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Rational Design and Nanofabrication of Gecko‐Inspired Fibrillar Adhesives

Shihao Hu、Zhenhai Xia2012-05-29Small

Gecko feet integrate many intriguing functions such as strong adhesion, easy detachment, and self-cleaning. Mimicking gecko toe pad structure leads to the development of new types of fibrillar adhesives useful for various applications. In this Concept article, in addition to the design of adhesive mimics by replicatin…

Surface Modification and SuperhydrophobicityPolymer Surface Interaction StudiesAdhesion, Friction, and Surface Interactions

Label-Free Enrichment of Functional Cardiomyocytes Using Microfluidic Deterministic Lateral Flow Displacement

Boyang Zhang、James V. Green、Shashi K. Murthy 等 4 位作者2012-05-29PLoS ONE

Progress in cardiac cell replacement therapies and tissue engineering critically depends on our ability to isolate functional cardiomyocytes (CMs) from heterogeneous cell mixtures. Label-free enrichment of cardiomyocytes is desirable for future clinical application of cell based products. Taking advantage of the physi…

Electrospun Nanofibers in Biomedical Applications3D Printing in Biomedical ResearchTissue Engineering and Regenerative Medicine

Four Low-Dimensional Cobalt(II) Coordination Polymers Based on a New Isophthalic Acid Derivative: Syntheses, Crystal Structures, and Properties

Xin-Hong Chang、Lu‐Fang Ma、Hui Guo 等 4 位作者2012-05-29Crystal Growth & Design

A isophthalic acid derivative, 5-(4′-methylphenyl)isophthalic acid (CH 3 C 6 H 4 -H 2 ip), has been prepared. Reaction of CH 3 C 6 H 4 -H 2 ip with Co(Ac) 2 ·4H 2 O and four N-donor ancillary ligands gave four new coordination polymers, {[Co(CH 3 C 6 H 4 -ip)(bip)]·2H 2 O} n ( 1 ), {[Co 2 (CH 3 C 6 H 4 -ip) 2 (bib)]·H…

Metal-Organic Frameworks: Synthesis and ApplicationsMetal complexes synthesis and propertiesMagnetism in coordination complexes

Valence band effective-mass Hamiltonians for the group-III nitrides from quasiparticle self-consistent GW band structures

Atchara Punya、Walter R. L. Lambrecht2012-05-29Physical Review B

We present band gaps, electron effective masses, and valence band effective-mass Hamiltonian parameters as well as strain deformation potentials of the crystal field splittings for AlN, GaN, and InN obtained from quasiparticle self-consistent $GW$ calculations. Excellent agreement is obtained with experimental data fo…

ZnO doping and propertiesGaN-based semiconductor devices and materialsMetal and Thin Film Mechanics

Quartz Crystal Microbalance Aptasensor for Sensitive Detection of Mercury(II) Based on Signal Amplification with Gold Nanoparticles

Zong-Mu Dong、Guang‐Chao Zhao2012-05-29Sensors

We show that a short mercury-specific aptamer (MSA) along with gold nanoparticles (Au-NPs) can be used to determine Hg(II) ion by a combination of a QCM-based sensor and a flow system. The MSA binds specifically to Hg(II), and the Au-NPs can amplify the signal to enhance sensitivity. Specifically, the short thiolated…

Gold and Silver Nanoparticles Synthesis and ApplicationsAdvanced biosensing and bioanalysis techniquesElectrochemical Analysis and Applications

Patterning of Heteroepitaxial Overlayers from Nano to Micron Scales

K. R. Elder、Giulia Rossi、P. Kanerva 等 8 位作者2012-05-29Physical Review Letters

Thin heteroepitaxial overlayers have been proposed as templates to generate stable, self-organized nanostructures at large length scales, with a variety of important technological applications. However, modeling strain-driven self-organization is a formidable challenge due to different length scales involved. In this…

Theoretical and Computational PhysicsBlock Copolymer Self-Assemblynanoparticles nucleation surface interactions

Transverse dynamics of water across the melting point: A parallel neutron and x-ray inelastic scattering study

Alessandro Cunsolo、C. N. Kodituwakku、Filippo Bencivenga 等 6 位作者2012-05-29Physical Review B

Joint inelastic neutron and x-ray scattering measurements have been performed on heavy water across the melting point. The spectra bear clear evidence of low- and high-frequency inelastic shoulders related to transverse and longitudinal modes, respectively. Upon increasing the momentum transfer, the spectral shape evo…

High-pressure geophysics and materialsMaterial Dynamics and PropertiesNMR spectroscopy and applications

Field Effects Induce Bathochromic Shifts in Xanthene Dyes

Martha Sibrian‐Vazquez、Jorge O. Escobedo、Mark Lowry 等 5 位作者2012-05-29Journal of the American Chemical Society

There is ongoing interest in near-infrared (NIR) absorbing and emitting dyes for a variety of biomedical and materials applications. Simple and efficient synthetic procedures enable the judicious tuning of through-space polar (field) effects as well as low barrier hydrogen bonding to modulate the HOMO-LUMO gap in xant…

Luminescence and Fluorescent MaterialsPhotochromic and Fluorescence ChemistryPhotoreceptor and optogenetics research

Star-Shaped Trimeric Quaternary Ammonium Bromide Surfactants: Adsorption and Aggregation Properties

Tomokazu Yoshimura、Takumi Kusano、Hiroki Iwase 等 6 位作者2012-05-29Langmuir

Novel star-shaped trimeric surfactants consisting of three quaternary ammonium surfactants linked to a tris(2-aminoethyl)amine core were synthesized. Each ammonium had two methyls and a straight alkyl chain of 8, 10, 12, or 14 carbons. The adsorption and aggregation properties of these tris(N-alkyl-N,N-dimethyl-2-ammo…

Advanced Polymer Synthesis and CharacterizationSurfactants and Colloidal SystemsPolymer Surface Interaction Studies

Cationic Porphyrins Are Reversible Proteasome Inhibitors

Anna Maria Santoro、Cristina Lo Giudice、Alessandro D’Urso 等 6 位作者2012-05-29Journal of the American Chemical Society

The aim of this study is to verify if water-soluble porphyrins can be used as proteasome inhibitors. We have found that cationic porphyrins inhibit proteasome peptidase activities much more effectively than the corresponding anionic derivatives. The relevance of electrostatics in driving porphyin-proteasome interactio…

Porphyrin and Phthalocyanine ChemistryUbiquitin and proteasome pathwaysToxoplasma gondii Research Studies

Environment-assisted quantum transport in ordered systems

Ivan Kassal、Alán Aspuru-Guzik2012-05-29New Journal of Physics

Noise-assisted transport in quantum systems occurs when quantum time evolution and decoherence conspire to produce a transport efficiency that is higher than what would be seen in either the purely quantum or purely classical cases. In disordered systems, it has been understood as the suppression of coherent quantum l…

Molecular Junctions and NanostructuresSpectroscopy and Quantum Chemical StudiesOrganic and Molecular Conductors Research

Fate of topological-insulator surface states under strong disorder

G. Schubert、Holger Fehske、Lars Fritz 等 4 位作者2012-05-29Physical Review B

Three-dimensional topological insulators feature Dirac-like surface states which are topologically protected against the influence of weak quenched disorder. Here we investigate the effect of surface disorder beyond the weak-disorder limit using large-scale numerical simulations. We find two qualitatively distinct reg…

Graphene research and applicationsTopological Materials and PhenomenaAdvanced Condensed Matter Physics

Synthesis, Spectroscopy, Thermal Analysis, Magnetic Properties and Biological Activity Studies of Cu(II) and Co(II) Complexes with Schiff Base Dye Ligands

Raziyeh Arab Ahmadi、Saeid Amani2012-05-29Molecules

Three azo group-containing Schiff base ligands, namely 1-{3-[(3-hydroxypropylimino) methyl]-4-hydroxyphenylazo}-4-nitrobenzene (2a), 1-{3-[(3-hydroxypropylimino) methyl]-4-hydroxyphenylazo}-2-chloro-4-nitrobenzene (2b) and 1-{3-[(3-hydroxypropylimino) methyl]-4-hydroxyphenylazo}-4-chloro-3-nitrobenzene (2c) were prepa…

Metal complexes synthesis and propertiesNonlinear Optical Materials ResearchProtein Interaction Studies and Fluorescence Analysis

Recent advances in mechanical characterisation of biofilm and their significance for material modelling

Markus Böl、Alexander E. Ehret、Antonio Bolea Albero 等 5 位作者2012-05-29Critical Reviews in Biotechnology

In recent years, the advances in microbiology show that biofilms are structurally complex, dynamic and adaptable systems including attributes of multicellular organisms and miscellaneous ecosystems. One may distinguish between beneficial and harmful biofilms appearing in daily life as well as various industrial proces…

Bacterial biofilms and quorum sensingBacteriophages and microbial interactionsCalcium Carbonate Crystallization and Inhibition

The Significance of Ionic Bonding in Sulfur Dioxide: Bond Orders from X‐ray Diffraction Data

Simon Grabowsky、Peter Luger、J. Buschmann 等 7 位作者2012-05-29Angewandte Chemie International Edition

A novel refinement technique for X-ray diffraction data has been employed to derive SO bond orders in sulfur dioxide experimentally. The results show that ionic SO bonding dominates over hypervalency.

Crystallography and molecular interactionsSolid-state spectroscopy and crystallographyThermal and Kinetic Analysis

Nanostructured p‐n Junctions for Kinetic‐to‐Electrical Energy Conversion

Joe Briscoe、Mark Stewart、Melvin M. Vopson 等 6 位作者2012-05-29Advanced Energy Materials

Abstract Piezoelectric ZnO nanorods grown on a flexible substrate are combined with the p‐type semiconducting polymer PEDOT:PSS to produce a p‐n junction device that successfully demonstrates kinetic‐to‐electrical energy conversion. Both the voltage and current output of the devices are measured to be in the range of…

ZnO doping and propertiesAdvanced Sensor and Energy Harvesting MaterialsConducting polymers and applications

Tuning the Electrical Memory Characteristics from Volatile to Nonvolatile by Perylene Imide Composition in Random Copolyimides

Tadanori Kurosawa、Yi‐Cang Lai、Tomoya Higashihara 等 6 位作者2012-05-29Macromolecules

Random copolyimides, PI–PBIX, with different compositions of 4,4′-(hexafluoroisopropylidene)diphthalic anhydride ( 6FDA ), N, N ′-bis(4-aminophenyl)-3,4,9,10-perylenebis(dicarboximide) ( PBI ), and 4,4′-diamino-4″-methyltriphenylamine ( AMTPA ) were designed and synthesized for resistive-switching memory device applic…

Perovskite Materials and ApplicationsAdvanced Memory and Neural ComputingConducting polymers and applications

Medium-Frequency Induction Melting Furnace as a Load on the Power System

İlker Yılmaz、Muammer Ermiş、I. Çadırcı2012-05-29IEEE Transactions on Industry Applications

The variable-frequency operation of the coreless induction melting furnace (IMF) has been investigated in detail both theoretically and experimentally. The time variations of the operational impedance value of the IMF, owing to the time-varying resonance frequency and crucible conditions, have been derived for typical…

Magnetic Properties and ApplicationsInduction Heating and Inverter Technology

Biosupramolecular Nanowires from Chlorophyll Dyes with Exceptional Charge‐Transport Properties

Sanchita Sengupta、Daniel Ebeling、Sameer Patwardhan 等 15 位作者2012-05-29Angewandte Chemie International Edition

Conductive tubes: Self-assembled nanotubes of a bacteriochlorophyll derivative are reminiscent of natural chlorosomal light-harvesting assemblies. After deposition on a substrate that consists of a non-conductive silicon oxide surface (see picture, brown) and contacting the chlorin nanowires to a conductive polymer (y…

Photosynthetic Processes and MechanismsPorphyrin and Phthalocyanine ChemistryPhotoreceptor and optogenetics research

A Novel Photoanode with Three‐Dimensionally, Hierarchically Ordered Nanobushes for Highly Efficient Photoelectrochemical Cells

Siva Krishna Karuturi、Jingshan Luo、Chuanwei Cheng 等 7 位作者2012-05-29Advanced Materials

A 3D hierarchically ordered nanobush structure is fabricated for use as a photoanode in photoelectrochemical cells. The photoanode structure has several favorable intrinsic characteristics, including high interface area, direct electron transport pathways, and engineered light scattering centers. Sensitization with Cd…

Advanced Photocatalysis TechniquesQuantum Dots Synthesis And PropertiesTransition Metal Oxide Nanomaterials