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Excited state absorption in chromium doped Li2B4O7glass

Cz. Koepke、K. Wiśniewski、M. Grinberg 等 5 位作者2001-03-01Journal of Physics Condensed Matter

Excited state absorption (ESA) measurements of the Cr:Li 2 B 4 O 7 glass (Cr:LBO-glass) along with preliminary interpretation are presented. The presence of chromium in its tri- (d 3 ) and hexa- (d 0 ) valence states is observed. Both Cr 3+ and Cr 6+ ions appear to contribute in the de-excitation processes and can be…

Luminescence Properties of Advanced MaterialsGlass properties and applicationsCrystal Structures and Properties

On the notion of anisotropy of constitutive laws

Alain Bossavit2001-03-01COMPEL The International Journal for Computation and Mathematics in Electrical and Electronic Engineering

We argue that, in static situations (magnetostatics, for instance) all materials can be considered as locally isotropic, though not homogeneous. Genuine anisotropy appears only in dynamic situations, e.g., in wave propagation problems.

Magnetic Properties and ApplicationsElectromagnetic Simulation and Numerical MethodsComposite Material Mechanics

Ni phases formed in cement and cement systems under highly alkaline conditions: an XAFS study

André M. Scheidegger、E. Wieland、Andreas C. Scheinost 等 6 位作者2001-03-01Journal of Synchrotron Radiation

X-ray absorption fine structure (XAFS) spectroscopy was applied to assess the solubility-limiting phase of Ni in cement and cement minerals. The study reveals the formation Ni and Al containing hydrotalcite-like layered double hydroxides (Ni-Al LDHs) when cement material (a complex mixture of CaO, SiO2, Al2O3, Fe2O3 a…

Concrete and Cement Materials ResearchLayered Double Hydroxides Synthesis and ApplicationsMagnesium Oxide Properties and Applications

Co K-edge XAS study on a new cobalt-doped-SiO2 pillared clay

Jin‐Ho Choy、Hyun Suk Jung、Joo-Byoung Yoon2001-03-01Journal of Synchrotron Radiation

New Co-doped-SiO2-sol pillared montmorillonite has been synthesized by interlayer hydrolysis and condensation of tetraethylorthosilicate (TEOS) in the presence of Co2+ ion using an organic template. The Co K-edge XANES and EXAFS analyses for the CoO-SiO2-PILC (before and after calcination) and for the references such…

Zeolite Catalysis and SynthesisMesoporous Materials and CatalysisIron oxide chemistry and applications

Emission uniformity enhancement between microfabricated tips in cold cathode arrays

P. R. Schwoebel、C.A. Spindt、C.E. Holland 等 4 位作者2001-03-01Journal of Vacuum Science & Technology B Microelectronics and Nanometer Structures Processing Measurement and Phenomena

The current–voltage characteristics can vary significantly between individual microfabricated tips in as-fabricated arrays of cold cathodes. Such emission nonuniformity is undesirable in device applications. We have shown that in situ tip self-heating by the emitted electron current can be used to make the current–vol…

Carbon Nanotubes in CompositesNanowire Synthesis and ApplicationsElectrostatic Discharge in Electronics

Comparison between analytical and numerical methods of calculating tooth ripple losses in salient pole synchronous machines

Oliver Drubel、R.L. Stoll2001-03-01IEEE Transactions on Energy Conversion

The application of analytical and numerical methods to an electromagnetic problem requiring an accurate representation of saturation is examined. The problem considered is that of tooth-ripple losses in salient-pole synchronous machines for the situation where the pole pitch is much greater than the armature slot pitc…

Electric Motor Design and AnalysisMagnetic Properties and ApplicationsInduction Heating and Inverter Technology

Effects of Oxygen Concentration on Characteristics of RF-Sputtered In2O3–ZnO Thin Films

Seoung-Hwan Park、Hwa-Min Kim、Byung-Roh Rhee 等 5 位作者2001-03-01Japanese Journal of Applied Physics

The effects of oxygen concentration on the electrical and optical properties of In 2 O 3 –ZnO films are investigated. In 2 O 3 –ZnO films deposited under the pure Ar gas show a resistivity of about 3.8 ×10 -4 Ω·cm, comparable to that of indium-tin-oxide (ITO) films (∼10 -4 Ω·cm), and an average transmittance of over 9…

ZnO doping and propertiesGas Sensing Nanomaterials and SensorsElectronic and Structural Properties of Oxides

Epitaxial growth of TiO2 thin films by pulsed laser deposition on GaAs(100) substrates

Xiaohua Liu、X. Y. Chen、J. Yin 等 8 位作者2001-03-01Journal of Vacuum Science & Technology A Vacuum Surfaces and Films

Rutile-phase TiO2 thin films have been epitaxially grown on GaAs(100) substrates at 700 °C under 5 Pa oxygen ambient pressure, and at room temperature (30 °C) and 5×10−4 Pa base vacuum by KrF pulsed excimer laser deposition. The [110]-oriented TiO2 films were composed of two types of domains perpendicular to each othe…

Quantum Dots Synthesis And PropertiesChalcogenide Semiconductor Thin FilmsPhase-change materials and chalcogenides

Lipase-Catalyzed Ring-Opening Polymerization of 3(S)-sec-Butylmorpholine-2,5-dione

Yakai Feng、Doris Klee、Hartwig Höcker2001-03-01Macromolecular Bioscience

Lipase-catalyzed ring-opening bulk polymerizations of 3(S)-sec-butylmorpholine-2,5-dione (BMD) were investigated. Selected commercial lipases were screened as catalysts for BMD polymerization at 110°C. Polymerizations catalyzed with 10 wt.-% of lipase PPL and PC result in BMD conversions of about 70% and in molecular…

Organometallic Complex Synthesis and Catalysisbiodegradable polymer synthesis and propertiesCarbon dioxide utilization in catalysis

Preparation and Characterization of Doped Polybenzidine

Mukul Kumar、M. Nagabhooshanam、M. Anand Rao 等 4 位作者2001-03-01Crystal Research and Technology

The polybenzidine has been synthesized by thermal method and characterized by X-ray diffraction and infrared absorption studies. Further, polybenzidine has been doped with nitrate, sulfate and acetate ions. The electrical conductivity behavior of doped and undoped polybenzidine has been studied for various concentrati…

Advanced Sensor and Energy Harvesting MaterialsConducting polymers and applicationsAnalytical Chemistry and Sensors

Capping layers for extreme-ultraviolet multilayer interference coatings

Mandeep Singh、Joseph J. M. Braat2001-03-01Optics Letters

The reflectivity of extreme-ultraviolet thin-film multilayer (ML) interference coatings, terminated by a native oxide or other capping layer (CL), is critically dependent on the thickness of the final deposited layer of the top period. We show in this numerical study that, for a molybdenum-silicon ML, a high reflectiv…

Thin-Film Transistor TechnologiesAdvancements in Photolithography TechniquesOptical Coatings and Gratings

Electrical characterization of ceramic insulation coatings for magnet technology

E. Çelik、İ.H. Mutlu、H. Okuyucu 等 4 位作者2001-03-01IEEE Transactions on Applied Superconductivity

In this study, electrical characterization of ceramic insulation coatings were evaluated by resistive, capacitance, and high voltage breakdown techniques. The insulation coatings were produced on Ag or AgMg sheathed Bi-2212 tapes and CuNb/sub 3/Sn wires by continuous, reel-to-reel sol-gel process. The coatings were th…

Physics of Superconductivity and MagnetismMagnetic Properties and ApplicationsMagnetic Field Sensors Techniques

Properties and manufacturing of a new starch plastic

R.A. de Graaf、L. P. B. M. Janssen2001-03-01Polymer Engineering and Science

Abstract Environmental awareness has strongly stimulated the introduction of biodegradable materials based on renewable resources of natural origin. This paper describes the properties and manufacturing of such a bioplastic. In a counter‐rotating twin screw extruder, starch and polystyrene were mixed. To enhance mater…

Polymer crystallization and propertiesbiodegradable polymer synthesis and propertiesMicroplastics and Plastic Pollution

Two-dimensional finite element magnetic modeling for scalar hysteresis effects

H.L. Toms、R.G. Colclaser、M. P. Krefta2001-03-01IEEE Transactions on Magnetics

A general transient simulation method accurately models the magnetic state of a device containing a ferromagnetic core by incorporating a scalar hysteresis model into the standard finite element framework. The method numerically implements the Jiles-Atherton hysteresis model to simulate hysteresis without introducing…

Magnetic properties of thin filmsElectric Motor Design and AnalysisMagnetic Properties and Applications

Methylium Ions with OPV Chains − New NIR Dyes

Herbert Meier、Soungkyoo Kim2001-03-01European Journal of Organic Chemistry

Carbinols, which contain three OPV chains, were generated in convergent syntheses. The extension of the conjugation leads to a bathochromic effect that shifts the absorption from the UV into the visible region. The carbinol series has a convergence limit of the absorption at λmax = 415 nm. The corresponding carbenium…

Photochemistry and Electron Transfer StudiesLuminescence and Fluorescent MaterialsPhotochromic and Fluorescence Chemistry

Polarized resonance Raman dispersion spectroscopy on metalporphyrins

Reinhard Schweitzer‐Stenner2001-03-01Journal of Porphyrins and Phthalocyanines

Resonance Raman spectroscopy is an ideal tool to investigate the structural properties of chromophores embedded in complex (biological) environments. This holds particularly for metalporphyrins which serve as prosthetic group in various proteins. Resonance Raman dispersion spectroscopy involves the measurement of reso…

Photosynthetic Processes and MechanismsPorphyrin and Phthalocyanine ChemistryHemoglobin structure and function

A Factorial Design Applied to the Extrusion Foaming of Polypropylene/Wood-Flour Composites

Laurent M. Matuana、Qingxiu Li2001-03-01Cellular Polymers

A factorial design was performed to determine the statistical effects of material compositions and extrusion processing variables on the foamability of polypropylene (PP)/wood-flour composites. Two levels with centrepoint values of wood flour content, chemical foaming agent (CFA) content, extruder's die temperature an…

Natural Fiber Reinforced Compositesbiodegradable polymer synthesis and propertiesPolymer Foaming and Composites

Cladistic analysis of plicated Thalassiosira (Bacillariophyceae)

Matthew L. Julius、Yoshihiro Tanimura2001-03-01Phycologia

Nineteen Thalassiosira species informally referred to as the plicated Thalassiosira were examined in a cladistic analysis. The species range in age from 17 Ma to modern, representing the earliest known members of the group and its most recent members. Two most parsimonious cladograms were discovered, generally agreein…

Diatoms and Algae Research

Synthesis and Thermal Properties of Biodegradable Poly(ester-urethane)s Based on Chemo-Synthetic Poly[(R,S)-3-hydroxybutyrate]

Gamal R. Saad、Y. J. Lee、H. Seliger2001-03-01Macromolecular Bioscience

A series of telechelic oligo[(R,S)-3-hydroxybutyrate]-diols (PHB-diols) was synthesized from ethyl (R,S)-3-hydroxybutyrate (ethyl (HB)) and four different aliphatic diols, namely, 1,4-butanediol, 1,6-hexanediol, 1,8-octanediol and 1,10-decanediol by transesterification and condensation in bulk. The structures of the s…

biodegradable polymer synthesis and propertiesCarbon dioxide utilization in catalysisPhotopolymerization techniques and applications

Molecular organization in two-dimensional films of liquid I. Langmuir films of binary mixtures of liquid crystals with a crystalline mixtures terminal cyano group

Tomasz Martyński、Robert Hertmanowski、Danuta Bauman2001-03-01Liquid Crystals

The Langmuir films of two liquid crystal materials, 4-octyl-4'-cyanobiphenyl (8CB) and 4-pentyl-4"-cyano-p-terphenyl (5CT), and of their mixtures have been studied by recording surface pressure-area isotherms and Brewster angle microscopy (BAM) images. The pure liquid crystals revealed very different characters of the…

Liquid Crystal Research AdvancementsPhase Equilibria and ThermodynamicsSurfactants and Colloidal Systems