Materials Literature
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The chemical deterioration of vegetable tanned leather is caused by acid hydrolysis and oxidation due to environmental deteriorative factors like air pollutants, heat and light. In addition, the type of tannin material influences the rate of deterioration. The degree of deterioration can be measured by the fall in the…
Recently, nanotechnology has developed to a stage that makes it possible to process magnetic nanoparticles for the site-specific delivery of drugs. To this end, it has been proposed as biomaterial for drug delivery system in which the drug release rates would be activated by a magnetic external stimuli. Alginate has b…
In this letter, an accurate semi-analytical model for the intrinsic gate capacitance of carbon nanotube (CN)-array based back-gated field-effect transistors (FETs) is proposed. The model accounts for electrostatic screening effect for any given number of nanotubes, their diameter, pitch, and gate-dielectric thickness.…
Abstract Second‐harmonic generation and two‐photon induced photoluminescence from arrays of ZnO nanowires and single nanowires under excitation with femtosecond pulses is experimentally studied. The ratio of relevant components of the nonlinear χ (2) tensor is obtained. The excitation of the nanowire array with femtos…
Hydroxyl groups of the macrocyclic compound p-tert-butylcalix[4]arene have been converted into urethanesil (-NH(C=O)O-)-grafted bridges through a hydrogen transfer nucleophilic addition reaction. Subsequently, the modified macrocyclic derivative can coordinate to lanthanide ions (Tb, Eu) effectively and form a hybrid…
Extensive Monte Carlo results are presented for the structure of a bottle-brush polymer under good solvent or theta solvent conditions. Varying the side chain length, backbone length, and the grafting density for a rigid straight backbone, both radial density profiles of monomers and side chain ends are obtained as we…
Magische Fünfecke: Mithilfe vielseitig übertragbarer fünfeckiger Baueinheiten/Liganden gelang bereits die Synthese riesiger gewölbter Molybdänoxid-Spezies – einschließlich sphärischer Keplerate. Nun wurden auch vergleichbare Polyoxowolframate zugänglich (die bisher unbekannte zentrale pentagonale Baueinheit ist im Bil…
1-Diphenylphosphinopyrene (1-PyP) and 1,6-bis(diphenylphosphino)pyrene (1,6-PyP) can be metalated at C5 and C10 to give cyclometalated complexes [M(L)(1-PyP-H)] + and [M 2 (L) 2 (1,6-PyP)] 2+ (M = Pd or Pt, L = diphosphines). The π → π* transitions of the pyrenyl ring are strongly perturbed by the PPh 2 groups at C1/6…
Abstract Sulfonated polyaniline‐silver (SPAni‐Ag) hybrid nanocomposites have been synthesized by the in situ reduction using a UV‐curing polymerization method without using any reducing or binding agent. An aqueous solution of aniline and orthoanilinic acid (OA) comonomers, a free‐radical oxidant and silver metal salt…
Single crystals of the noncentrosymmetric borate CaBiGaB(2)O(7) were synthesized by conventional solid state reaction. The purity of the crystal was checked by x-ray powder diffraction. The optical properties were measured by analyzing the diffuse reflectance data obtained with a Shimadzu UV-3101PC double-beam, double…
Utilizing the osmotic swelling of LDH in formamide, for the first time, the bulky thiacalix[4]arene anion is introduced, leading to the recovery of LDH layers, and the hexagonal prism morphology of the precursor is well retained.
Tungsten-doped tin oxide transparent conductive films were fabricated on quartz substrates by the method of pulsed plasma deposition with post-annealing. Doping of tungsten can effectively enhance the conductivity of the films while maintaining high transparency. The structural, electrical and optical properties of th…
Coarse-grained (CG) molecular dynamics (MD) simulations are performed to study the insertion of cyclic peptide nanotubes into cell membranes and to examine whether cyclic peptide nanotubes can function as an ion channel and thereby as an antibacterial agent. To do so, the two coarse-grained (CG) models for lipid molec…
New amphiphilic monomers (OCA-DTPAGlu and OCA-DOTA) containing, in the same molecule, three different functions: (i) the chelating agent (DTPAGlu or DOTA) able to coordinate gadolinium ion, (ii) the octreotide bioactive peptide able to target somatostatin receptors, and (iii) a hydrophobic moiety with two 18-carbon at…
Four tetrathiafulvalene (TTF)-annulated porphyrins 1-4 were synthesized and characterized. All contain a tetraphenylporphyrin (TPP) core onto which four, two, or one TTF subunits were annulated. Absorption and fluorescence spectroscopic studies together with electrochemical investigations reveal that interactions betw…
The synthesis of amphiphilic linear-hyperbranched block copolymers with a linear poly(ethylene oxide) (PEO) segment and a hyperbranched poly(carbosilane)s (PCS) block in a rapid three-step strategy is described, combining oxyanionic polymerization with carbosilane chemistry. A linear precursor block copolymer was synt…
Crosslinked organic and hybrid multilayer thin films based on polystyrene-grafted platinum nanoparticles and azidomethyl-functionalized polystyrenes are built-up by sequential spin-coating and UV crosslinking processes. This approach allows to easily tune thickness, composition and periodicity of each layer, as highli…
A very fast, electroless, microwave method is described to synthesize electrically conductive CdS nanowires on DNA just within 60 s. The electrical characterization indicates that the CdS wires are continuous, have very low contact resistance, and exhibit Ohmic behavior. Highly selective deposition on DNA is obtained…
One kind of novel hierarchical carbon nanotubes/bamboo charcoal (CNTs/BC) was prepared by CVD growth of CNTs on low-cost bamboo charcoal (BC). The obtained CNTs/BC composites were characterized by SEM and TEM observations. Adsorption of copper ions by CNTs/BC in aqueous solution was investigated. The adsorbed copper s…
Magnetic cage: Simple cobalt(II) diketonates react with triols under solvothermal conditions to give a family of compounds based on supertetrahedral cage structures: a regular and a distorted {CoII10} species, and a bi-supertetrahedral {CoII19} species. Magnetic studies show unusual properties, such as nonvanishing ma…