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Simulation and modelling of slip flow over surfaces grafted with polymer brushes and glycocalyx fibres

Mingge Deng、Xuejin Li、Haojun Liang 等 5 位作者2012-09-03Journal of Fluid Mechanics

Abstract Fabrication of functionalized surfaces using polymer brushes is a relatively simple process and parallels the presence of glycocalyx filaments coating the luminal surface of our vasculature. In this paper, we perform atomistic-like simulations based on dissipative particle dynamics (DPD) to study both polymer…

Surfactants and Colloidal SystemsPolymer Surface Interaction StudiesBlood properties and coagulation

Electronic structure of graphene oxide and reduced graphene oxide monolayers

D.S. Sutar、Gulbagh Singh、V. Divakar Botcha2012-09-03Applied Physics Letters

Graphene oxide (GO) monolayers obtained by Langmuir Blodgett route and suitably treated to obtain reduced graphene oxide (RGO) monolayers were studied by photoelectron spectroscopy. Upon reduction of GO to form RGO C1s x-ray photoelectron spectra showed increase in graphitic carbon content, while ultraviolet photoelec…

Carbon Nanotubes in CompositesGraphene research and applicationsMolecular Junctions and Nanostructures

Evidence for ferromagnetic strain glass in Ni-Co-Mn-Ga Heusler alloy system

Yu Wang、Chonghui Huang、Jinghui Gao 等 7 位作者2012-09-03Applied Physics Letters

We report that both a strain glass transition and a ferromagnetic transition take place in a Ni43Co12Mn20Ga25 Heusler alloy. This results in a ferromagnetic strain glass with coexisting short range strain ordering and long range magnetic moment ordering. The phase diagram of the Ni-Co-Mn-Ga system shows that the subst…

Shape Memory Alloy TransformationsMagnetic Properties and ApplicationsMagnetic Properties of Alloys

Making a Robust Interfacial Scaffold: Bijel Rheology and its Link to Processability

Matthew N. Lee、Job H. J. Thijssen、Jessica A. Witt 等 5 位作者2012-09-03Advanced Functional Materials

Abstract Confocal microscopy and rheology studies of two bijel systems are presented to elucidate relationships between the physicochemical properties of bijels and their ability to be utilized as soft matter templates for materials synthesis. For the first time, the origins of viscoelasticity in these systems are inv…

Advanced Materials and MechanicsPickering emulsions and particle stabilizationPolysaccharides Composition and Applications

Bio‐Inspired Synthesis of Minerals for Energy, Environment, and Medicinal Applications

Sungjin Kim、Chan Beum Park2012-09-03Advanced Functional Materials

Abstract Biomineralization, the natural pathway of assembling biogenic inorganic compounds, inspires us to exploit unique, effective strategies to fabricate functional materials with intricate structures. In this article, the recent advances in bio‐inspired synthesis of minerals—with a focus on those of calcium‐based…

Bone Tissue Engineering MaterialsPaleontology and Stratigraphy of FossilsCalcium Carbonate Crystallization and Inhibition

Composite reinforcement by oxide TiO 2

Mehrdad Soltani、Seid Abbas Hoseininejad2012-09-03Science and Engineering of Composite Materials

Abstract This composite has been developed by solidification processing by the addition of 0.5–3. 5 wt% powders of oxide TiO 2 to molten Al-Cu alloy. The dry sliding wear behavior of pins of cast composite, fabricated by the solidification of the melt-particle slurry in mold, has been determined by pin-on-disc wear te…

Advanced ceramic materials synthesisAluminum Alloys Composites PropertiesAdvanced materials and composites

Room-temperature Magnetic Ordering in Functionalized Graphene

Jeongmin Hong、Elena Bekyarova、Ping Liang 等 6 位作者2012-09-03Scientific Reports

Despite theoretical predictions, the question of room-temperature magnetic order in graphene must be conclusively resolved before graphene can fully achieve its potential as a spintronic medium. Through scanning tunneling microscopy (STM) and point I-V measurements, the current study reveals that unlike pristine sampl…

Graphene research and applicationsQuantum and electron transport phenomenaMolecular Junctions and Nanostructures

Low Temperature Synthesis, Structural, Optical and Magnetic Properties of Bismuth Ferrite Nanoparticles

Simant Kumar Srivastav、N. S. Gajbhiye2012-09-03Journal of the American Ceramic Society

Phase pure nanosized BiFeO 3 ( BFO ) powder was synthesized by sol–gel method based on the propylene glycol‐gel reaction. The formation mechanism, crystal structure, magnetic and optical properties were investigated by thermogravimetry, differential thermal analysis, infrared spectroscopy, X –ray diffractometry, Rietv…

Multiferroics and related materialsMagnetic Properties and Synthesis of FerritesDielectric properties of ceramics

Dynamic Understanding of Human-Skin Movement and Strain-Field Analysis

Ashley M. Wessendorf、Dava Newman2012-09-03IEEE Transactions on Biomedical Engineering

Understanding the skin's material properties and natural motion is critical to a myriad of applications from tissue engineering to spacesuits. While there is an extensive understanding of human skin properties based on active tensile testing, both in vitro and in vivo, there is a little current knowledge of the strain…

Advanced Sensor and Energy Harvesting MaterialsTextile materials and evaluationsSpaceflight effects on biology

Synthesis and Characterization of Alkyl‐Imidazolium‐Based Periodic Mesoporous Organosilicas: A Versatile Host for the Immobilization of Perruthenate (RuO 4 − ) in the Aerobic Oxidation of Alcohols

Babak Karimi、Dawood Elhamifar、Omolbanin Yari 等 7 位作者2012-09-03Chemistry - A European Journal

The preparation and characterization of a set of periodic mesoporous organosilicas (PMOs) that contain different fractions of 1,3-bis(3-trimethoxysilylpropyl)imidazolium chloride (BTMSPI) groups uniformly distributed in the silica mesoporous framework is described. The mesoporous structure of the materials was charact…

Mesoporous Materials and CatalysisPolyoxometalates: Synthesis and ApplicationsOxidative Organic Chemistry Reactions

Investigation of the processing, the mechanical properties, and the morphology of short glass fiber-reinforced polypropylene-layered silicate composites

Christian Hopmann、Walter Michaeli、Florian Puch2012-09-03Science and Engineering of Composite Materials

Abstract Polypropylene composites containing layered silicate and glass fibers are prepared by melt compounding. To investigate the influence of the processing conditions on the mechanical properties and the morphology of short glass fiber-reinforced polypropylene-layered silicate composites, the process parameters ar…

Polymer Nanocomposites and PropertiesNatural Fiber Reinforced CompositesInnovative concrete reinforcement materials

Morphology dependence of radial elasticity in multiwalled boron nitride nanotubes

Hsiang‐Chih Chiu、Sumin Kim、Christian Klinke 等 4 位作者2012-09-03Applied Physics Letters

We report on the measurement of the radial modulus of boron nitride nanotubes (BN-NTs) with various sizes and thicknesses. These BN-NTs are radially much stiffer than previously reported thinner and smaller BN-NTs. Here, we show the key role of the morphology of the nanotubes in determining their radial rigidity; in p…

Graphene research and applications2D Materials and ApplicationsBoron and Carbon Nanomaterials Research

Conduction mechanisms of epitaxial EuTiO3 thin films

R. Zhao、W. W. Li、L. Chen 等 9 位作者2012-09-03Applied Physics Letters

To investigate leakage current density versus electric field characteristics, epitaxial EuTiO3 thin films were deposited on (001) SrTiO3 substrates by pulsed laser deposition and were post-annealed in a reducing atmosphere. This investigation found that conduction mechanisms are strongly related to temperature and vol…

Ferroelectric and Piezoelectric MaterialsMultiferroics and related materialsElectronic and Structural Properties of Oxides

Temperature dependent graphene suspension due to thermal Casimir interaction

Anh D. Phan、Lilia M. Woods、D. Drosdoff 等 5 位作者2012-09-03arXiv

Thermal effects contributing to the Casimir interaction between objects are usually small at room temperature and they are difficult to separate from quantum mechanical contributions at higher temperatures. We propose that the thermal Casimir force effect can be observed for a graphene flake suspended in a fluid betwe…

Mesoscale and Nanoscale PhysicsMaterials Sciencequant-ph

Strain induced lithium functionalized graphane as a high capacity hydrogen storage material

Tanveer Hussain、Abir De Sarkar、Rajeev Ahuja2012-09-03Applied Physics Letters

Strain effects on the stability, electronic structure, and hydrogen storage capacity of lithium-doped graphane have been investigated by state-of-the-art first principles density functional theory. Molecular dynamics simulations have confirmed the stability of Li on graphane sheet when it is subject to 10% of tensile…

Advancements in Battery MaterialsGraphene research and applicationsHydrogen Storage and Materials

Excellent magnetocaloric properties of melt-extracted Gd-based amorphous microwires

N. S. Bingham、Hai Wang、Faxiang Qin 等 8 位作者2012-09-03Applied Physics Letters

We report upon the excellent magnetocaloric properties of Gd53Al24Co20Zr3 amorphous microwires. In addition to obtaining the large magnetic entropy change (−ΔSM ∼ 10.3 J/kg K at TC ∼ 95 K), an extremely large value of refrigerant capacity (RC ∼ 733.4 J/kg) has been achieved for a field change of 5 T in an array of for…

Magnetic and transport properties of perovskites and related materialsShape Memory Alloy TransformationsMagnetic Properties of Alloys

Positive and negative exchange bias effects in the simple perovskite manganite NdMnO3

Fang Hong、Zhenxiang Cheng、Jianli Wang 等 5 位作者2012-09-03Applied Physics Letters

Exchange bias effects were studied in the simple perovskite NdMnO3. Nd3+ ordering is induced by the Mn3+ ferromagnetic component, and they are antiferromagnetically coupled with each other. At 30 K, both negative and positive exchange bias effects are found, which are dependent on the cooling field. The exchange bias…

Magnetic and transport properties of perovskites and related materialsMultiferroics and related materialsAdvanced Condensed Matter Physics

Metal Carbonyl–Gold Nanoparticle Conjugates for Live‐Cell SERS Imaging

Kien Voon Kong、Zhiyong Lam、Wenda Douglas Goh 等 5 位作者2012-09-03Angewandte Chemie International Edition

Conjugates of organometallic osmium carbonyl clusters and gold nanoparticles show a strong carbonyl signal in surface-enhanced Raman spectroscopy. The ease of bio-functionalization and the high stability and good dispersibility in aqueous solution make these conjugates excellent candidates for biomedical applications,…

Gold and Silver Nanoparticles Synthesis and ApplicationsAdvanced biosensing and bioanalysis techniquesNanocluster Synthesis and Applications

Synthesis of new polyester polyols from epoxidized vegetable oils and biobased acids

Sylvain Caillol、Myriam Desroches、Gilles Boutevin 等 6 位作者2012-09-03European Journal of Lipid Science and Technology

Abstract Biobased polyols were synthesized from reaction between epoxidized soybean oil and lactic, glycolic, or acetic acids. Polyols were characterized by NMR, alcohol and acid titration, and SEC. These analyses allowed to determine an average hydroxyl functionality between 4 and 5, with an oligomer content close to…

biodegradable polymer synthesis and propertiesPolymer composites and self-healingCarbon dioxide utilization in catalysis

Formation and control of wrinkles in graphene by the wedging transfer method

V. E. Calado、Grégory F. Schneider、A.M.M.G. Theulings 等 5 位作者2012-09-03Applied Physics Letters

We study the formation of wrinkles in graphene upon wet transfer onto a hydrophilic target substrate, whereby draining of water appears to play an important role. We are able to control the orientation of the wrinkles by tuning the surface morphology. Wrinkles are absent in flakes transferred to strongly hydrophobic s…

Graphene research and applicationsAdvanced Sensor and Energy Harvesting MaterialsAdvanced Materials and Mechanics