Materials Literature
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A new photoremovable protecting group, (6-hydroxy-3-oxo-3H-xanthen-9-yl)methyl (1), with a molar absorption coefficient ε of ∼4 × 10(4) m(-1) cm(-1) at ∼520 nm for the release of carboxylates or phosphates is reported. Three derivatives of 1 (diethyl phosphate, acetate, and bromide) were isolated as complexes with DDQ…
We report detailed Seebeck coefficient, Hall resistivity, as well as specific heat measurement on Ca${}_{3}$Ir${}_{4}$Sn${}_{13}$ single crystals. The Seebeck coefficient exhibits a peak corresponding to the anomaly in resistivity at ${T}^{*}$, and the carrier density is suppressed significantly below ${T}^{*}$. This…
Exotic vortex states with long range attraction and short range repulsion have recently been proposed to arise in superconducting hybrid structures and multi-band superconductors. Using large scale simulations we examine the static and dynamic properties of such vortex states interacting with random and periodic pinni…
We present a model for the effect of stress on thin amorphous films that develop atop ion-irradiated silicon, based on the mechanism of ion-induced anisotropic plastic flow. Using only parameters directly measured or known to high accuracy, the model exhibits remarkably good agreement with the wavelengths of experimen…
Anomalous anisotropy of work function values in ternary alkali metal transition metal acetylides is reported. Work function values of some characteristic surfaces in these emerging semiconducting materials may differ by more than 2 eV as predicted by density functional theory calculations. This large anisotropy is a c…
We present a new methodology to solve the Anderson impurity model, in the context of dynamical mean-field theory, based on the exact diagonalization method. We propose a strategy to effectively refine the exact diagonalization solver by combining a finite-temperature Lanczos algorithm with an adapted version of the cl…
The toxic effects of silver nanoparticles (AgNPs) on cells are well established, but only limited studies on the effect of AgNPs and silver ions on the cellular transcriptome have been performed. In this study, the effect of AgNPs on the gene expression in the human lung epithelial cell line A549 exposed to 12.1 µg/ml…
Using mesa array of $\rm{Bi_{2}Sr_{2}CaCu_{2}O_{8}}$ single crystal was demonstrated recently as a promising route to enhance the radiation power generated by Josephson oscillations in mesas. We study the synchronization in such an array via the plasma waves in the base crystal. First, we analyze plasma oscillations i…
The optical conductivity ${\ensuremath{\sigma}}_{1}(\ensuremath{\omega})$ and the spectral weight $SW$ of four topological insulators with increasing chemical compensation (${\mathrm{Bi}}_{2}{\mathrm{Se}}_{3},\phantom{\rule{0.28em}{0ex}}{\mathrm{Bi}}_{2}{\mathrm{Se}}_{2}\mathrm{Te},\phantom{\rule{0.28em}{0ex}}{\mathrm…
By using the $\stackrel{\ensuremath{\rightharpoonup}}{k}\ifmmode\cdot\else\textperiodcentered\fi{}\stackrel{\ensuremath{\rightharpoonup}}{p}$ method, we propose a first-principles theory to study the linear dispersions in phononic and photonic crystals. The theory reveals that only those linear dispersions created by…
A pure spin current generated within a nonlocal spin valve can exert a spin transfer torque on a nanomagnet. This nonlocal torque enables new design schemes for magnetic memory devices that do not require the application of large voltages across tunnel barriers that can suffer electrical breakdown. Here we report a qu…
A comparative study of unloaded Q-factor measurements of a TE011 mode sapphire dielectric resonator with unloaded Q-factor value of 731,000 at a frequency of 10 GHz and temperature of 65 K using two best Q-factor measurement methods are presented. The Transmission (TMQF) and Reflection methods are based on relevant mu…
Carbon materials are excellent candidates for photovoltaic solar cells: they are Earth-abundant, possess high optical absorption, and superior thermal and photostability. Here we report on solar cells with active layers made solely of carbon nanomaterials that present the same advantages of conjugated polymer-based so…
We demonstrate a simple network-analyzer technique to make quantitative measurements of the bias dependence of spin torque in a magnetic tunnel junction. We apply a microwave current to exert an oscillating spin torque near the ferromagnetic resonance frequency of the tunnel junction's free layer. This produces an osc…
Structural Fe in clay minerals is an important, albeit poorly characterized, redox-active phase found in many natural and engineered environments. This work develops an experimental approach to directly assess the redox properties of a natural Fe-bearing smectite (ferruginous smectite, SWa-1, 12.6 wt % Fe) with mediat…
Our previous studies have demonstrated that a generation 5 dendrimer (G5) conjugated with both folic acid (FA) and methotrexate (MTX) has a higher chemotherapeutic index than MTX alone. Despite this, batch-to-batch inconsistencies in the number of FA and MTX molecules linked to each dendrimer led to conjugate batches…
We use multipulse dynamical decoupling to increase the coherence lifetime (${T}_{2}$) of large numbers of nitrogen-vacancy (NV) electronic spins in room temperature diamond, thus enabling scalable applications of multispin quantum information processing and metrology. We realize an order-of-magnitude extension of the…
Colloidal particles have the right size to form ordered structures with periodicities comparable to the wavelength of visible light. The tantalizing colours of precious opals and the colour of some species of birds are examples of polycrystalline colloidal structures found in nature. Driven by the demands of several e…
The assembly of noble metal nanoparticles offers an appealing means to control and enhance the plasmonic properties of nanostructures. However, making nanoassemblies with easily modifiable gap distances with high efficiency has been challenging. Here, we report a novel strategy to assemble gold nanoparticles (AuNPs) i…
A link between structural ordering and slow dynamics has recently attracted much attention from the context of the origin of glassy slow dynamics. Candidates for such structural order are icosahedral, exotic amorphous and crystal-like. Each type of order is linked to a different scenario of glass transition. Here we e…