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Detection of temperature-induced molten globule states in small, β-sheet-rich proteins by infrared spectroscopy

Maurizio Baldassarre、Andrea Scirè、Fabio Tanfani2012-08-01Biomedical Spectroscopy and Imaging

The study of the mechanisms underlying formation of molten globule states in proteins is gaining growing interest due to recent discoveries concerning the involvement of this folding intermediate in several biological processes and to the possibility it offers to clarify the general process of protein folding. Differe…

Protein Structure and DynamicsProteins in Food SystemsEnzyme Structure and Function

Theoretical investigation on tautomerism and NBO analysis of 3-hydroxy-1,2,5-thiadiazole derivatives: solvent and substituent effects

Meisam Shabanian、Mohsen Hajibeygi、Hassan Moghanian 等 4 位作者2012-08-01Heterocyclic Communications

Abstract Thiadiazole compounds including 3-hydroxy-4-substituted-1,2,5-thiadiazole are known as non-nucleoside inhibitors of HIV-1. Density functional calculations at the B3LYP/6-311++G(d,p) level were employed to determine the stability, tautomerism, and substituent effects of 1,2,5-thiadiazole, a widely used skin-wh…

Synthesis and biological activityNonlinear Optical Materials ResearchOrganic Chemistry Cycloaddition Reactions

Influence of Erosion and Deposition on Metallic First Mirror in HT-7 Tokamak

Ju Chen、Rong Yan、Junling Chen2012-08-01Plasma Science and Technology

Dedicated experiments in the HT-7 tokamak were performed to investigate the influence of erosion and deposition on the mirror samples. The first mirror (FM) samples made of polycrystalline (PC) stainless steel (SS), molybdenum (Mo) and tungsten (W) were fixed on a holder at an angle of 45° with respect to the horizont…

Magnetic confinement fusion researchLaser-Plasma Interactions and DiagnosticsFusion materials and technologies

Cathode-Control Alloying at an Au-ZnSe Nanowire Contact via in Situ Joule Heating

Yaping Zeng、Yanguo Wang、Baihua Qu 等 4 位作者2012-08-01Chinese Physics Letters

Controllable interfacial alloying is achieved at a Au-ZnSe nanowire (M-S) contact via in situ Joule heating inside transmission electron microscopy (TEM). TEM inspection reveals that the Au electrode is locally molten at the M-S contact and the tip of the ZnSe nanowire is covered by the Au melting. Experimental eviden…

Advanced Thermoelectric Materials and DevicesMolecular Junctions and NanostructuresNanowire Synthesis and Applications

Organo Montmorillonite Nanoclay: Alternative Modifier to Sustain Durability of Asphalt Pavement

G Liu、M.F.C. van de Ven、A A A Molenaar 等 4 位作者2012-08-01Transportation research circular

Three types of montmorillonite (Mt) clay (one natural and two organo) with 4 wt% were used to modify bitumens with different penetration grades. X-ray diffraction (XRD) was employed to observe structures of Mt in bitumen. Rolling thin film oven testing (RTFOT) and pressure-aging vessel (PAV) methods were used to simul…

Asphalt Pavement Performance EvaluationPolymer Nanocomposites and PropertiesInfrastructure Maintenance and Monitoring

Synthesis and crystal structure of Co(III) dioximates with the complex anion [SbF6]−

Eduard B. Coropceanu、A. Rija、Vasile Lozan 等 8 位作者2012-08-01Russian Journal of Coordination Chemistry

The complexes [Co(DioxH) 2 L 2 ][SbF 6 ] · n H 2 O, where DioxH is dimethylglyoxime monoanion (DioxH − ) or 1,2-cyclohexanedione dioxime (NioxH − ), L is aniline (An) or triphenylphosphine (PPh 3 ), were isolated from the CoX 2 · n H 2 O-NaSbF 6 -DioxH 2 -L system (X = F or CH 3 COO) in aqueous methanol. The complexes…

Magnetism in coordination complexesFluorine in Organic ChemistryInorganic Fluorides and Related Compounds

The experimental verification of mathematical two-plate model describing the metal deposition/dissolution process

Piotr M. Skitał、Przemysław T. Sanecki2012-08-01Russian Journal of Electrochemistry

The advanced two-plate model with BET adsorption equation has been verified by the use of the experimental Cu 2+ /Cu 0 system in 1 M NaClO 4 /pH 3 solution at different scan rates and at 5, 10, 25 mM concentrations of Cu 2+ . A change of electrode properties during electrode process was included into the applied model…

Corrosion Behavior and InhibitionElectrodeposition and Electroless CoatingsElectrochemical Analysis and Applications

Application Technology of Bamboo Reinforced Concrete in Building Structure

Wei Zhao、Jing Zhou、Guo Bin Bu2012-08-01Applied Mechanics and Materials

Bamboo is mainly a tropical and subtropical plant which is found adequate in many countries. The strength of bamboo as concrete reinforcement is much lower than steel bar reinforcement. However, one of the merits is a cheap and replenishable agricultural resource and abundantly available. Due to excellent properties l…

Natural Fiber Reinforced CompositesBamboo properties and applicationsTree Root and Stability Studies

Guided-mode resonances in dielectric photonic crystal slabs with low index contrast

Thomas Kusserow、Yousuf Khan、Ricardo Zamora 等 5 位作者2012-08-01OpenAlex

We present nanophotonic structures consisting of a dielectric slab waveguide with low index contrast and photonic crystals. The guided-mode resonance effect is used to implement elements with selective reflection properties. The design procedure, including numerical simulations, as well as a fabrication approach emplo…

Photonic and Optical DevicesPhotonic Crystals and ApplicationsOptical Coatings and Gratings

Densification and properties of ODS‐iron based alloy

Zhimeng Guo、Qing Liu、Weiwei Yang 等 4 位作者2012-08-01Rare Metals

Abstract Y 2 O 3 dispersion strengthened iron‐based powders and oxide dispersion strengthened (ODS) alloys were prepared by hydrothermal synthesis and spark plasma sintering (SPS), respectively. The effects of Y 2 O 3 , vibratory milling treatment, and Ti element on the microstructure and mechanical properties of the…

High-Temperature Coating BehaviorsMetallurgical Processes and ThermodynamicsNuclear Materials and Properties

Dye-sensitized solar cells using graphene-based counter electrode

Kai‐Hsiang Hung、Yi‐Sheng Li、Hong‐Wen Wang2012-08-01OpenAlex

Graphene film was fabricated using graphene oxide (GO) prepared from a modified Hummers' method. The reduction of GO (rGO) was accomplished by coating the GO paste on a piece of glass and immersing into a Ti+3solution. The freeze drying (FD) process employed for drying GO before its forming of paste and coating into a…

TiO2 Photocatalysis and Solar CellsAdvanced Photocatalysis TechniquesGraphene research and applications

Pressure free sintering of silver nanoparticles to silver substrate using weakly binding ligands

R. Durairaj、Roya Ashayer、Hiren R. Kotadia 等 7 位作者2012-08-01OpenAlex

The use of a weakly binding ligand to facilitate sintering between particles and a planar substrate in the absence of pressure and at low homologous temperature has been explored. Ag nanoparticles in the 5-15 nm range suspended in water and stabilized by a BH4complex were dropped onto a polished Ag substrate heated to…

Block Copolymer Self-AssemblyNanomaterials and Printing Technologiesnanoparticles nucleation surface interactions

Optimization of exposure parameters for lift-off process of sub-100 features using a negative tone electron beam resist

Diana C. Leitão、Rita Macedo、Ana V. Silva 等 8 位作者2012-08-01OpenAlex

A thorough study of exposure parameters for electron beam lithography using AR7520 negative tone electron beam resist is here presented. We optimized the beam voltage, apertures diameter and resist thickness in order to achieve the smaller dimensions possible for each resist thicknesses. Monte Carlo simulations of the…

Semiconductor materials and devicesAdvancements in Photolithography TechniquesElectron and X-Ray Spectroscopy Techniques

Size-dependent surface tension of a cylindrical nanobubble in liquid Ar

Hong Yan、Ru-Zeng Zhu、Jiu-An Wei2012-08-01Chinese Physics B

In view of the continued disputes on the fundamental question of whether the surface tension of a vapour bubble in liquid argon increases, or decreases, or remains unchanged with the increase of curvature radius, a cylindrical vapour bubble of argon is studied by molecular dynamics simulation in this paper instead of…

Catalytic Processes in Materials ScienceMinerals Flotation and Separation Techniquesnanoparticles nucleation surface interactions

Histologic and histomorphometric evaluation of an implant retrieved 8 years after insertion in a sinus augmented with anorganic bovine bone and anorganic bovine matrix associated with a cell-binding peptide: a case report.

Marco Degidi、Adriano Piattelli、Vittoria Perrotti 等 4 位作者2012-08-01PubMed

Few histologic and histomorphometric reports are present in the literature regarding the peri-implant bone response around implants inserted in sinuses grafted with different biomaterials. Anorganic bovine bone (ABB) and anorganic bovine matrix with the addition of an active cell-binding peptide (PepGen P-15) are xeno…

Bone Tissue Engineering MaterialsDental Implant Techniques and OutcomesElectrospun Nanofibers in Biomedical Applications

Hydrous fluid as the growth media of natural polycrystalline diamond, carbonado: Implication from IR spectra and microtextural observations

Hidemi Ishibashi、H. Kagi、H. Sakuai 等 5 位作者2012-08-01American Mineralogist

Carbonado, a variety of natural polycrystalline diamond whose origin remains unknown, differs notably in the properties from common diamonds of mantle origin. In this study, infrared spectroscopic and microscopic analyses were conducted on carbonado from the Central African Republic. Stepwise heating followed by infra…

Geological and Geochemical AnalysisHigh-pressure geophysics and materialsDiamond and Carbon-based Materials Research

M/DBT, new alternative dielectric liquids for transformers

Janine Walker、A.Valot、Zhongdong Wang 等 5 位作者2012-08-01Research Explorer (The University of Manchester)

Mono/dibenzyltoluene (M/DBT) is based on synthetic aromatic hydrocarbons. It is an insulating liquid with specifications meeting standard IEC 60867 where it is defined as methylpolyarylmethane derivatives. M/DBT has been used in high voltage capacitors for over 25 years. It has also been approved for other electrical…

High voltage insulation and dielectric phenomenaPower Quality and HarmonicsPower Transformer Diagnostics and Insulation

Multi-physics modeling of LED-based luminaires under temperature and humidity environment

Hongyu Tang、Daoguo Yang、G. Q. Zhang 等 7 位作者2012-08-01OpenAlex

The purpose of this work is to conduct the multi-physics simulation analysis of LED-based luminaires under certain temperature and humidity environment, and to find out the vulnerable spot of the luminaire. The coupled modeling of LED luminaire during step stress accelerated test (SSAT) is simulated by ANSYS. Five typ…

Mechanical Behavior of CompositesSilicone and Siloxane ChemistryStructural Analysis of Composite Materials

Sub-60 nm Periodic Grating Feature Patterning by Immersion Based 364 nm Laser Interference

Raghuraman Sidharthan、V. M. Murukeshan、Krishnan Sathiyamoorthy2012-08-01Journal of Nanoscience and Nanotechnology

In this paper, we report a methodology to fabricate high resolution periodic grating features using high index prism based interferometer and i-line laser source. Features with sub-60 nm half pitch size were fabricated on i-line resist in an immersion medium using a prism of high index 1.939.

Photonic and Optical DevicesAdvanced Optical Imaging TechnologiesOptical Coatings and Gratings

Comparison of square and hexagonal fuel lattices for high conversion PWRs

Dan Kotlyar、Eugene Shwageraus2012-08-01Kerntechnik

Abstract This paper reports on an investigation into fuel design choices of a pressurized water reactor operating in a self-sustainable Th-233U fuel cycle. In order to evaluate feasibility of this concept, two types of fuel assembly lattices were considered: square and hexagonal. The hexagonal lattice may offer some a…

Nuclear reactor physics and engineeringNuclear Materials and PropertiesNuclear and radioactivity studies