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Synthesis and kinetics study of diiron-hydrogenase active site mimics

Katherine M. Macri2012-07-21Cardinal Scholar (Ball State University)

The hydrogenase enzyme is an effective replacement for the expensive platinum catalysts used in hydrogen fuel cells today. However, many enzymes themselves are found in extreme environments and are inactive under standard conditions, but current active site models have a much larger over-potential for H+ reduction tha…

Hydrogen Storage and MaterialsHybrid Renewable Energy SystemsMetalloenzymes and iron-sulfur proteins

Experience in the Production of Horizontal Ingots of Platinum Metals and Alloys

S D Levchenko、E N Vershinina2012-07-21贵金属

The quality of semi-products of platinum metals and alloys,produced by way of plastic working,essentially depends on or,in many cases,is completely determined by the quality of ingots.Plastic working does not make it possible to eliminate or localize metallurgical defects.In many cases it promotes the occurence thereo…

Metallurgical Processes and ThermodynamicsMaterial Properties and ApplicationsAdvanced Materials Characterization Techniques

Research Progress on AgSbTe2-based Thermoelectric Materials

Qigao Cao、Ma Guang、Zhihua Jia 等 5 位作者2012-07-21贵金属

Thermoelectric power generation represents a class of energy conversion technology,which has been used in power supply of aeronautic and astronautic exploring missions,now showing notable advantages to harvest the widely distributed waste heat and convert the abundant solar energy into electricity at lower cost than S…

Quantum Dots Synthesis And PropertiesAdvanced Thermoelectric Materials and DevicesChalcogenide Semiconductor Thin Films

The Effect of pH in Nickel Ferrite Nanoparticles Synthesis by Hydrothermal Method

Zeynep Karcıoğlu Karakaş、Recep Boncukçuoğlu、İbrahim Hakkı Karakaş 等 4 位作者2012-07-21Nanomaterials: Application & Properties '2012

In this study, NiFe2O4 nano particles was prepared with aqueous solutions of nickel nitrate and ferric nitrate salts. An appropriate ratio of solutions nickel nitrate and ferric nitrate were dissolved in deionized water and poured into a crucible. Later, polyethylene glycol 600 (PEG 600) was added to this mixture. Sam…

Magnetic Properties and Synthesis of Ferrites

ANALISIS WAKTU DAN PEMBIAYAAN UNTUK PROSES LOADOUT JACKET STRUCTURE MENGGUNAKAN DOLLY DAN SKIDWAY

Dhini Amelia Barlian2012-07-21OpenAlex

Konstruksi anjungan lepas pantai dibangun di perusahaan pembangun anjungan lepas pantai (offshore fabricator), dimana proses loadout merupakan salah tahapan pekerjaan yang dilakukan. Proses loadout dapat dilakukan dengan menggunakan tiga metode, yakni menggunakan skidway, lifting dan menggunakan dolly. Proses loadout…

Engineering Structural Analysis MethodsMaterial Selection and PropertiesMechanical Failure Analysis and Simulation

Science to Practice: How Will Myocardial Inflammation Be Imaged with MR Imaging?

David E. Sosnovik、Matthias Nahrendorf、Peter Caravan2012-07-21Radiology

The elegant study by Naresh and colleagues (1) synthesizes many of the best aspects of molecular magnetic resonance(MR) imaging: Quantitative serial imaging of a well-defined molecular process is performed in vivo, and its results are correlated with sensitive measures of left ventricular function. The technique descr…

Nanoparticle-Based Drug DeliveryProtease and Inhibitor MechanismsCardiovascular Disease and Adiposity

Synthesis of Water-soluble single-walled nanotubes by Functionalization Via Esterification

Javad Azizian、Mahdieh Entezari、Shahab Zomorodbakhsh 等 4 位作者2012-07-21Global Journal of Human Social Science

Water soluble compoundes were attached to single-walled carbon nanotubes (SWNTs) to form water- soluble nano dyes. functionalized SWNTs were then characterized by Fourier Transform Infrared spectroscopy (FT- IR), Raman spectroscopy, scanning electron microscopy (SEM) and UV analysis. The product can be dissolved in wa…

Carbon Nanotubes in CompositesGraphene research and applicationsFullerene Chemistry and Applications

Influence of anisotropy on the constraints field of a bicrystal (layer/substrate) under the effect of a network of interfacial dislocations

Mourad Brioua、Rafik Makhloufi、Rachid Benbouta2012-07-21Journal of the Association of Arab Universities for Basic and Applied Sciences

The purpose of this work is to model the monoscale predictive behavior and to reproduce certain experimental observations by using numerical simulation based on the theory of anisotropic elasticity. The latter allows us to express all the necessary expressions describing the strain field. The Fourier series expansion…

Microstructure and mechanical propertiesMicrostructure and Mechanical Properties of SteelsHigh Temperature Alloys and Creep

Synthesis and Crystal Structure of a One-dimensional Cu(II) Coordination Polymer Bridged by Inorganic CH3SO3− Anions Using Werner-type Cu(II) Complexes as Building Blocks

Shin‐ichiro Noro、Kazuya Kubo、Takayoshi Nakamura2012-07-21Chemistry Letters

Abstract The reaction of [Cu(PF6)2(py)4] (py: pyridine) with [Cu(CH3SO3)2(py)4], both of which are Werner-type Cu(II) complexes, in a MeOH solution led to the formation of a one-dimensional framework composed of [–{Cu(1)2(MeO)2}–Cu(2)–Cu(3)–Cu(3)–Cu(2)–] repeating units bridged by inorganic CH3SO3− anions.

Metal-Organic Frameworks: Synthesis and ApplicationsCrystal structures of chemical compoundsMagnetism in coordination complexes

Exploring spatial resolution in high-sensitivity nanogap quantum dot photodetectors

Ludan Huang、Matthew Strathman、Lih Y. Lin2012-07-21Optics Letters

We propose a new approach to experimentally determine the spatial resolution of nanogap quantum dot (QD) photodetectors consist of solution-processed QDs. Cross talk between a pair of closely positioned QD photodetectors was measured. Devices with 200 nm spacing exhibit low crosstalk of 8.4%. A single QD photodetector…

Semiconductor Quantum Structures and DevicesQuantum Dots Synthesis And PropertiesAdvanced Semiconductor Detectors and Materials

Nanogratings of fibronectin provide an effective biochemical cue for regulating focal adhesion and cellular structure

Lifang Shi、Jie-Ren Li、Yi-Ping Shih 等 5 位作者2012-07-21Nano Research

Integrin clustering, typically nanometers in dimension, is the first and an important step in integrin-mediated cellular signaling processes such as focal adhesion. Engineered nanostructures mimicking extracellular matrices (ECM) provide a new approach for investigation and regulation of this initial step and of downs…

Cellular Mechanics and InteractionsCell Adhesion Molecules ResearchSilk-based biomaterials and applications

Ultra-Stable oligonucleotide-gold and -silver nanoparticle conjugates prepared by a facile silica reinforcement method

Jacky K. F. Wong、Shea Ping Yip、Thomas M. H. Lee2012-07-21Nano Research

We report a simple method of enhancing the chemical stability of monothiol-modified oligonucleotide-gold and -silver nanoparticle conjugates by a thin silica reinforcement coating. Conventional conjugates prepared by chemisorption of monothiol-modified oligonucleotides onto nanoparticle surfaces undergo rapid aggregat…

Gold and Silver Nanoparticles Synthesis and ApplicationsAdvanced biosensing and bioanalysis techniquesNanocluster Synthesis and Applications

A new manganese-based oral contrast agent (CMC-001) for liver MRI: pharmacological and pharmaceutical aspects

Jan Trøst Jørgensen、Matthias Rief、Torkel B. Brismar 等 5 位作者2012-07-21Acta Radiologica

Manganese is one of the most abundant metals on earth and is found as a component of more than 100 different minerals. Besides being an essential trace element in relation to the metabolic processes in the body, manganese is also a paramagnetic metal that possesses similar characteristics to gadolinium with regards to…

Folate and B Vitamins ResearchTrace Elements in HealthLanthanide and Transition Metal Complexes

Production Of Spherical Ag/Zno Nanocomposite Particles For Photocatalytic Applications

Kamil Burak Dermenci、Burçak Ebin、Sebahattin Gürmen2012-07-21Zenodo (CERN European Organization for Nuclear Research)

Noble metal participation in nanostructured semiconductor catalysts has drawn much interest because of their improved properties. Recently, it has been discussed by many researchers that Ag participation in TiO2, CuO, ZnO semiconductors showed improved photocatalytic and optical properties. In this research, Ag/ZnO na…

Copper-based nanomaterials and applicationsNanomaterials for catalytic reactionsAdvanced Nanomaterials in Catalysis

Research on VO x uncooled infrared bolometer based on porous silicon

Bin Wang、Jianjun Lai、Erjing Zhao 等 5 位作者2012-07-21Frontiers of Optoelectronics

In this paper, vanadium oxide thin film of TCR of −3.5%/K has been deposited by pulsed DC magnetron sputtering method. The property of this VO x has been investigated by X-ray diffractometer (XRD) and atomic force microscopy (AFM) in detail. XRD test indicates that this film is composed of V2O3, V3O5 and VO2.VO x micr…

Gas Sensing Nanomaterials and SensorsTransition Metal Oxide NanomaterialsSilicon Nanostructures and Photoluminescence

Theoretical investigation of the use of doped graphene as a membrane support for effective CO removal in hydrogen fuel cells

D. J. Durbin、Cecile Malardier‐Jugroot2012-07-21Molecular Simulation

Carbon monoxide poisoning of the anode catalyst is currently a big problem facing the use of hydrogen fuel cells. This study uses density functional theory to model the interaction between a filter membrane and carbon monoxide to optimise the removal of CO from the H2 feed gas. The membranes studied are graphene/metal…

Advancements in Battery MaterialsElectrocatalysts for Energy ConversionGraphene research and applications

Nanostructured Metal-Enhanced Raman Spectroscopy for DNA Base Detection

Zhu Zhiqian、Li Zhan、Cailing Hou 等 4 位作者2012-07-21IEEE photonics journal

Periodic arrays of subwavelength apertures on Ag film are used as the substrates for nanohole-enhanced Raman spectroscopy. This study presents a rectangular bull's eye structure in an array. We demonstrate the quantitative features of the pattern by the finite-difference time-domain method. This structure is used to e…

Gold and Silver Nanoparticles Synthesis and ApplicationsAdvanced biosensing and bioanalysis techniquesPlasmonic and Surface Plasmon Research

Low-Temperature ZnO TFTs Fabricated by Reactive Sputtering of Metallic Zinc Target

Shaojuan Li、Yong Cai、Dedong Han 等 7 位作者2012-07-21IEEE Transactions on Electron Devices

A low-temperature metallic-zinc-target reactive sputtering technology is used to fabricate a ZnO thin-film transistor (TFT). The effect of the$\hbox{O}_{2}/\hbox{Ar}$flow rate ratio on the performance of the resulting TFTs is investigated in detail. It is found that an$\hbox{O}_{2}/\hbox{Ar}$ratio of 0.75–0.8 produces…

ZnO doping and propertiesSemiconductor materials and devicesThin-Film Transistor Technologies

Effect of Medium on Deposited Energy in Microsecond Electrical Explosion of Wires

Qing Zhou、Qiaogen Zhang、Wenyu Yan 等 7 位作者2012-07-21IEEE Transactions on Plasma Science

The properties of the medium have an obvious effect on the process of the electrical explosion of the wire. In this paper, the electrical explosions of copper and aluminum wires were investigated in air and water with pulsed voltage in a time scale of a few microseconds. Based on the measurements of the current and vo…

Laser-Plasma Interactions and DiagnosticsCombustion and Detonation ProcessesHigh-Velocity Impact and Material Behavior

Gas-Phase Hydration Thermochemistry of Sodiated and Potassiated Nucleic Acid Bases

H. Wincel2012-07-21Journal of the American Society for Mass Spectrometry

Hydration reactions of sodiated and potassiated nucleic acid bases (uracil, thymine, cytosine, and adenine) produced by electrospray have been studied in a gas phase using the pulsed ion-beam high-pressure mass spectrometer. The thermochemical properties, ΔH(o)(n), ΔS(o)(n), and ΔG(o)(n), for the hydrated systems were…

Analytical Chemistry and ChromatographyEnzyme Structure and Functionthermodynamics and calorimetric analyses