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Microporous Polystyrene Particles for Selective Carbon Dioxide Capture

M. Kaliva、Gerasimos S. Armatas、Maria Vamvakaki2012-01-04Langmuir

This study presents the synthesis of microporous polystyrene particles and the potential use of these materials in CO(2) capture for biogas purification. Highly cross-linked polystyrene particles are synthesized by the emulsion copolymerization of styrene (St) and divinylbenzene (DVB) in water. The cross-link density…

Carbon Dioxide Capture TechnologiesMembrane Separation and Gas TransportCovalent Organic Framework Applications

Design of a light-weight magnetic radar absorber embedded with resistive FSS

Sun Liang Kui、J. Wang、Hui Cheng 等 4 位作者2012-01-04META'12

In this letter, the design of a light-weight magnetic radar absorber (RA) having broadband bandwidth in frequency range of 1-18GHz is demonstrated. A 5mm-thick magnetic RA with weak wave absorbing performance is obtained on the basis of polyurethane foam filled with flake ferrous microwave absorbent. The use of freque…

Metamaterials and Metasurfaces ApplicationsElectromagnetic wave absorption materialsAdvanced Antenna and Metasurface Technologies

Microscopic Structures of Tri-n-butyl Phosphate/n-Octane Mixtures by X-ray and Neutron Scattering in a Wide q Range

Ryuhei Motokawa、Shinichi Suzuki、Hiroki Ogawa 等 5 位作者2012-01-04The Journal of Physical Chemistry B

Tri-n-butyl phosphate (TBP) is an important extractant for separating hexavalent uranium and tetravalent plutonium from used nuclear fuel by solvent extraction. In such solvent extractions using TBP, the organic phase occasionally separates into two organic phases, namely, light and heavy organic phases. The latter on…

Radioactive element chemistry and processingLanthanide and Transition Metal ComplexesNMR spectroscopy and applications

Berry phase and the phase of the Shubnikov–de Haas oscillations in three-dimensional topological insulators

G. P. Mikitik、Yu. V. Sharlaı̆2012-01-04Physical Review B

Within the semiclassical approach, we calculate contributions of the Berry phase and of the Zeeman coupling of an electron moment with the magnetic field to the phase of the Shubnikov--de Haas oscillations for the surface electrons in the Bi${}_{2}$$X$${}_{3}$ family of three-dimensional topological insulators ($X$ st…

Graphene research and applicationsTopological Materials and PhenomenaQuantum Mechanics and Non-Hermitian Physics

A BODIPY‐Based Highly Selective Fluorescent Chemosensor for Hg2+ Ions and Its Application in Living Cell Imaging

Mani Vedamalai、Shu‐Pao Wu2012-01-04European Journal of Organic Chemistry

Abstract A new boron–dipyrromethene (BODIPY) derivative (FS1) containing two triazole units exhibits an enhanced fluorescence in the presence of Hg2+ ions and a high selectivity for Hg2+ ions over competing metal ions in methanol: Ag+, Ca2+, Cd2+, Co2+, Cu2+, Fe2+, Fe3+, K+, Mg2+, Mn2+, Ni2+, Pb2+, and Zn2+ produced o…

Advanced biosensing and bioanalysis techniquesMolecular Sensors and Ion DetectionLuminescence and Fluorescent Materials

Hydraulic Conductivity Increases in a Sodic Clay Soil in Response to Gypsum Applications

Lucy Reading、Thomas Baumgartl、Keith L. Bristow 等 4 位作者2012-01-04Soil Science

Amelioration of sodic soils is commonly achieved by applying gypsum, which increases soil hydraulic conductivity by altering soil chemistry. The magnitude of hydraulic conductivity increases expected in response to gypsum applications depends on soil properties including clay content, clay mineralogy, and bulk density…

Geotechnical Engineering and Soil MechanicsSoil and Unsaturated FlowClay minerals and soil interactions

Lower Rim 1,3-Di{4-antipyrine}amide Conjugate of Calix[4]arene: Synthesis, Characterization, and Selective Recognition of Hg2+and Its Sensitivity toward Pyrimidine Bases

Jayaraman Dessingou、Khatija Tabbasum、Atanu Mitra 等 5 位作者2012-01-04The Journal of Organic Chemistry

The structurally characterized lower rim 1,3-di{4-antipyrine}amide conjugate of calix[4]arene (L) exhibits high selectivity toward Hg(2+) among other biologically important metal ions, viz., Na(+), K(+), Ca(2+), Mg(2+), Mn(2+), Fe(2+), Co(2+), Ni(2+), Cu(2+), Zn(2+), Cd(2+), Hg(2+), Pb(2+), and Ag(+) as studied by flu…

Molecular Sensors and Ion DetectionSupramolecular Chemistry and ComplexesLuminescence and Fluorescent Materials

Role of Surface Charge and Hydrophobicity in the Three-Phase Contact Formation and Wetting Film Stability under Dynamic Conditions

Anna Niecikowska、Marta Krasowska、John Ralston 等 4 位作者2012-01-04The Journal of Physical Chemistry C

Determination and control of the parameters influencing three-phase contact formation and wetting film stability under dynamic conditions is important for both industrial applications and fundamental studies. Hydrophobicity profoundly affects not only the critical thickness of rupture but also the subsequent rate of t…

Surface Modification and SuperhydrophobicityFluid Dynamics and MixingMinerals Flotation and Separation Techniques

Probing the Effect of Conformational Constraint on Phosphorylated Ligand Binding to an SH2 Domain Using Polarizable Force Field Simulations

Yue Shi、Crystal Z. Zhu、Stephen F. Martin 等 4 位作者2012-01-04The Journal of Physical Chemistry B

Preorganizing a ligand in the conformation it adopts upon binding to a protein has long been considered to be an effective way to improve affinity by making the binding entropy more favorable. However, recent thermodynamic studies of a series of complexes of the Grb2 SH2 domain with peptide analogues having constraine…

Protein Structure and DynamicsCrystallography and molecular interactionsEnzyme Structure and Function

Effect of Lignin Incorporation and Reactive Compatibilization on the Morphological, Rheological, and Mechanical Properties of ABS Resin

Pingan Song、Zhenhu Cao、Qingrong Meng 等 7 位作者2012-01-04Journal of Macromolecular Science Part B

In order to develop the potential application of industrial alkali lignin, its acrylonitrile-butadiene-styrene (ABS) composites were fabricated via melt blending in the absence/presence of a compatibilizer. The lignin can uniformly disperse in the ABS matrix with number-average dispersed-phase domains of sub-micron sc…

Natural Fiber Reinforced CompositesAdvanced Cellulose Research StudiesLignin and Wood Chemistry

Dual-Wavelength Detection of Rotational Diffusion of Single Anisotropic Nanocarriers on Live Cell Membranes

Ji Won Ha、Wei Sun、Anthony S. Stender 等 4 位作者2012-01-04The Journal of Physical Chemistry C

Single-particle rotational tracking is of great importance to monitor orientation changes of biomolecules and to understand their functions and mechanisms in biological systems. Differential interference contrast (DIC) microscopy has been found to be an excellent tool to measure polarization anisotropy for tracking ro…

Gold and Silver Nanoparticles Synthesis and ApplicationsAdvanced biosensing and bioanalysis techniquesPlasmonic and Surface Plasmon Research

Entropic and Electrostatic Effects on the Folding Free Energy of a Surface-Attached Biomolecule: An Experimental and Theoretical Study

Herschel M. Watkins、Alexis Vallée‐Bélisle、Francesco Ricci 等 5 位作者2012-01-04Journal of the American Chemical Society

Surface-tethered biomolecules play key roles in many biological processes and biotechnologies. However, while the physical consequences of such surface attachment have seen significant theoretical study, to date this issue has seen relatively little experimental investigation. In response we present here a quantitativ…

Advanced biosensing and bioanalysis techniquesPolymer Surface Interaction StudiesNanopore and Nanochannel Transport Studies

Recovery of Bacillus cereus cyclodextrin glycosyltransferase and recycling of phase components in an aqueous two-phase system using thermo-separating polymer

Hui Suan Ng、Chin Ping Tan、Mohd Noriznan Mokhtar 等 7 位作者2012-01-04Separation and Purification Technology

An aqueous two-phase system (ATPS) composed of thermo-separating polymer and salt was deployed in this study for the recovery of Bacillus cereus cyclodextrin glycosyltransferase (CGTase) and recycling of phase components simultaneously. CGTase was recovered using ATPS over two successive extractions and the recycled p…

Extraction and Separation ProcessesCrystallization and Solubility StudiesChemical and Physical Properties in Aqueous Solutions

Antinociceptive and anti-ulcerogenic activities of the ethanolic extract of Annona muricata leaf

Roslida Abd Hamid、Chan Foong、Zuraini Ahmad 等 4 位作者2012-01-04Revista Brasileira de Farmacognosia

Ethanolic extract of Annona muricata L., Annonaceae, leaf (AML) was used to investigate its antinociceptive and anti-ulcerogenic activities and the involvement of the mechanism of ethanolic leaves extract of AML in various animal models. Antinociceptive activity of AML extract was done using acetic acid-induced abdomi…

Ethnobotanical and Medicinal Plants StudiesTraditional and Medicinal Uses of AnnonaceaePhytochemistry and Bioactive Compounds

Genomic Design of Strong Direct-Gap Optical Transition in Si/Ge Core/Multishell Nanowires

Lijun Zhang、Mayeul d’Avezac、Jun‐Wei Luo 等 4 位作者2012-01-04Nano Letters

Finding a Si-based material with strong optical activity at the band-edge remains a challenge despite decades of research. The interest lies in combining optical and electronic functions on the same wafer, while retaining the extraordinary know-how developed for Si. However, Si is an indirect-gap material. The conserv…

Silicon Nanostructures and PhotoluminescenceNanowire Synthesis and ApplicationsSemiconductor materials and interfaces

Ag(I) Complexes Containing FlexibleN,N′-Di(3-pyridyl)adipoamide Ligands: Syntheses, Structures, Ligand Conformations, and Crystal-to-Crystal Transformations

Pei-Chi Cheng、Chun‐Wei Yeh、Wayne Hsu 等 7 位作者2012-01-04Crystal Growth & Design

The reactions of N, N′ -di(3-pyridyl)adipoamide ( L ) with the corresponding silver(I) salts afforded the complexes {[Ag( L )](PF 6 )·2CH 3 CN} ∞, 1, {[Ag( L )](BF 4 )·CH 3 CN} ∞, 2, {[Ag( L )](NO 3 )·CH 3 CN} ∞, 3, {[Ag( L )](PF 6 )·4DMF} ∞, 4, {[Ag( L )](BF 4 )·4DMF} ∞, 5, {[Ag( L )](CF 3 SO 3 )·DMF} ∞, 6, {[Ag( L )…

Metal-Organic Frameworks: Synthesis and ApplicationsMetal complexes synthesis and propertiesMagnetism in coordination complexes

Three-dimensional temperature distribution and modification mechanism in glass during ultrafast laser irradiation at high repetition rates

Masahiro Shimizu、Masaaki Sakakura、Masatoshi Ohnishi 等 7 位作者2012-01-04Optics Express

We experimentally determined the three-dimensional temperature distribution and modification mechanism in a soda-lime-silicate glass under irradiation of ultrafast laser pulses at high repetition rates by analyzing the relationship between the morphology of the modification and ambient temperature. In contrast to prev…

Glass properties and applicationsLaser Material Processing TechniquesOcular and Laser Science Research

Synthesis Techniques, Properties and Applications of Polymer Nanocomposites

Jingfei Luan、Shu Wang、Zhitian Hu 等 4 位作者2012-01-04Current Organic Synthesis

The polymer nanocomposites are composed of different nanometer units and organic polymer materials. In this review article, we have summarized different novel nanometer units which can be divided into inorganic materials and organic materials. For (inorganic materials)-polymer nanocomposites, the nanometer units inclu…

Dendrimers and Hyperbranched PolymersInorganic and Organometallic ChemistryChemistry and Chemical Engineering

New Insights into the Adsorption of 3-(Trimethoxysilyl)propylmethacrylate on Hydroxylated ZnO Nanopowders

Christine Bressy、Van Giang Ngo、Fabio Ziarelli 等 4 位作者2012-01-04Langmuir

Functionalization of zinc oxide (ZnO) nano-objects by silane grafting is an attractive method to provide nanostructured materials with a variety of surface properties. Active hydroxyl groups on the oxide surface are one of the causes governing the interfacial bond strength in nanohybrid particles. Here, "as-prepared"…

Advanced Photocatalysis TechniquesSurface Modification and SuperhydrophobicityAdvanced Sensor and Energy Harvesting Materials

Nanocystals of Hematite with Unconventional Shape-Truncated Hexagonal Bipyramid and Its Optical and Magnetic Properties

Thanh Khue Van、Hyun Gil、Cuong K. Nguyen 等 6 位作者2012-01-04Crystal Growth & Design

The capping agent plays a critical function in anisotropic crystal growth to induce polyhedral morphology of a nanocrystal. Uniform and single-crystalline α-Fe 2 O 3 polyhedral nanoparticles in the hexagonal single crystal system named truncated hexagonal bipyramid for the first time were successfully synthesized by a…

Magnetic Properties and Synthesis of FerritesClay minerals and soil interactionsIron oxide chemistry and applications