Materials Literature
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A pyrogallol (PG) and formaldehyde condensation reaction was carried out under alkaline conditions to prepare the pyrogallol–formaldehyde resol resin (PGNR). Polymerization was performed to establish the nano resin formation. Obtained nano resin was used as an adsorbent for recovery of rhodium(III) ions from chloride-…
Abstract Chalcogenidotetrelates show a rich and complex chemistry encompassing intricate structures and useful materials. A step‐wise coordination chemistry approach allows the sequential formation of multinary M/T/E anions (M = transition metal, T = tetrel, E = chalcogen) from simple T/E building blocks in solution.…
High-bandgap solar cells such as a-Si:H with a bandgap around 1.8-eV loose 50% of the incident solar energy due to transmittance of near infrared photons. Part of these photons can be converted into visible photons with a suitable upconverter and in this way can increase the photo response of solar cells in the near i…
A large refractive index difference of 0.58 is demonstrated in organic semiconductor films toward advanced optical design of organic optoelectronic devices. Efficient control of light propagation is shown by distributed Bragg reflectors (DBRs) consisting of organic semiconductor films. The DBRs also show photoconducti…
A new class of chiral microspheres (μm in size) was prepared via suspension polymerization. The microspheres were constituted by optically active helical substituted polyacetylenes, which render the microspheres with considerable optical activity according to CD and UV-vis spectroscopy measurements. The chiral microsp…
Topological insulators show unique properties resulting from massless, Dirac-like surface states that are protected by time-reversal symmetry. Theory predicts that the surface states exhibit a quantum spin Hall effect with counter-propagating electrons carrying opposite spins in the absence of an external magnetic fie…
The structural and electronic properties of three carbazole containing copolymers used in organic photovoltaic applications, poly[ N -1-octylnonyl-2,7-carbazole-alt-5,5-(4′,7′-di-2-thienyl-2′,1′,3′-benzothiadiazole)] (PCDTBT), poly[ N -1-octylnonyl-2,7-carbazole-alt-4,7-(2′,1′,3′-benzothiadiazole)] (PCBT), and poly[ N…
Three D–A alternating copolymers P1–3 with 3,7-linked 2,8-bis(alkoxy)dibenzothiophene as the donor unit and benzothiadiazole ( P1 and P2 ) or 3,4-bis(octyloxy)benzothiadiazole ( P3 ) as the acceptor unit have been designed and synthesized. P1–3 show two broad absorption peaks in the visible region, and the internal ch…
Analysis of transverse magnetic (TM) mode light extraction efficiency enhancement for AlGaN quantum wells (QWs) based deep ultraviolet (UV) light-emitting diodes (LEDs) with III-nitride micro-hemisphere and micro-dome structures on the p-type layer are studied and compared to that of the conventional deep-UV LEDs with…
Decomposition of three imidazole based model energetic systems (2-nitroimidazole, 4-nitroimidazole, and 1-methyl-5-nitroimidazole) is investigated both experimentally and theoretically. The initial decomposition mechanism for these three nitroimidazoles is explored with nanosecond energy resolved spectroscopy, and qua…
The stability of nanoscale devices is directly related to elasticity and the effect of temperature on the elasticity of thin films and nanocrystals. The elastic instability induced by rising temperature will cause the failure of integrated circuits and other microelectronic devices in service. The temperature effect o…
With recent improvements in instrumentation and computational tools, serial section electron microscopy has become increasingly straightforward. A new method for imaging ultrathin serial sections is developed based on a field emission scanning electron microscope fitted with a transmitted electron detector. This metho…
Integration of a scanning electron microscope (SEM) and focused ion beam (FIB) technology into a single FIB/SEM system permits use of the FIB as a nano-scalpel to reveal site-specific subsurface microstructures which can be examined in great detail by SEM. The FIB/SEM technology is widely used in the semiconductor ind…
Mechanically Interlocked molecules, such as catenanes and rotaxanes, are of great interest due to their fascinating structures and potential applications, while such molecules have been mainly restricted to comprising components of interlocked rings or polygons. The constructions of infinite polycatenanes and polyrota…
Abstract Indium Tin Oxide (ITO) films are widely used as transparent electrodes in electronic displays and solar cells. However, the small fracture strain of brittle ITO films poses significant challenge to their applications in flexible electronics devices that often undergo large deformation. Inspired by recent deve…
The aim of this study was to evaluate the physical and chemical parameters of Williams pear, stored at 25 ºC for 15 days, with and without edible coating. Edible coatings prepared with alginate 2% and carrageenan 0.5% were tested. The analyses carried out on the samples were: weight loss, pH, soluble solids, firmness,…
Understanding the interface between DNA and nanomaterials is crucial for rational design and optimization of biosensors and drug delivery systems. For detection and delivery into cells, where high concentrations of cellular proteins are present, another layer of complexity is added. In this context, we employ polyethy…
Near linear scaling fragment based quantum chemical calculations are becoming increasingly popular for treating large systems with high accuracy and is an active field of research. However, it remains difficult to set up these calculations without expert knowledge. To facilitate the use of such methods, software tools…
In this study, a novel three-dimensional fluffy PPy conductive fibrous scaffold (3D-cFSs) was fabricated by electrospinning technique combined with situ surface polymerization. Chemical compositions, morphology were characterized by fourier transform infrared (FTIR) and scanning electron microscopy (SEM). The results…
The magnetoresistance of a hydrogen-phthalocyanine molecule placed on an antiferromagnetic Mn(001) surface and contacted by a ferromagnetic Fe electrode is investigated using density functional theory based transport calculations and low-temperature scanning tunneling microscopy. A large and negative magnetoresistance…