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Metal‐Fluorocarbon Pyrolants. XIV: High Density‐High Performance Decoy Flare Compositions Based on Ytterbium/Polytetrafluoroethylene/Viton®

Ernst‐Christian Koch、Arno Hahma2012-03-08Zeitschrift für anorganische und allgemeine Chemie

Abstract Three pyrotechnic compositions based on ytterbium /polytetrafluoroethylene/Viton® (YTV) 77/18/5, 82/13/5 and 87/8/5 wt.‐% were compared to a baseline magnesium /polytetrafluoroethylene/Viton® (MTV) 60/35/5 wt.‐% composition. YTV though energetically inferior to MTV both gravimetrically and volumetrically exhi…

Combustion and Detonation ProcessesStructural Response to Dynamic LoadsSilicone and Siloxane Chemistry

A novel Co(phen)2/C catalyst for the oxygen electrode in rechargeable lithium air batteries

Hong Wang、Xiao‐Zhen Liao、Qi-Zhong Jiang 等 6 位作者2012-03-08Chinese Science Bulletin

A novel Co(phen) 2 /C catalyst was prepared by coating cobalt(II) phenanthroline (phen) chelate on BP2000 carbon black and then heat treating in an inert atmosphere. The obtained Co(phen) 2 /C product with 1.0 wt% cobalt loading exhibits similar morphology and porosity characteristics to those of the bare BP2000. X-ra…

Advancements in Battery MaterialsSupercapacitor Materials and FabricationAdvanced Battery Materials and Technologies

ToF‐SIMS and Laser‐SNMS analysis of macrophages after exposure to silver nanoparticles

Felix Draude、S. Galla、Andreas Pelster 等 11 位作者2012-03-08Surface and Interface Analysis

Silver nanoparticles (SNPs) are among the most commercialized nanoparticles because of their antibacterial effects. Besides being employed, e.g. as a coating material for sterile surfaces in household articles and appliances, the particles are also used in a broad range of medical applications. Their antibacterial pro…

Nanoparticles: synthesis and applicationsIon-surface interactions and analysisLaser-Ablation Synthesis of Nanoparticles

Hydroxide Ion versus Chloride and Methoxide as an Exogenous Ligand Reveals the Influence of Hydrogen Bonding with Second-Sphere Coordination Water Molecules in the Electron Transfer Kinetics of Mn Complexes

Sanae El Ghachtouli、Régis Guillot、Ally Aukauloo 等 6 位作者2012-03-08Inorganic Chemistry

We recently reported on the synthesis of a new pentadentate N(4)O ligand, tBuL(-), together with the X-ray diffraction structure of the corresponding mononuclear manganese(III)-hydroxo complex namely [(tBuL)Mn(III)OH](ClO(4)), (1 (ClO(4))). [El Ghachtouli et al. Energy Environ. Sci. 2011, 4, 2041.] In the present work…

Electrocatalysts for Energy ConversionPorphyrin and Phthalocyanine ChemistryElectrochemical Analysis and Applications

Characterisation of electroless nickel plated titanium powder

K. Zangeneh-Madar、A.H. Jafari2012-03-08Surface Engineering

In this study, pure titanium powder with an average size of 20 μm was treated by electroless nickel plating to obtain titanium–nickel composite/duplex powder. Two plating procedures were applied; continuous short period (CSP) and discontinuous long period (DLP) processes. The plated titanium powder particles as well a…

Corrosion Behavior and InhibitionHigh-Temperature Coating BehaviorsElectrodeposition and Electroless Coatings

Residual stress measurement of low temperature plasma surface alloyed layer using X-ray diffraction techniques

S. Thaiwatthana、Narin Jantaping、Pimpa Limthongkul2012-03-08Surface Engineering

X-ray diffraction (XRD) techniques including stress measurement were applied to untreated, low temperature plasma nitrided and low temperature plasma carburised AISI 304 austenitic stainless steels treated at 425°C for 12 h in H2/N2 and H2/CH4 gases respectively. Relationships between surface microhardness and XRD pea…

Metal and Thin Film MechanicsDiamond and Carbon-based Materials ResearchBoron and Carbon Nanomaterials Research

Investigation on the antiferromagnetic component in the intrinsic exchange bias in structurally single phase Cr2Te3 thin film

Hui Lu、Sze Ter Lim、J. F. Bi 等 4 位作者2012-03-08Journal of Applied Physics

We report the intrinsic exchange bias in structurally single phase Cr2Te3 thin film grown by low temperature molecular beam epitaxy. The hysteresis loop shift is confirmed due to the ferromagnet/antiferromagnet coupling rather than surface spin disorder effect or minor loop effect. The AFM component attributing to the…

Magnetic properties of thin filmsMagnetic and transport properties of perovskites and related materialsMultiferroics and related materials

High-speed de-excitation system for brushless synchronous machines

Carlos A. Platero、Marta Redondo、Francisco Cuadros Blázquez 等 4 位作者2012-03-08IET Electric Power Applications

This study presents a novel high-speed de-excitation system for brushless synchronous machines, where the de-excitation time constant can reach values of several seconds. In these conditions, despite the proper operation of the protection system, the slow de-excitation time constant may produce severe damage in the ev…

Machine Fault Diagnosis TechniquesElectric Motor Design and AnalysisMagnetic Properties and Applications

Cyclodextrin-Induced Change in Crystal Habit of Acetylsalicylic Acid in Aqueous Solution

Daisuke Iohara、Kenshi Yoshida、Kohki Yamaguchi 等 8 位作者2012-03-08Crystal Growth & Design

The present work refers to a method to selectively modify the crystal habit of acetylsalicylic acid (ASA) through the use of the cyclic oligosaccharide derivatives 2-hydroxybutyl-β-cyclodextrin (HB-β-CD) and 2,6-di- O -methyl-β-cyclodextrin (DM-β-CD) as a growth inhibitor. ASA crystallized in plate crystals in solutio…

Drug Solubulity and Delivery SystemsProtein purification and stabilityCrystallization and Solubility Studies

Initial Processes of Atomic Layer Deposition of Al2O3 on InGaAs: Interface Formation Mechanisms and Impact on Metal-Insulator-Semiconductor Device Performance

Wipakorn Jevasuwan、Yuji Urabe、Tatsuro Maeda 等 10 位作者2012-03-08Materials

Interface-formation processes in atomic layer deposition (ALD) of Al₂O₃ on InGaAs surfaces were investigated using on-line Auger electron spectroscopy. Al₂O₃ ALD was carried out by repeating a cycle of Al(CH₃)₃ (trimethylaluminum, TMA) adsorption and oxidation by H₂O. The first two ALD cycles increased the Al KLL sign…

Semiconductor materials and devicesAdvanced Memory and Neural ComputingElectronic and Structural Properties of Oxides

Effects of plasma nitriding on properties of electroless Ni–B coating

Donya Ahmadkhaniha、F. Mahboubi2012-03-08Surface Engineering

In this study, the properties of nitrided electroless Ni–B coating prepared by conventional plasma nitriding (CPN), were compared with those of annealed one. For this purpose, electroless Ni–B coatings were deposited from an alkaline bath on AISI 4140 substrates. Then some of the prepared coatings were annealed under…

Corrosion Behavior and InhibitionElectrodeposition and Electroless CoatingsSemiconductor materials and interfaces

Spectroscopic and magnetic properties of Cu(II) complexes with selected biologically important ligands

Renata Świsłocka、Monika Kalinowska、Wiesława Ferenc 等 5 位作者2012-03-08Open Chemistry

Abstract The aim of this work was to study the spectroscopic and magnetic properties of copper(II) o-, m-, p-aminobenzoates, o-, m-, p-methoxybenzoates and o-, m- and p-nitrobenzoates. The complexes were synthesized and their compositions were evaluated by elementary analysis. The infrared and Raman spectra for Cu(II)…

Metal complexes synthesis and propertiesNonlinear Optical Materials ResearchFree Radicals and Antioxidants

Tribological behaviour of nanostructured Al2O3 coatings

Vinay Pratap Singh、Anjan Sil、R. Jayaganthan2012-03-08Surface Engineering

Nanostructured alumina coatings have been deposited on SS 304 substrate using atmospheric plasma spray process. In the present work, nanostructured feed powder is obtained by manual granulation of nano-Al2O3 powder particles followed by exhaustive sieving, which is helpful in their proper consolidation. The tribologic…

Metal and Thin Film MechanicsDiamond and Carbon-based Materials ResearchHigh-Temperature Coating Behaviors

Ultrasound enhanced plasma surface modification at atmospheric pressure

Yukihiro Kusano、Sudhanshu Singh、Kion Norrman 等 8 位作者2012-03-08Surface Engineering

Efficiency of atmospheric pressure plasma treatment can be highly enhanced by simultaneous high power ultrasonic irradiation onto the treating surface. It is because ultrasonic waves with a sound pressure level (SPL) above ∼140 dB can reduce the thickness of a boundary gas layer between the plasma and the material sur…

Surface Modification and SuperhydrophobicityPlasma Applications and DiagnosticsElectrospun Nanofibers in Biomedical Applications

Porosity measurement of electroless Ni–P coatings reinforced by CNT or SiC particles

Arman Zarebidaki、S-R Allahkaram2012-03-08Surface Engineering

Ni–P composite coatings containing SiC nanoparticles or carbon nanotubes (CNTs) were deposited on steel substrates via electroless plating technique. An electrochemical polarisation technique was employed to measure the porosity of Ni–P and composite coatings in as plated condition. The technique was based on the chan…

Corrosion Behavior and InhibitionElectrodeposition and Electroless CoatingsSemiconductor materials and interfaces

Soft Capsules, Hard Capsules, and Hybrid Capsules

Katsuhiko Ariga、Qingmin Ji、Gary J. Richards 等 4 位作者2012-03-08Soft Materials

Capsule structures are often regarded as mimics of living cells and have attracted attention within bio-related fields. In addition, their use in other practical applications has become important. The demands of practical applications have stimulated recent developments in capsule science and technologies. In this rev…

Supramolecular Chemistry and ComplexesPolymer Surface Interaction StudiesBlock Copolymer Self-Assembly

Kinetic Modeling of Nitrate Reduction Catalyzed by Pd–Cu Supported on Carbon Nanotubes

O.S.G.P. Soares、Xiaolei Fan、J.J.M. Órfão 等 5 位作者2012-03-08Industrial & Engineering Chemistry Research

New catalysts for liquid phase nitrate reduction were recently synthesized using multiwalled carbon nanotubes as a support. The most promising catalyst (1%Pd–1%Cu/CNT) was used in this kinetic study. The catalyst experimentally showed high selectivity to nitrogen, between 80 and 89%. A mechanistic model was applied to…

Catalytic Processes in Materials ScienceAmmonia Synthesis and Nitrogen ReductionNanomaterials for catalytic reactions

Modeling of Droplet-Based Processing for the Production of High-Performance Particulate Materials using the Level Set Method

Pengtao Wang、Hongwei Sun、Peter Y. Wong 等 5 位作者2012-03-08Numerical Heat Transfer Part A Applications

The dynamic and thermal processes of an Mg-Zn-Y alloy droplet's spreading and solidification are investigated using the level set method in order to understand their effects on the phase change process in a uniform droplet spray process. The level set method, driven with the solidification velocity predicted by a free…

Solidification and crystal growth phenomenaFluid Dynamics and Heat TransferFluid Dynamics Simulations and Interactions

Conserved phosphoryl transfer mechanisms within kinase families and the role of the C8 proton of ATP in the activation of phosphoryl transfer

Colin Kenyon、Robyn Roth、Christiaan W. van der Westhuyzen 等 4 位作者2012-03-08BMC Research Notes

BACKGROUND: The kinome is made up of a large number of functionally diverse enzymes, with the classification indicating very little about the extent of the conserved kinetic mechanisms associated with phosphoryl transfer. It has been demonstrated that C8-H of ATP plays a critical role in the activity of a range of kin…

Enzyme Structure and FunctionChemical Reaction MechanismsATP Synthase and ATPases Research

Anti-inflammatory polysaccharides of Azadirachta indica seed tegument

Lívia de Paulo Pereira、Kaira Emanuella S. da Silva、Racquel O. da Silva 等 5 位作者2012-03-08Revista Brasileira de Farmacognosia

Azadirachta indica A. Juss., Meliaceae, or Indian neem is a plant used to treat inûammatory disorders. Total polysaccharide (TPL) and FI (fractioned by ion exchange chromatography) from the seed tegument of A. indica were evaluated in models of acute inflammation (paw edema/peritonitis) using Wistar rats. Paw edema (m…

Ethnobotanical and Medicinal Plants StudiesPhytochemistry and Bioactive CompoundsPhytochemistry and biological activities of Ficus species