-assembled nanotubes is usually accounted for by anisotropic elastic properties of membranelike precursors. We present experimental data as evidence of the role played by electrostatics in the formation of self-assembled tubes in alkaline aqueous suspensions of lithocholic acid (LCA). Striking sal…
A series of group 4 metal tetracarbamates M(O(2)CNR(2))(4) (M = Ti, R = Et, 1a; M = Zr, R = Et, 1b; (i)Pr, 1c; M = Hf, R = Et, 1d; R = (i)Pr, 1e) were studied as catalytic precursors in the solution polymerization of rac-lactide. The titanium complex but not the zirconium and hafnium ones increase the activity by addi…
A high-nitrogen-concentration diamond sample was subjected to 200-keV electron irradiation using a transmission electron microscope. The optical and spin-resonance properties of the nitrogen-vacancy (NV) color centers were investigated as a function of the irradiation dose up to 6.4 × 10(21) e(-)/cm(2). The microwave…
Views Icon Views Article contents Figures & tables Video Audio Supplementary Data Peer Review Share Icon Share Twitter Facebook Reddit LinkedIn Tools Icon Tools Reprints and Permissions Cite Icon Cite Search Site Citation D. West, Y. Y. Sun, S. B. Zhang; Importance of the correct Fermi energy on the calculation of def…
The proton-conducting network in lanthanum orthophosphate, LaPO 4, has been theoretically clarified from first principles in the present study. It consists of as many as 20 kinds of migration paths with potential barriers below 1 eV, which are classified into three groups, i.e., rotations and intra- and intertetrahedr…
The X-ray line broadening technique was used to calculate the grain size of MgO at 1023, 1123, 1223 K respectively either in $CO_2$ or during the thermal decomposition of magnesites in air as well as in vacuum. By referring to the conventional grain growth equation, $D^n=kt$ , the activation energy and pre-exponential…
We report here the synthesis and characterization of four dinuclear cyanide-bridged Fe(III)-Cu(II) complexes, based on a tetra- or a pentadentate bispidine ligand (L(1) or L(2), respectively; bispidines are 3,7-diazabiyclo[3.3.1]nonane derivatives) coordinated to the Cu(II) center, and a tridentate bipyridineamide (bp…
We present systematic experimental study on the electrical response and two-phonon Raman scattering mode of graphene under small uniaxial strain. The graphene, which was initially grown by chemical vapor deposition, was transferred to a transparent-flexible-polyethylene-terephthalate substrate. It was found that the e…
This paper presents the concept, design, optimization, and experimental analysis of a biologically inspired wet shape memory alloy (SMA) actuated pump for robotic and mechatronic systems. Just as the human heart provides energy to the muscles in the body, the robotic SMA pump distributes thermofluidic energy to arrays…
PURPOSE: Pyrrole-imidazole (Py-Im) polyamides are programmable, sequence-specific DNA minor groove-binding ligands. Previous work in cell culture has shown that various polyamides can be used to modulate the transcriptional programs of oncogenic transcription factors. In this study, two hairpin polyamides with demonst…
Reaction of the half-sandwich complexes M(III)(Pc)(acac) (M = La, Eu, Y, Lu; Pc = phthalocyaninate; acac = acetylacetonate) with the metal-free N-confused 5,10,15,20-tetrakis[(4-tert-butyl)phenyl]porphyrin (H(2)NTBPP) or its N2-position methylated analogue H(CH(3))NTBPP in refluxing 1,2,4-trichlorobenzene (TCB) led to…
The blossoming of interest in colloids and nanoparticles has given renewed impulse to the study of hard-body systems. In particular, hard spheres have become a real test system for theories and experiments. It is therefore necessary to study the complex dynamics of such systems in presence of a solvent; disregarding h…
The quantum Hall effect is universal and expected to occur in all two-dimensional electron systems in perpendicular high-magnetic field. We revisit quantum localization thanks to the high-energy scale of the quantum Hall effect in graphene, where the electron dynamics obey the Dirac equation. We solve a long debated q…
Abstract Concerns about the environmental impact of chemical transformations prompted chemists to develop clean chemical processes using water as a solvent. Although appropriate for small partially water‐soluble molecules, these processes do not allow for the transformation of hydrophobic substrates due to the mass tr…
Enzymatic synthesis of doped polypyrrole (PPy) complexes using oxidoreductases (specifically peroxidases) is very well established "green" methods for producing conducting polypyrrole. The importance of this approach is realized by the numerous potential opportunities of using PPy in biological applications. However,…
A bilayer graphene nanoribbon based strain sensor is designed and investigated via first principles simulations. The interlayer sliding induces dramatically oscillation of current in order of several magnitudes. Electronic structure analysis attributes this oscillation of current to periodic variation of HOMO-LUMO gap…
High-quality yttrium iron garnet (YIG) thin films were grown on a sandwich structure that consisted of a thick Cu layer and two thin cladding layers. The cladding layers were high entropy alloy nitrides (HEAN) and served as barriers to prevent Cu diffusion and oxidation during the YIG deposition. The Cu and HEAN layer…