Materials Literature
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The reaction of 1/3 equivalent of CuCl2.2H2O with MnCl2.4H2O and 5-bromo-2-salicylideneamino-1-propanol (H(2)5-Br-sap) in methanol gave dark brown crystals of [MnIIICuIICl(5-Br-sap)2(MeOH)] (1). Complex 1 has an alkoxo-bridged dinuclear core of MnIII and CuII ions, which have elongated octahedral and square-planar coo…
The dielectric constant and ac conductivity have been measured for the layered organic conductor theta-(BEDT-TTF)_2CsZn(SCN)_4 along the out-of-plane direction, which show a relaxation behavior similar to those in the charge-density-wave conductor. Most unexpectedly, they exhibit a large bias dependence with a hystere…
We have performed high-resolution angle-resolved photoemission spectroscopy (ARPES) with synchrotron radiation on layered transition-metal dichalcogenide 1 T -VSe 2 to study the mechanism of the three-dimensional charge-density-wave (CDW) transition. We found that the Fermi surface around the M(L) and K(H) points show…
Abstract For Abstract see ChemInform Abstract in Full Text.
Different techniques used for the mass coloration of polyester fibers are discussed in this article. Dope-dyed fibers have been produced starting from PET bottle wastes. Dope dyeing has been carried out both by the incorporation of pigments during drying before melt extrusion and by masterbatch addition. Fibers produc…
Nanocomposites of a bifunctional epoxy resin are synthesized and evaluated. Organically modified layered silicate (OLS) particles (4% by weight) and multiwalled carbon nanotubes (MWNT) (1% by weight) are used as reinforcements. Thermal and viscoelastic characterization of the two composites are performed and compared…
The out-of-plane thermal conductivity $({\ensuremath{\kappa}}_{c})$ of ${\mathrm{Bi}}_{2\ensuremath{-}x}{\mathrm{Pb}}_{x}{\mathrm{Sr}}_{2}{\mathrm{Co}}_{2}{\mathrm{O}}_{y}$ is measured and analyzed. A low value of $4--8\phantom{\rule{0.3em}{0ex}}\mathrm{mW}∕\mathrm{cm}\phantom{\rule{0.2em}{0ex}}\mathrm{K}$ is observed…
For degradation of chitosan, chitosan with an 80% degree of deacetylation and a weight-average molecular mass (Mw) of approx. 48 kDa was irradiated with gamma-rays at doses up to 200 kGy in a 10% (w/v) solution. The Mw of chitosan was reduced from 48 to 9.1 kDa by irradiation. The characteristics of irradiated chitosa…
Abstract The contribution of electrochemical methods to the development of conducting polymers has been most relevant, although the electropolymerization mechanism has not yet been totally elucidated. The formation of a high‐density oligomeric region in the electrode–solution interface has been clearly established as…
Au, Pt and Au–Pt alloy nanocrystals have been prepared in thin SiO2 film matrices by sol–gel spin-coating, followed by heating at 450 °C in 10% H2–90% Ar. X-Ray diffraction patterns reveal that the Au and Au–Pt nanocrystals have a preferential (111) orientation. Upon increasing the Pt concentration, part of the Pt doe…
Particle sizes of a supramolecular polymer composed of diarylethene having two quadruple hydrogen bonding moieties were changed photoreversibly.
Using 1,2-bis(trimethoxysilyl)ethane as organosiloxane precursor and a triblock copolymer surfactant, Pluronic F127, as template, a highly ordered mesoporous organosilica with large cagelike pores has been successfully synthesized. Its structure was resolved to be 3-D cubic Fmm by high-resolution transmission electron…
We present a study of the magnetization, coercivity, ac susceptibility, and magnetotransport properties of polycrystalline ${\mathrm{Nd}}_{1\ensuremath{-}x}{\mathrm{Sr}}_{x}{\mathrm{CoO}}_{3}\phantom{\rule{0.3em}{0ex}}(0<x<0.6)$. The magnetic phase diagram is dominated by a crossover from a semiconducting spin/c…
We demonstrate a solar cell based on n-type nanoporous Si (PSi) filled with copper phthalocyanine (CuPC) and its derivatives (including a discotic liquid crystal form). The CuPC device shows conversion efficiency up to 2% under white light illumination (20–30mW∕cm2), distinct from cells filled with CuPC derivatives wi…
Spatial variations in electric conductivity and evolutions of band structures of polyaniline (PANI) films have been studied by use of a so-called current-sensing atomic force microscope (CS-AFM) or atomic force microscope current image tunneling spectroscopy (AFM-CITS). PANI films were deposited chemically onto indium…
Flame-retardant nanocomposites are synthesized by melt-blending ethylene-vinyl acetate copolymers with modified layered silicates as nanofillers. Thermogravimetric analysis performed under air demonstrates a clear increase in the thermal stability of the layered silicate-based nanocomposites. The cone calorimeter is u…
The effect of pore size on the radiolytic production of hydroxyl radicals has been investigated in silica controlled pore glasses (CPGs) by means of the HO.-induced conversion of coumarin into 7-hydroxycoumarin (7-OHC). Production of 7-OHC decreases with decreasing pore size (see plot). This effect is not attributed t…
Abstract Poly(styrene‐ co ‐butadiene) rubber (SBR) and polybutadiene rubber (BR)/clay nanocomposites have been prepared. The effects of the incorporation of inorganically and organically modified clays on the vulcanization reactions of SBR and BR were analysed by rheometry and differential scanning calorimetry. A redu…
Methionine ranks among the amino acids most sensitive to oxidation, which converts it to a racemic mixture of methionine-S-sulfoxide (Met-S-SO) and methionine-R-sulfoxide (Met-R-SO). The methionine sulfoxide reductases MsrA and MsrB reduce free and protein-bound MetSO, MsrA being specific for Met-S-SO and MsrB for Met…
ZnO atomic layer deposition (ALD) was achieved using sequential exposures of Zn(CH2CH3)2 and H2O on ZrO2 and BaTiO3 particles at 450K. The surface chemistry of ZnO ALD was monitored in vacuum using Fourier transform infrared spectroscopy. The BaTiO3 and ZrO2 particles initially displayed vibrational features consisten…