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Single-atom quantum memory with degenerate atomic levels

В. А. Решетов、Е. Н. Попов2012-08-14Journal of Physics B Atomic Molecular and Optical Physics

The storage and retrieval of a single-photon polarization q-bit by means of STIRAP through the atoms with degenerate levels is studied theoretically for arbitrary polarization of the driving laser field and arbitrary values of the angular momenta of resonant atomic levels. The dependence of the probability of long-ter…

Diamond and Carbon-based Materials ResearchLaser-Matter Interactions and ApplicationsQuantum optics and atomic interactions

Effect of sintering temperature on microstructure and strength distribution of alumina coil springs

Serkan Nohut、C. A. Perottoni、Chunsheng Lu 等 5 位作者2012-08-14Advances in Applied Ceramics Structural Functional and Bioceramics

Ceramic coil springs are one of the most widely used components in mechanical systems under harsh chemical conditions and high temperatures. In real applications of ceramic coil springs, knowing the effect of sintering temperature on their microstructure and strength distribution plays a crucial role. In this paper, t…

Advanced ceramic materials synthesisAluminum Alloys Composites PropertiesPowder Metallurgy Techniques and Materials

Rheological investigation of polyamide 6 TiO2‐ and BaSO4‐nanocomposites

Irene Hassinger、Thomas Burkhart2012-08-14Journal of Applied Polymer Science

Abstract Commercially available TiO2 and BaSO4 nanoparticles were incorporated in polyamide 6 (PA 6) via twin screw extrusion. The primary particle size of nanoparticles was 15 nm and 20 nm. The compounds were manufactured via multiple extrusion and dilution processing steps. The dispersion of the nanoparticles in the…

Polymer crystallization and propertiesPolymer Nanocomposites and Propertiesbiodegradable polymer synthesis and properties

Crystallization and Morphology of Autophobic Dewetted Poly(ε‐caprolactone)‐b‐poly(L‐lactide) Diblock Copolymer Ultrathin Films

Derong Yan、Haiying Huang、Tianbai He2012-08-14Chinese Journal of Chemistry

Abstract We have investigated the crystallization and morphological behaviors of poly(ε‐caprolactone)‐b‐poly(L‐lactide) (PCL‐b‐PLLA) in its autophobic dewetted ultrathin films (∼11 nm) using atomic force microscopy (AFM) and transmission electron microscopy (TEM). The autophobic dewetting process creates a well define…

Polymer crystallization and propertiesAdvanced Polymer Synthesis and CharacterizationBlock Copolymer Self-Assembly

Structural Reassessment of [W(CO)5(TCNE)]: N (σ) Coordination Instead of an Olefin (π) Complex

Martina Bubrin、Michael J. Krafft、Lisa M. Steudle 等 7 位作者2012-08-14Organometallics

The blue title compound, long assumed to be an olefin complex on the basis of an apparently single unresolved CN stretching band in the IR spectrum, has been identified by experiment and through DFT analysis as a σ complex with the tungsten atom coordinated to one of the nitrile N centers. The previously reported data…

Organometallic Complex Synthesis and CatalysisMetal complexes synthesis and propertiesMagnetism in coordination complexes

Improved Thermal Stability and Electrical Performance by Using PEALD Ultrathin Al2O3 Film with Ta as Cu Diffusion Barrier on Low k Dielectrics

Shan Ding、Qi Xie、Fei Chen 等 8 位作者2012-08-14ECS Solid State Letters

Improved Thermal Stability and Electrical Performance by Using PEALD Ultrathin Al2O3 Film with Ta as Cu Diffusion Barrier on Low k Dielectrics, Ding, Shao-Feng, Xie, Qi, Chen, Fei, Lu, Hai-Sheng, Deng, Shao-Ren, Deduytsche, David, Detavernier, Christophe, Qu, Xin-Ping

Metal and Thin Film MechanicsSemiconductor materials and devicesCopper Interconnects and Reliability

Urea–Water Solvation Forces on Prion Structures

Jens Kleinjung、Franca Fraternali2012-08-14Journal of Chemical Theory and Computation

Solvation forces are crucial determinants in the equilibrium between the folded and unfolded state of proteins. Particularly interesting are the solvent forces of denaturing solvent mixtures on folded and misfolded states of proteins involved in neurodegeneration. The C-terminal globular domain of the ovine prion prot…

Protein Structure and DynamicsEnzyme Structure and FunctionPrion Diseases and Protein Misfolding

Electrical and magnetic properties of the diluted magnetic semiconductors Cd1 − x Mn x GeP2 and Cd1 − x Mn x GeAs2 at high pressures

A. Yu. Mollaev、И. К. Камилов、R. K. Arslanov 等 9 位作者2012-08-14Inorganic Materials

The structural and magnetic phase transitions and magnetoresistance of the diluted magnetic semiconductors Cd1 − x Mn x GeAs2 and Cd1 − x Mn x GeP2 have been studied at high hydrostatic pressures, up to 7 GPa. The normal and anomalous Hall coefficients of the samples have been determined graphically from experimental…

Semiconductor Quantum Structures and DevicesZnO doping and propertiesChalcogenide Semiconductor Thin Films

UV Grafting of a Vinyl Monomer Onto a Methanol Plasma Polymer

Benjamin W. Muir、Anna Tarasova2012-08-14Plasma Processes and Polymers

Abstract We have shown that it is possible to graft a vinyl monomer from a plasma polymer surface in the presence of UV light without the use of a photoinitiator. A polyethylene glycol methacrylate (PEGMA) coating can be grown from the surface of a methanol plasma polymer via photopolymerization. It is proposed that t…

Surface Modification and SuperhydrophobicityAdvanced Polymer Synthesis and CharacterizationPolymer Surface Interaction Studies

Effect of heat treatment on the physicochemical properties of Cu- and Mn-containing oxide catalysts

Andrei Ivanets、А. И. Ратько、Т. Ф. Кузнецова 等 4 位作者2012-08-14Inorganic Materials

We have studied the effect of calcination temperature on the phase composition and pore structure of Cu- and Mn-containing supported oxide catalysts. These characteristics have been shown to influence the catalytic activity of the materials for the oxidation of divalent iron in water.

Catalytic Processes in Materials ScienceMesoporous Materials and CatalysisCatalysis and Oxidation Reactions

Significant Promotion of Morphology in Fabricating Efficient Environment Protector

Yu Zhou、Wenjuan Qian、Jing Yang 等 6 位作者2012-08-14Chinese Journal of Chemistry

Abstract A new strategy of morphology control was applied for mesoporous silica SBA‐15 to fabricate efficient environment protector, and the micro‐ and macro‐morphology of SBA‐15 were simultaneously controlled in weak acidic condition by using citric acid. Through simply tuning the synthetic temperature, monolithic SB…

Zeolite Catalysis and SynthesisMesoporous Materials and CatalysisPolyoxometalates: Synthesis and Applications

Laser clad corrosion protection for mild and harsh environments

Khalid Mahmood、Nicholas Stevens、Andrew J. Pinkerton2012-08-14Surface Engineering

Corrosion of one type or another occurs in almost every environment and high performance corrosion protection methods are often too expensive to be economically viable. This work examines the performance of protective layers of Inconel 617, laser clad in the form of salvaged machining chips, to protect a corrosive sub…

Corrosion Behavior and InhibitionHigh-Temperature Coating BehaviorsHigh Entropy Alloys Studies

Ballistic resistance of nanostructured and gradient surface layers of protective modules of armour surfaced using the GMA method

A. Klimpel、K. Luksa、Marek Burda2012-08-14Welding International

The purpose of the investigations was to develop technological conditions of robotized GMA surfacing of experimental protective modules of armours. On the grounds of ballistic tests, the high resistance of armour protective modules against the impact of B-32 armour-piercing incendiaries of 7.62 × 54 mm Mosin rifle car…

Energetic Materials and CombustionHigh-Velocity Impact and Material BehaviorSurface Treatment and Residual Stress

Tin(II) Selective PVC Membrane Electrode Based on Salicylaldehyde Thiosemicarbazone as an Ionophore

Sulekh Chandra、Kusum Sharma、Adarsh Kumar2012-08-14Journal of Chemistry

A polymeric membrane‐based tin selective electrode was developed by using salicylaldehyde thiosemicarbazone (STSC). The best performance was recorded with a membrane composition of PVC : TBP : ionophore : NaTPB as 28 : 59 : 8 : 5 (w/w%). The Nernstian slope calculated from the calibration curve for Sn 2+ sensor was 28…

Electrochemical sensors and biosensorsConducting polymers and applicationsAnalytical Chemistry and Sensors

Koordinationspolymere mit Tris(4‐carboxyphenyl)‐phosphanoxid als Ligand – Synthese, Kristallstrukturen und topologische Untersuchungen

Peter Schmiedel、Harald Krautscheid2012-08-14Zeitschrift für anorganische und allgemeine Chemie

Abstract The solvothermal reaction of MnCl2·4H2O or CoCl2·6H2O with tris(4‐carboxyphenyl)‐phosphine oxide (H3TPO), in DMF orDMA resulted in the four coordination polymers [M3(tpo)2(dmf)(H2O)2](1: M = Mn; 2: M = Co), (NMe2H2)[Mn3Cl(HCO2)(htpo)(tpo)(H2O)] (3) and (NMe2H2)[Mn3(tpo)2(OAc)] (4). Structural characterization…

Metal-Organic Frameworks: Synthesis and ApplicationsMetal complexes synthesis and propertiesMagnetism in coordination complexes

Relationship between the water molecules in fish-meat gel and the gel structure

Lujia Luo、Yuri Tashiro、Hiroo Ogawa2012-08-14Fisheries Science

To elucidate the structure of the network of the water retention mechanism of fish-meat gel, the microscopic relationship between the water content and viscoelasticity was investigated, and the specific surface area (S) where the water molecules are adsorbed was also measured. The gel structures of fish-meat, actomyos…

Meat and Animal Product QualityProteins in Food SystemsCollagen: Extraction and Characterization

Inactivation of Met471Cys Tyramine β-Monooxygenase Results from Site-Specific Cysteic Acid Formation

Robert L. Osborne、Hui Zhu、Anthony T. Iavarone 等 5 位作者2012-08-14Biochemistry

Tyramine β-monooxygenase (TβM), the insect homologue of dopamine β-monooxygenase, is a neuroregulatory enzyme that catalyzes the β-hydroxylation of tyramine to yield octopamine. Mutation of the methionine (Met) ligand to Cu(M) of TβM, Met471Cys, yielded a form of TβM that is catalytically active but susceptible to ina…

Mass Spectrometry Techniques and ApplicationsEnzyme Structure and FunctionMetal-Catalyzed Oxygenation Mechanisms

Controllable synthesis of Ag/poly(o-phenylenediamine) hollow hybrids and their catalytic application

Bo‐Qing Xu2012-08-14Materials Research Innovations

Poly(o-phenylenediamine) (POPD) hollow microspheres with Ag submicrometre particles decorated on both inner and outer surfaces of shells as Ag/POPD hollow hybrids have been successfully fabricated through the reduction of AgNO3 by ascorbic acid in aqueous solution containing POPD hollow microspheres. Poly(o-phenylened…

Graphene research and applicationsDendrimers and Hyperbranched PolymersNanomaterials for catalytic reactions

Fast Morphological Evolution and Enhanced Capacitive Behavior of MnO2 at High Operating Temperature

Yiming Jiang、Z. Li、Jie Xu 等 4 位作者2012-08-14ECS Electrochemistry Letters

Amorphous nanostructured MnO 2 was anodically deposited onto duplex stainless steel substrate. The cyclic stability of MnO 2 was investigated by chronopotentiometry in 1 M Na 2 SO 4 at two different temperatures. Results demonstrated that the specific capacitance was enhanced significantly after 2000 cycles at 70°C, f…

ZnO doping and propertiesSupercapacitor Materials and FabricationElectrodeposition and Electroless Coatings

Tunable Polarization States With Helical Metamaterials

Zhenyu Yang、Ming Zhao、Peiyuan Xie 等 6 位作者2012-08-14IEEE Photonics Technology Letters

In this letter, we demonstrate the relationship between the incident angles and the polarization states of transmitted beams on the basis of a kind of helical metamaterials. Through finite-difference time-domain simulations, it is found that the polarization states of the transmitted lights can be tuned by changing th…

Metamaterials and Metasurfaces ApplicationsPlasmonic and Surface Plasmon ResearchAdvanced Antenna and Metasurface Technologies