Materials Literature
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Synthetic model peptides have proven useful for examining fundamental peptide-lipid interactions. A frequently employed peptide design consists of a hydrophobic core of Leu-Ala residues with polar or aromatic amino acids flanking each side at the interfacial positions, which serve to "anchor" a specific transmembrane…
We prepared anionic multistimuli responsive core-shell polymer nanoparticles with very low size dispersity. By using either acrylic acid (AA) or methacrylic acid (MA) as a comonomer in the poly(N-isopropyl acrylamide) (PNIPAM) shell, we are able to change the distribution of negative charges in the nanoparticle shell.…
Certain heavy metal ions such as copper and zinc serve as essential cofactors of many enzymes, but are toxic at high concentrations. Thus, intracellular levels have to be subtly balanced. P-type ATPases of the P(IB)-subclass play a major role in metal homeostasis. The thermoacidophile Sulfolobus solfataricus possesses…
Meclofenamic acid (MFA) is the most potent anti-inflammatory drug among the fenamic acids. We report (1) two cocrystals of MFA with isonicotinamide (INA) and 4,4′-bipyridine (BPY); (2) polymorphs of MFA and piperazine (PPZ) 1:1 salt (orthorhombic P 2 1 2 1 2 1 O and monoclinic P 2 1 / c M), MFA–PPZ–H 2 O 1:1:1 salt hy…
We have investigated the assembly of a two-dimensional coordination polymer, Nd(2)(C(6)H(2)N(2)O(4))(2)(C(2)O(4))(H(2)O)(2), that has been prepared from the hydrothermal reaction of Nd(NO(3))(3)·6H(2)O and 2,3-pyrazinedicarboxylic acid (H(2)pzdc). In situ oxalate formation as observed in this system has been been inve…
Ag nanowires are prepared as templates by a polyol reduction process. Then Ag nanotubes coated with a thin layer of Pd are synthesized through sequential reduction accompanied with the galvanic displacement reaction. The products show a hollow core-shell nanotubular structure, as demonstrated by detailed characterizat…
By selectively dealloying a PtCoAl ternary alloy, a novel nanoporous PtCo (np-PtCo) alloy with a three-dimensional bicontinuous pore-ligament structure is successfully fabricated. X-ray diffraction and electron microscopic characterizations demonstrate the single-crystal nature of the alloy ligament with a ligament si…
Proteomics is defined as the large-scale study of proteins in particular for their structures and functions Proteomics increasingly plays an important role in areas like protein interaction studies, biomarker discovery, cancer prevention, drug treatment and disease screening medical diagnostics Proteomics can be perfo…
The switching dynamics of a multiferroic nanomagnetic NAND gate with fan-in/fan-out is simulated by solving the Landau-Lifshitz-Gilbert (LLG) equation while neglecting thermal fluctuation effects. The gate and logic wires are implemented with dipole-coupled two-phase (magnetostrictive/piezoelectric) multiferroic eleme…
Because RNA interference (RNAi) can be applied to any gene, this technique has been widely used for studying gene functions. In addition, many researchers are attempting to use RNAi technology in RNAi-based therapies. However, several challenging and controversial issues have arisen during the widespread application o…
We report the first structural determination of the metastable β polymorph of nifedipine (NIF) by single-crystal X-ray diffraction. Stable, high-quality crystals were grown from the melt in the presence of a polymer dopant. Our β NIF structure is characterized by a unit cell similar to that of the structure recently p…
We report on the generation of high-order optical vortices by spiral phase mirrors (SPMs). The mirrors are produced by direct machining with a diamond tool and are shown to produce high-quality optical vortices with topological charges ranging from 1 to upwards of 100 at a wavelength of 532 nm. The direct machining te…
Magnetization orientation in Ga${}^{+}$-irradiated Pt/Co(${d}_{\mathrm{Co}}$)/Pt ultrathin films can be changed in a controlled way by adjusting the ion fluence, $F$. Two-dimensional (${d}_{\mathrm{Co}}$, $F$) diagrams of magnetic and magneto-optical properties have been derived. Distinct out-of-plane magnetic anisotr…
A biologically inspired compound-eye structure, which composes of ~5,867 honeycomb-patterned microlenses, was fabricated on a hemispherical shell. The fabrication process was simple and low-cost, which involves a femtosecond laser-enhanced wet etching and casting process followed by a thermomechanical process to conve…
Porphyrins have been used for photodynamic therapy (PDT) against a wide range of targets like bacteria, viruses and tumor cells. In this work, we report porphyrin-conjugated multi-walled carbon nanotubes (NT-P) as potent antiviral agents. Specifically, we used Protoporphyrin IX (PPIX), which we attached to acid-functi…
The complexes M(II){N(H)Ar(Pr(i)(6))}(2) (M = Co, 1 or Ni, 2; Ar(Pr(i)(6)) = C(6)H(3)-2,6(C(6)H(2)-2,4,6-Pr(i)(3))(2)), which have rigorously linear, N-M-N = 180°, metal coordination, and M(II){N(H)Ar(Me(6))}(2) (M = Co, 3 or Ni, 4; Ar(Me(6)) = C(6)H(3)-2,6(C(6)H(2)-2,4,6-Me(3))(2)), which have bent, N-Co-N = 144.1(4)…
Phenothiazinyl rhodanylidene acetic acid merocyanine dyes with variable substitution pattern on the peripheral benzene ring were synthesized in good to excellent yields by Knoevenagel condensation of the corresponding phenothiazinyl aldehydes and rhodanine-N-acetic acid. The electronic properties were investigated by…
The half-lantern compound [{Pt(bzq)(μ-C(7)H(4)NS(2)-κN,S)}(2)]·Me(2)CO (1) was obtained by reaction of equimolar amounts of potassium 2-mercaptobenzothiazolate (KC(7)H(4)NS(2)) and [Pt(bzq)(NCMe)(2)]ClO(4). The Pt(II)···Pt(II) separation in the neutral complex [{Pt(bzq)(μ-C(7)H(4)NS(2)-κN,S)}(2)] is 2.910 (2) Å, this…
Two cadmium(II) metal–organic frameworks based on two mixed ligands of HBTA and H 2 BDC, [Cd 5 (BTA) 6 (BDC) 2 (DMF) 4 (H 2 O) 2 ] n · n (2DMF·H 2 O) ( 1 ) and [Cd 7 (BTA) 2 (BDC) 6 (DMF) 8 ] n ·2 n DMF ( 2 ) (HBTA = 1,2,3-benzenetriazole; H 2 BDC = 1,4-benzenedicarboxylic acid), have been prepared through methods of…
A method is provided to compute the exponent parameter λ yielding the dynamic exponents of critical slowing down in mode coupling theory. It is independent from the dynamic approach and based on the formulation of an effective static field theory. Expressions of λ in terms of third order coefficients of the action exp…