Materials Literature
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Nominal ${\mathrm{La}}_{2}{\mathrm{NiMnO}}_{6}$ prepared by solid-state reaction in air in accordance with earlier reports is shown to contain excess oxygen as well as the coexistence of two ferromagnetic phases of comparable Curie temperatures, one monoclinic and the other rhombohedral. As originally predicted, order…
Digital video imaging of the plasma electrolytic oxidation (PEO) of aluminium has been performed, which allowed evaluation of both dimensional characteristics of individual microdischarges appearing at the oxide–electrolyte interface and their collective behaviour throughout the oxidation process. It has been shown th…
We report the preparation, structural characterization, and detailed lactide polymerization behavior of a new Zn(II) alkoxide complex, (L(1)ZnOEt)(2) (L(1) = 2,4-di-tert-butyl-6-{[(2'-dimethylaminoethyl)methylamino]methyl}phenolate). While an X-ray crystal structure revealed the complex to be dimeric in the solid stat…
Unusually structure-selective growth of single-walled carbon nanotubes (SWNTs) has been attained using a CVD method with a solid supported catalyst. In this method, CO feedstock disproportionates on silica-supported catalytic nanoclusters of Co that are formed in situ from mixed salts of Co and Mo. The nanotube produc…
We present a detailed study of static and dynamic magnetic behavior of Fe3O4 nanoparticles with average particle sizes 〈d〉 ranging from 5 to 150 nm. Bulk-like properties such as saturation magnetization, hyperfine parameters, coercive field, and Verwey transition are observed in 150 nm particles. For decreasing partic…
A large body of experimental evidence suggests that the decay of the false vacuum, accompanied by quantum pair creation of soliton domain walls, can occur in a variety of condensed matter systems. Examples include nucleation of charge soliton pairs in density waves (e.g., Miller J H Jr et al 2000 Phys. Rev. Lett . 84…
Abstract The relaxation of liquid‐crystalline polymer (LCP) fibers in the polycarbonate (PC)/LCP blend was examined under various conditions on a hot‐stage microscope. LC5000 is a thermotropic LCP consisting of 80/20 hydroxybenzoic acid and poly(terephthalate). The geometry of the fibers is not an important factor in…
We investigated the translational dynamics of water molecules in the hydrated aluminate and aluminum-ferrite pastes (C 3 A and C 4 AF), two main components of the Ordinary Portland Cement (OPC), using the incoherent quasi-elastic neutron scattering (QENS) technique. We used a high-resolution disk chopper spectrometer…
Presented here are results of ab initio Density Functional Theory (DFT) structural relaxations performed on dehydrogenated and monohydrogenated nanocrystalline diamond structures of octahedral {111} and cuboctahedral morphologies, up to approximately 2 nm in diameter. Our results in this size range show an inward tran…
Visible light reflectivities are measured for graphite and molybdenum tokamak wall tiles as a function of incident angle and wavelength. Using the measured reflectivities together with a ray-tracing routine, estimates of the effect of wall reflections on Dα light measurements in the DIII-D and Alcator C-Mod tokamaks a…
Recently, a new class of active materials, known as ferromagnetic shape-memory alloys, has shown promise as actuator and sensor materials. These alloys, such as Ni2MnGa and Fe3Pd, are ferromagnetic and undergo a reversible diffusionless structural phase transformation giving rise to shape-memory behavior. In order to…
Excitation of a carotenoid (C) porphyrin (P) fullerene (C 60 ) molecular triad yields the porphyrin first excited singlet state, C− 1 P−C 60, which decays via a sequential two-step photoinduced electron-transfer process into a C •+ −P−C 60 •- charge-separated state with a lifetime of 340 ns in 2-methyltetrahydrofuran…
[reaction: see text] By means of a two-layered ONIOM approach, we predict that sidewall epoxidation of single-walled carbon nanotubes (SWNTs) with dioxiranes is viable. The SWNT epoxides thus produced could be precursors for further chemical modification of SWNTs, given the abundant and well-established chemistry of o…
We study the possibility of nanoscale phase separation in manganites in the framework of the double-exchange model. The homogeneous canted state of this model is proved to be unstable towards the formation of small ferromagnetic droplets inside an antiferromagnetic insulating matrix. For the ferromagnetic polaronic st…
Raman spectra of HiPco SWNT and SWNT-pyrene films were measured in the 160–1800 cm−1 range. Due to the non-covalent interaction between SWNT and pyrene the most intensive component of the SWNT G mode (1590 cm−1) is downshifted by 2 cm−1 and becomes narrower. Also the intensity of the low-frequency component of the G m…
We present a systematic study on the synthesis of mixed monolayer-protected clusters (MMPCs) from mixtures of alkanethiols. Our results show that solvation-driven thermodynamic preferential adsorption of precursor ligands governs monolayer composition of MMPCs. In the mixed system HO(CH 2 ) n SH/ CH 3 (CH 2 ) m SH ( n…
Abstract Hydrogen bonding in polyamide 66/clay nanocomposite (PA66CN) was first investigated with temperature Fourier transform infrared (FTIR), the results of which were compared with that of pristine polyamide 66 (PA66) with the same thermal history. FTIR spectra at room temperature revealed that there is essentiall…
The complexation behavior, binding properties, and spectral parameters of supramolecular chirality induction in the achiral host molecule, syn (face-to-face conformation) ethane-bridged bis(zinc porphyrin), upon interaction with chiral bidentate guests (diamines and amino alcohols) have been studied by means of UV-vis…
Amorphous syndiotactic polystyrene (sPS) was crystallized at room temperature in dichloromethane, chloroform, toluene, o -dichlorobenzene, and decalin (cis−trans) to form the clathrate structure (δ form) with respective solvent molecules. Room temperature FTIR spectra are compared for subtle differences, which arise d…
Abstract Impact‐modified polypropylene (PP)/vermiculite (VMT) nanocomposites toughened with maleated styrene–ethylene butylene–styrene (SEBS‐ g ‐MA) were compounded in a twin‐screw extruder and injection‐molded. VMT was treated with maleic anhydride, which acted both as a compatibilizer for the polymeric matrices and…