Materials Literature
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Mesostructured silica films have been doped with lead sulfide (PbS) nanocrystals by a two-step impregnation, using the mesopores as nanoreactors for PbS growth. Secondary ion mass spectrometry and transmission electron microscopy characterizations demonstrated nanocrystals growth inside the pores and throughout the fi…
Telechelic random copolymers were prepared by copolymerization of ε-caprolactone (εCL) and trimethylene carbonate (TMC) in bulk using bismuth(III) hexanoate, Bi(OHex) 3, as initiator. These copolymers were characterized by 1 H and 13 C NMR spectroscopy. A−B−A triblock copolymers were synthesized by chain extension of…
Porphyrins bearing four urea-linked dodecyl groups (3a) or four urea-linked triethoxysilylpropyl groups (3TEOS) at their peripheral positions were synthesized. 3a tends to assemble into a sheetlike two-dimensional structure due to the predominant hydrogen-bonding interaction among the urea groups and acts as a moderat…
The fragilities (T(g)-normalized temperature dependence of alpha-relaxation times) of 33 glass-forming liquids and polymers are compared for isobaric, mP, and isochoric, mV, conditions. We find that the two quantities are linearly correlated: mP = (37+/-3) + (0.84+/-0.05)mV. This result has obvious and important conse…
The purpose of this study is to compare the results from molecular-dynamics and dissipative particle dynamics (DPD) simulations of Lennard-Jones (LJ) fluid and determine the quantitative effects of DPD coarse graining on flow parameters. We illustrate how to select the conservative force coefficient, the cut-off radiu…
Abstract Summary: Epoxy nanocomposites containing rod‐like silicate (attapulgite) were prepared using a simple organic modification to the nanorods. The modification led to effective interfacial adhesion between the ceramic nanorods and the epoxy resin and hence good load transfer. Scanning electron microscopy examina…
We determine the lifetime of the surface plasmon in metallic nanoparticles under various conditions, concentrating on the Landau damping, which is the dominant mechanism for intermediate-size particles. Besides the main contribution to the lifetime, which smoothly increases with the size of the particle, our semiclass…
The complex formation between a weak polyelectrolyte chain and an oppositely charged nanoparticle is investigated using Monte Carlo simulations. Global structural parameters such as the polyelectrolyte length, nanoparticle size, solution pH, and ionic concentration as well as local features, such as the nanoparticle s…
Monodispersed copolymer latex particles functionalized by surface carboxylate groups are used as effective colloidal templates for the controlled crystallization of calcium carbonate in solution. After template removal, well-defined, calcite single crystals exhibiting a rhombohedral morphology and uniform surface pore…
High electron mobility thin films of In2−xWxO3+y(0⩽x⩽0.075) were prepared on amorphous SiO2 and single-crystal yttria-stablized zirconia (001) substrates by pulsed laser deposition. Mobilities ranged between 66 and 112cm2∕Vs depending on the substrate type and deposition conditions, and the highest mobility was observ…
Hybrid biofibers (sisal and oil palm) were incorporated into natural rubber matrix. The water absorption characteristics of the composites were evaluated with reference to fiber loading. The influence of temperature on water sorption of the composites is also analyzed. Moisture uptake was found to be dependent on the…
Au atoms have been deposited on oxidized and reduced TiO2 thin films grown on Mo(110). The gold binding sites and the occurrence of Au-TiO2 charge transfer were identified by measuring infrared spectra as a function of temperature and substrate preparation. The results have been interpreted by slab model DFT calculati…
The structure of thin films cast from regenerated solutions of Bombyx mori cocoon silk in hexafluoroisopropyl alcohol (HFIP) was studied by synchrotron X-ray diffraction during heating. A solid-state conformational transition from an alpha-helical structure to the well-known beta-sheet silk II structure occurred at a…
Besides being a fascinating class of new materials, magnetic molecules provide the opportunity to study concepts of condensed matter physics in zero dimensions. This contribution will exemplify the impact of molecular magnetism on concepts of frustrated spin systems. We will discuss spin rings and the unexpected rules…
We have recently demonstrated a one-step process to fabricate silver-polypyrrole (PPy) coaxial nanocables (Chen, A.; Wang, H.; Li, X. Chem. Commun. 2005, 14, 1863). The formation process of silver-PPy coaxial nanocables is discussed in this article. It was found from the results of TEM and SEM images that large number…
Experiments in which mass-selected gold clusters were deposited on a surface have found that the catalytic properties depend strongly on cluster size. However, these experiments have not established definitively that the clusters maintain their size after deposition. We report here work in which we deposit low kinetic…
Orbital order present in several transition metal compounds could give rise to topological defects. Here we argue that the topological defects in orbital ordered half doped manganites are orbital solitons that carry a charge of +/-e/2. When extra charge is added to the system an array of solitons is formed and an inco…
With the empirical bond polarizability model, the nonresonant Raman spectra of the chiral and achiral single-wall carbon nanotubes (SWCNTs) under uniaxial and torsional strains have been systematically studied by ab initio method. It is found that both the frequencies and the intensities of the low-frequency Raman-act…
Since crack propagation in oxide materials at low crack velocities is partly determined by chemical corrosion, proper knowledge of the crack tip chemistry is crucial for understanding fracture in these materials. Such knowledge can be obtained only from in situ studies because the processes that occur in the highly co…
We present a detailed study of the magnetic-field and temperature-dependent polarization of the near-band-gap photoluminescence in Gd-doped GaN layers. Our study reveals an extraordinarily strong influence of Gd doping on the electronic states in the GaN matrix. We observe that the spin splitting of the valence band r…