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Sinterability and Piezoelectric Properties of KNbO3Ceramics after Substituting Pb and Na for K

Shinjiro Tashiro、Hideki Nagamatsu、Kunihiro Nagata2002-11-30Japanese Journal of Applied Physics

Potassium niobate (KNbO 3 ) ceramics are usually porous due to their poor sinterabilty under ordinary firing in air, although the single crystal exhibits a large amount of piezoelectricity. We found a marked improvement in the sinterability of KNbO 3 ceramics on substituting a small amount of Pb for K. However, the am…

Acoustic Wave Resonator TechnologiesMicrowave Dielectric Ceramics SynthesisFerroelectric and Piezoelectric Materials

Defect Engineering for Control of Polarization Properties in SrBi 2 Ta 2 O 9

Yuji Noguchi、Masaru Miyayama、Kenichi Oikawa 等 6 位作者2002-11-30Japanese Journal of Applied Physics

Defect engineering to design for remanent polarization ( P r ) and coercive field ( E c ) in SrBi 2 Ta 2 O 9 (SBT) is proposed. Cation vacancies coupled with substituents or oxide vacancies are shown to play an essential role in determining the polarization properties. High-resolution neutron powder diffraction studie…

Ferroelectric and Piezoelectric MaterialsElectronic and Structural Properties of OxidesMicrowave Dielectric Ceramics Synthesis

Electrical Conduction Mechanism in Bi4Ti3O12Single Crystal

Masatake Takahashi、Yuji Noguchi、Masaru Miyayama2002-11-30Japanese Journal of Applied Physics

To reveal the influence of lattice defects on electrical conduction of bismuth titanate (Bi 4 Ti 3 O 12 : BIT), one of the bismuth layer structured ferroelectrics, changes in lattice parameters and weight by high-temperature annealing and the dependence of conductivity on oxygen partial pressure ( P o 2 ) were examine…

Geophysics and Sensor TechnologyFerroelectric and Piezoelectric MaterialsAcoustic Wave Resonator Technologies

Piezoelectric Properties of Spark-Plasma-Sintered (Na0.5K0.5)NbO3–PbTiO3Ceramics

Ruiping Wang、Rong‐Jun Xie、Tadashi Sekiya 等 7 位作者2002-11-30Japanese Journal of Applied Physics

In the search for high-performance piezoelectrics, (1- y )(Na 0.5 K 0.5 )NbO 3 – y PbTiO 3 ( y ≤0.50) solid solution has been prepared using the spark-plasma-sintering method. Dielectric investigation reveals that both the ferroelectric phase transition temperatures and the peak value of the dielectric constant are st…

Dielectric materials and actuatorsAcoustic Wave Resonator TechnologiesFerroelectric and Piezoelectric Materials

Spirooxazines: synthesis, structure, spectral and photochromic properties

Vladimir Lokshin、André Samat、Anatolii V Metelitsa2002-11-30Russian Chemical Reviews

The review surveys synthetic approaches to spiro[1,4]oxazines belonging to one of the most promising classes of organic photochromes. The relationships between the structures of spirooxazines and their spectral properties as well as characteristics of thermal and photoinduced processes are considered. The bibliography…

Organic Chemistry Cycloaddition ReactionsSynthesis of Indole DerivativesPhotochromic and Fluorescence Chemistry

Dielectric Properties of Fine-Grained BaTiO3Ceramics Doped with CaO

Yukio Sakabe、Nobuyuki Wada、Takashi Hiramatsu 等 4 位作者2002-11-30Japanese Journal of Applied Physics

Fine-grained dielectric ceramics, i.e., of 0.2 µm grain diameter, were obtained using Ca-doped BaTiO 3 powders consisting of particles 0.2 µm in diameter. The (Ba 1- x Ca x ) m TiO 3 ceramics ( x : 0–0.10, m : 1.003–1.009) showed a high dielectric constant and stable temperature dependence, which were provided by inte…

Ferroelectric and Piezoelectric MaterialsMicrowave Dielectric Ceramics SynthesisDielectric properties of ceramics

Fission of collapsing cavitation bubbles

Christopher E. Brennen2002-11-30Journal of Fluid Mechanics

High-speed observations clearly show that though a collapsing cavitation bubble approaches its minimum size as a coherent single volume, it usually reappears in the first rebounding frame as a cloud of much smaller bubbles or as a highly distorted single volume. This paper explores two mechanisms that may be responsib…

Nuclear Physics and ApplicationsCavitation Phenomena in PumpsUltrasound and Cavitation Phenomena

Chemical localization

V. F. Gantmakher2002-11-30Physics-Uspekhi

The current status of research and development in the realm of physics and technology of collective ion acceleration in systems with a virtual cathode (VC) is reviewed. Three major acceleration methods and devices developed on their basis are considered: reflex triodes and their modifications, gas-filled vircators, an…

Quasicrystal Structures and Properties

Spiral symmetry and general Bloch's theorem

Z. C. Tu2002-11-30arXiv

In this paper, spiral symmetry in cylindrical coordinate and general Bloch's theorem induced from it are discussed. This general Bloch's theorem is useful for considering the properties related to single-walled carbon nanotubes.

Materials ScienceMesoscale and Nanoscale Physics

Quantum tunneling of two coupled single-molecular magnets

J. M. Hu、Z. D. Chen、S. Q. Shen2002-11-30arXiv

Two single-molecule magnets are coupled antiferromagnetically to form a supramolecule dimer. We study the coupling effect and tunneling process by means of the numerical exact diagonalization method, and apply them to the recently synthesized supramoleculer dimer [Mn4]2 The model parameters are calculated for the dime…

Mesoscale and Nanoscale PhysicsMaterials Science

Singlet-energy transfer in quadruple hydrogen-bonded oligo(p-phenylenevinylene)perylene-diimide dyads

Edda E. Neuteboom、Edwin H. A. Beckers、Stefan C. J. Meskers 等 5 位作者2002-11-29Organic & Biomolecular Chemistry

The photophysical properties of a supramolecular donor-acceptor dyad consisting of an oligo(p-phenylenevinylene) unit and a perylene-diimide unit are described. The dyad is created by functionalising the two chromophores with quadruple hydrogen bonding 2-ureido-4[1H]-pyrimidinone units, which provide a high associatio…

Luminescence and Fluorescent MaterialsPorphyrin and Phthalocyanine ChemistryPhotochemistry and Electron Transfer Studies

Determining the structure of active sites, transition states and intermediates in heterogeneously catalysed reactions

John Meurig Thomas、C. Richard A. Catlow、Gopinathan Sankar2002-11-29Chemical Communications

With open-structure (nanoporous) oxidic solids, numerous distinct kinds of single-site catalysts may be precisely designed. Apart from serving as a means of generating a range of powerful new catalysts (especially for selective oxidations), in which well-defined active sites are carefully engineered, the detailed loca…

Catalysis and Oxidation ReactionsMesoporous Materials and CatalysisCatalytic Processes in Materials Science

Granular systems in the Coulomb blockade regime

D. P. Arovas、F. Guinea、C. Herrero 等 4 位作者2002-11-29arXiv

Disordered granular systems, at temperatures where charging effects are important, are studied, by means of an effective medium approximation. The intragrain charging energy leads to insulating behavior at low temperatures, with a well defined Coulomb gap. Non equilibrium effects can give rise to a zero temperature tr…

Materials ScienceStrongly Correlated ElectronsMesoscale and Nanoscale Physics

High quality GaMnAs films grown with As dimers

RP Campion、KW Edmonds、LX Zhao 等 7 位作者2002-11-29arXiv

We demonstrate that GaMnAs films grown with As2 have excellent structural, electrical and magnetic properties, comparable or better than similar films grown with As4. Using As2, a Curie temperature of 112K has been achieved, which is slightly higher than the best reported to date. More significantly, films showing met…

Materials Science

Phasons and the Plastic Deformation of Quasicrystals

Maurice Kleman2002-11-29arXiv

The plastic deformation of a quasicrystal (QC) is ruled by singularities of its 'phonon' strain field and of its 'phason' strain field. In the framework of the topological theory of defects, and the QC being defined as an irrational subset of a high dimensional crystal, both types of defects appear as distinct compone…

Materials Science

Ferroelectricity, SSFLC, bistability and all that

Ingolf Dahl2002-11-29arXiv

In the book "Ferroelectric and Antiferroelectric Liquid Crystals" by S. T. Lagerwall, the concept "polar liquid crystals" is proposed for the concept earlier known as "ferroelectric liquid crystals", reserving the word "ferroelectric liquid crystals" for the case of "surface stabilization". Thus Lagerwall in this way,…

Materials ScienceSoft Condensed Matter

Adsorbate-induced Surface Stiffening: Surface Lattice Dynamics of Ru(001)-(1x1)-O

T. Moritz、W. Widdra、D. Menzel 等 5 位作者2002-11-29arXiv

The dynamical properties of the high-density Ru(001)-(1$\times$1)-O phase has been investigated by a combined high-resolution electron energy loss spectroscopy and density functional theory study. Due to a strong static outward relaxation of the first Ru layer a soft Rayleigh phonon mode is expected. However, a Raylei…

Materials Science

Anisotropic Magnetoresistance in GaMnAs films

K. Y. Wang、K. W. Edmonds、R. P. Campion 等 8 位作者2002-11-29arXiv

The magnetoresistance in a series of Ga1-xMnxAs samples with 0.2 =< x =< 0.8 have been measured for three mutually orthogonal orientations of the external magnetic field. The anisotropy magnetoresistance decreases with increasing of the Mn content, which means that the magnetic disorder or defects scattering increases…

Materials ScienceMesoscale and Nanoscale Physics

In Vivo Imaging of Quantum Dots Encapsulated in Phospholipid Micelles

Benoît Dubertret、Paris A. Skourides、David J. Norris 等 6 位作者2002-11-29OpenAlex

Fluorescent semiconductor nanocrystals (quantum dots) have the potential to revolutionize biological imaging, but their use has been limited by difficulties in obtaining nanocrystals that are biocompatible. To address this problem, we encapsulated individual nanocrystals in phospholipid block-copolymer micelles and de…

Quantum Dots Synthesis And PropertiesRNA Interference and Gene DeliveryAdvanced biosensing and bioanalysis techniques