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Dioxygen binding of water-soluble iron(ii) porphyrins in phosphate buffer at room temperature

Christian Ruzi、Pascale Even‐Hernandez、Bernard Boitrel2007-01-01Organic & Biomolecular Chemistry

Two water-soluble tris(2-aminoethylamine) (tren) capped iron porphyrins were synthesized. The stability of their dioxygen adducts was studied in phosphate buffer, leading to half-life times around 7 min for the oxygenated species.

Porphyrin and Phthalocyanine ChemistryMetal-Catalyzed Oxygenation MechanismsHemoglobin structure and function

Life Cycle Analysis of Environmental Load from Polyvinyl Chloride Products

Katsuhito Nakazawa、Seiji SAKAI、Keiichi Katayama 等 4 位作者2007-01-01Journal of the Japan Institute of Energy

Polyvinyl chloride (PVC) is a material with advantages of productivity, recyclability and economy, and that is applied to various products such as pipes, films and electric cables. On the other hand, it is limited that the PVC products are used because of excessive fear to chemical substances generated by the combusti…

Recycling and Waste Management TechniquesPolymer Science and PVC

3D Finite Element Modeling of the Swage Autofrettage Process Including the Bauschinger Effect

Edward Troiano、John H. Underwood、Rolf R. de Swardt 等 6 位作者2007-01-01OpenAlex

The autofrettage process is a method that produces tensile plastic deformation during the overloading of a pressure vessel which reverses and becomes compressive during unloading. This process produces favorable compressive residual hoop stresses at the bore of the pressure vessel, and results in an increase in the li…

Fatigue and fracture mechanicsEngineering Structural Analysis MethodsMaterial Properties and Failure Mechanisms

Influence of Hydrostatic Pressure on Magnetic Properties of (Sr,La)(Ru,Cr,Mn)O3

Jarosław Piętosa、A. Wiśniewski、R. Puźniak 等 6 位作者2007-01-01Acta Physica Polonica A

An influence of hydrostatic pressure, P , on phase transition temperature, T C , and spontaneous magnetisation, M 0 , of selected perovskite ruthenates (SrRuO3, La0.2Sr0.8RuO3, SrRu0.9Mn0.1O3, and SrRu0.9Cr0.1O3) was determined to 12 kbar. A decrease in T C with pressure was found for all of the studied samples. The M…

Magnetic and transport properties of perovskites and related materialsMultiferroics and related materialsAdvanced Condensed Matter Physics

Genetic Algorithm for Structural Optimization of Tubular Nanostructures

Teresa Davies、Mihail M. Popa、Cristian V. Ciobanu 等 5 位作者2007-01-01AIP conference proceedings

Why can metals or oxides form nanotubes, sometimes even chiral ones? How could silicon, which has little or no propensity for sp2 hybridization, form nanotubes akin with the well understood carbon nanotubes in which the atoms are unequivocally sp2 hybridized? It would be perhaps beneficial, if not expected, for the th…

Graphene research and applications2D Materials and ApplicationsMachine Learning in Materials Science

Mechanical And Microstructural Aspects Of High Temperature Formability Of AZ31 Sheets

S. Spigarelli、E. Evangelìsta、Mohamad El Mehtedi 等 4 位作者2007-01-01AIP conference proceedings

The high temperature formability of AZ31 magnesium alloy sheets has been investigated in the temperature from 150 to 350°C. The different straining conditions have been studied by using sheet blanks with several length to width ratios, and Forming Limit Diagrams were then obtained. As expected, an increase in temperat…

Magnesium Alloys: Properties and ApplicationsAluminum Alloy Microstructure PropertiesMetal Forming Simulation Techniques

Valve morphology of Amphora chilensis Hustedt (Bacillariophyceae)

S.E. Sala、José María Guerrero、Michel Coste2007-01-01HAL (Le Centre pour la Communication Scientifique Directe)

Plankton and epilithon samples containing Amphora chilensis Hustedt, collected from rivers in Argentina and type material of the species, have been examined using light (LM) and scanning electron microscopy (SEM). This species has been previously recorded as fossil from a\ndesert in northern Chile and as living from a…

Diatoms and Algae Research

New Development in Through Hardened Bearing Steel Grades for Use in Contaminated Lubrication

P. Daguier、Oliver Roesch、Werner Trojahn2007-01-01OpenAlex

Bearing steel quality has been improved over the past decades by reducing the level and the size of nonmetallic inclusions. Therefore, fatigue lifetime of bearings Is mainly governed by surface damage, such as debris denting due to foreign particles. Numerous studies have been performed to find out new steel grades or…

Microstructure and Mechanical Properties of SteelsMetallurgy and Material FormingMetal Alloys Wear and Properties

Effect of boron on microstructure and mechanical properties of low carbon microalloyed steels

Yu Lu2007-01-01Open MIND

Low carbon bainitic steels microalloyed with Nb, Ti and V are widely used for the pipeline, construction and automobile industries because of their excellent combination of strength, toughness and weldability. Boron as another major alloying element has been also frequently used in this type of steels since the 1970s.…

Metal and Thin Film MechanicsMetal Alloys Wear and PropertiesMaterial Properties and Applications

Magnetic and Dielectric Behavior of the Ruthenium Double Perovskite Oxides R2MRuO6 (R=La, Pr and Nd, M=Mg, Co, Ni and Zn)

Kenji Yoshii、Naoshi Ikeda、Shigeo Mori 等 7 位作者2007-01-01Transactions of the Materials Research Society of Japan

Magnetic and dielectric properties of the ruthenium double perovskites R 2 MRu0 6 were studied (R=La, Pr and Nd, M=Mg, Co, Ni and Zn). For R=La, the materials with the magnetic lvf+ ions (M=Co and Ni) showed magnetic ordering and large dielectric constants ( ~5000). On the other hand, for the non-magnetic Jvf+ ions (M…

Magnetic and transport properties of perovskites and related materialsMultiferroics and related materialsAdvanced Condensed Matter Physics

Preparation of Anisotropic Metal Dimer Array on Glass Substrate Showing Intense Surface-Enhanced Raman Scattering

Mai Takase、Y Sawai、Hideki Nabika 等 4 位作者2007-01-01Transactions of the Materials Research Society of Japan

Structure of the Ag and Au dot dimers arrayed on a glass substrate was optimized to exhibit intense surface-enhanced Raman scattering (SERS) of adsorbed 4,4'bipyridine molecule in an aqueous solution. The substrates with the Ag and Au dimers show clear optical anisotropy correlated to the polarization direction of the…

Gold and Silver Nanoparticles Synthesis and ApplicationsQuantum Dots Synthesis And PropertiesNanomaterials and Printing Technologies

STUDYING THE STRESSED-STRAINED STATE OF STAINLESS STEELSTRUCTURES WORKING UNDER INTENSIVETHERMAL-RADIATION LOADING

С. А. Капустин、В. А. Горохов、O. Yu. Vilenskiy 等 6 位作者2007-01-01Problems of Strength and Plasticity

The paper examines basic experimental relations and mathematical models describing the main laws of behaviour of stainless steels under intensive thermal-radiation loading, as well as the basic methodological postulates used in the program for analyzing elements and units of supporting structures under quasistatic str…

Material Properties and ApplicationsEngineering Diagnostics and ReliabilityMaterial Properties and Failure Mechanisms

Boundary‐Roughness Effects in Nematic Liquid Crystals

Paolo Biscari、Stefano Turzi2007-01-01SIAM Journal on Applied Mathematics

We study the equilibrium configuration of a nematic liquid crystal bounded by a rough surface. The wrinkling of the surface induces a partial melting in the degree of orientation. This softened region penetrates the bulk up to a length scale which turns out to coincide with the characteristic wavelength of the corruga…

Liquid Crystal Research AdvancementsAdvanced Materials and MechanicsAdhesion, Friction, and Surface Interactions

MULTI-WALLED CARBON NANOTUBES MODIFIED BY POLY(VINYL PYRROLIDONE)

Jing Shang2007-01-01Acta Polymerica Sinica

MWNTs were modified by amphiphilic polymer poly(vinyl pyrrolidone) (PVP) with ultrasonic assistance methods.The modified MWNTs were characterized by Fourier transform infrared spectroscopy (FTIR),thermogravimetry (TG),high-resolution transmission electron microscopy (TEM) and Raman spectrum.The results show that the s…

Conducting polymers and applicationsElectrospun Nanofibers in Biomedical ApplicationsPolymer Nanocomposite Synthesis and Irradiation

Studies on Epoxy Resin/Montmorillonite Nanocomposites Cured with 4,4′-Diamino Diphenyl Ether Diphenyl Ketone

Cui Hua Ji2007-01-01OpenAlex

Ca-montmorillonite was directly modified by ion-exchang method using hexadecyl trimethyl ammonium bromide. The interlamellar spacing of the montmorillonite, corresponding to the(001) plane peak, increases from 1.49 nm for the purified MMT to 2.21 nm for the organophilic clay(C16-MMT). The epoxy resin/BADK/MMT nanocomp…

Epoxy Resin Curing ProcessesSynthesis and properties of polymersSilicone and Siloxane Chemistry

Study on the zero order reflection efficiency of subwavelength grating

Zhenqing Li2007-01-01Journal of the University of Shanghai for Science and Technology

Based on the rigorous coupled wave theory,the phenomenon that the zero order reflection efficiency of rectangular subwavelength grating varies with the wavelength is studied when incidence angle,azimuth and grating parameters are variant.The relatively rational parameters of grating are chosen according to the calcula…

Advanced Fiber Optic SensorsPhotonic and Optical DevicesOptical Coatings and Gratings

Improvement of Abrasion Resistance of Polydiene

Iwakazu Hattori、Toshihiro Tadaki2007-01-01NIPPON GOMU KYOKAISHI

The tire test was carried out by twelve tires, which were made of various BRs and SBRs. From these results, the overpowering correlation was glass transition temperature with abrasion resistance. Sn coupled SBR reacted with carbon black (CB), and the bound rubber was increased than that of the non-modified SBR, so the…

Synthesis and properties of polymersTribology and Wear Analysis

Bismuth aluminoborate Bi0.96Al2.37(B4O10)O: Synthesis and crystal structure

А. В. Егорышева、А. С. Канищева、Yu. F. Kargin 等 5 位作者2007-01-01Russian Journal of Inorganic Chemistry

The crystal structure of a new bismuth aluminoborate Bi0.96Al2.37(B4O10)O is studied by single-crystal X-ray diffraction. The Bi0.96Al2.37(B4O10)O single crystals are hexagonal (space group $$P\bar 6$$ 2m). The unit cell parameters are as follows: a = b = 4.587(4) Å, c = 2.253(9) Å, α = β = 90°, γ = 120°, V = 168.60 Å…

High-pressure geophysics and materialsCrystal Structures and PropertiesX-ray Diffraction in Crystallography

Species Diversity of Marine Planktonic Diatoms around Chang Islands, Trat Province

Kesorn Teanpisut、Sunan Patarajinda2007-01-01OpenAlex

In March 2003, the marine planktonic diatoms were collected from 27 stations around Chang Islands, Trat Province in the Gulf of Thailand. Two types of the plankton net were used as filtering 100 litres of seawater through 20 ∝m mesh size and obliquely towing 70 ∝m mesh size at 2 meters above the seafloor. The diatoms…

Marine and coastal ecosystemsDiatoms and Algae ResearchMarine Biology and Environmental Chemistry

FRACTOGRAPHIC INVESTIGATION OF FAILURES IN 316L STAINLESS STEEL ORTHOPEDIC CONDYLAR BLADE PLATE

F. Naghdi、Hassan Farhangi、Maryam Zahiri Azar 等 4 位作者2007-01-01OpenAlex

In this paper, premature fracture of two condylar blade plates that failed inside the thigh of two separate patients is investigated. Condylar blade plates made of 316L austenitic stainless steel are widely used for internal fixation and repair of femoral fractures in orthopedic surgery. Fracture of such plates could…

Orthopaedic implants and arthroplastyShape Memory Alloy TransformationsTitanium Alloys Microstructure and Properties