Materials Literature
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Abstract Azulene has been shown to react with pyrrole and a series of aromatic aldehydes in the presence of boron trifluoride etherate to give meso ‐tetraarylazuliporphyrins 6 . Good yields of azuliporphyrins were obtained for benzaldehyde, 4‐chlorobenzaldehyde, 4‐bromobenzaldehyde, and 4‐iodobenzaldehyde, and under d…
An isothermal magnetic entropy change in itinerant-electron systems is discussed on the theory of itinerant-electron metamagnetism. The effect of spin fluctuations is taken into account based on the phenomenological Ginzburg-Landau theory. By the Clausius-Clapeyron relation, the magnetic entropy change depends not onl…
Abstract Two models, E-S and R-S unit cell models, are presented based on the thermal-electrical analogy technique. The analytical expressions for transverse thermal conductivities of unidirectional composites are derived. The dimensionless effective transverse thermal conductivities ke+ are expressed as a function of…
The superelasticity of a shape memory alloy (SMA) is exploited in a new form: a pseudo-rubber metal, which is a damping material used in vibration control. After taking some technical measures, SMA pseudo-rubber metal was made successfully. A damper composed of two pseudo-rubber metal damping elements is presented and…
Silica films with controlled thickness and refractive index have been formed by the sequential adsorption of a cationic polyelectrolyte and silica sols. The conditions used to prepare the sol were varied, and allowed films with refractive indices as low as 1.16 to be obtained. The sequential adsorption technique allow…
In this paper, we report the synthesis of several poly(propyl ether imine) dendrons and dendrimers. These dendrons and dendrimers were constructed by involving an ether as the linker component and an imine as the branching component. The divergent syntheses of dendrons and dendrimers were established with the aid of t…
Abstract The kinetics of nonisothermal crystallization of polypropylene (PP) containing nanoparticles of silicon dioxide (SiO 2 ) were investigated by differential scanning calorimetry (DSC) at various cooling rates. Several different analysis methods were used to describe the process of nonisothermal crystallization.…
Static and time-dependent density functional calculations, geometrically optimized and including all electrons, are described for silicon nanocrystals as large as Si(87)H(76), which contains 163 atoms. We explore and predict the effect that different sp(3) passivation schemes-F or H termination, thin oxide shell, or a…
Herein, we present results from a computational study of dinickel complexes that are relevant to the catalytic hydrolysis of urea exerted by the urease enzymes. The B3LYP density functional is used to characterize the equilibrium geometry, electronic and magnetic properties, and energies for a series of realistic comp…
The compound [CeIVMnIII8O8(O2CMe)12(H2O)4].4H2O (1.4H2O) has been obtained from a template synthesis involving the reaction of the chain polymer {[MnIII(OH)(O2CMe)2] .(MeCO2H).(H2O)}n (3) with Ce(IV). Compound 1 contains a MnIII8 loop inside which is held the Ce(IV) ion by the bridging oxide ions. Magnetization and ma…
Shape memory polymers (SMPs) have the capacity to recover large strains when pre-deformed at an elevated temperature, cooled to a lower temperature and reheated. The thermomechanical recovery behavior of an SMP is examined in three-point flexure for various pre-deformation and recovery conditions. Results indicate tha…
Radical Theory of Rings distills the most noteworthy present-day theoretical topics, gives a unified account of the classical structure theorems for rings, and deepens understanding of key aspects of ring theory via ring and radical constructions. Assimilating radical theory's evolution in the decades since the last m…
Abstract Composites based on phenolic matrices and both untreated and alkali and ionized air–treated jute fibers were prepared. Different fiber lengths and fiber content were used to reinforce the phenolic matrices. The jute fibers were characterized with respect to lignin, holocellulose, ash, and humidity contents an…
Abstract Particle laden polymers are one of the most prominent thermal interface materials (TIM) used in electronics cooling. Most of the research has primarily dealt with the understanding of the thermal conductivity of these types of TIMs. For thermal design, reduction of the thermal resistance is the end goal. Ther…
Local effects of multiple electrostatic gates placed beneath carbon nanotubes grown by chemical vapor deposition (CVD) are reported. Single-walled carbon nanotubes were grown by CVD from Fe catalyst islands across thin Mo “finger gates” (∼150 nm × 10 nm). Prior to tube growth, several finger gates were patterned litho…
We express the cross section for indirect resonant inelastic X-ray scattering in terms of an intrinsic dynamic correlation function of the system that is studied with this technique. The cross section is a linear combination of the charge response function and the dynamic longitudinal spin density correlation function…
A novel approach is proposed, where energy filtered electrons, carrying both chemical identity and electrical information, serve as fine and flexible electrodes in direct electrical measurements. The method, termed 'chemically resolved electrical measurements' (CREM), is simple and general, demonstrated here with a sl…
The modeling of finite-extent semiconductor nanostructures that are embedded in a host material requires the numerical treatment of the boundary in a finite simulation domain. For the study of a self-assembled InAs dot embedded in GaAs, three kinds of boundary conditions are examined within the empirical tight-binding…
Some of the most popular ways to treat quantum critical materials, that is, materials close to a magnetic instability, are based on the Landau functional. The central quantity of such approaches is the average magnitude of spin fluctuations, which is very difficult to measure experimentally or compute directly from th…
A theory is formulated for time dependent fluctuations of the spectrum of a single molecule in a dynamic environment. In particular, we investigate the photon counting statistics of a single molecule undergoing a spectral diffusion process. Based on the stochastic optical Bloch equation, fluctuations are characterized…