Materials Literature
按标题、摘要、年份、主题和来源检索公开元数据。结果保留作者、摘要、分类与原始来源链接。
The response of the Cu(111) Shockley surface state to an external electrical field is characterized by combining a density-functional theory calculation for a slab geometry with an analysis of the Kohn-Sham wavefunctions. Our analysis is facilitated by a decoupling of the Kohn-Sham states via a rotation in Hilbert spa…
Experimental demonstration of the overcoming of basic dispersion-energy constraints in metamaterials with the help of active non-Foster negative capacitors is reported. The experimental metamaterial operates in RF regime, and it is based on air transmission line loaded with negative capacitors. Measurement results cle…
Graphene phonons are measured as a function of electron doping via the addition of potassium adatoms. In the low doping regime, the in-plane carbon $G$ peak hardens and narrows with increasing doping, analogous to the trend seen in graphene doped via the field effect. At high dopings, beyond those accessible by the fi…
Hot carrier and multiple exciton extractions from lead salt quantum dots (QDs) to TiO(2) single crystals have been reported. Implementing these ideas on practical solar cells likely requires the use of nanocrystalline TiO(2) thin films to enhance the light harvesting efficiency. Here, we report 6.4 ± 0.4 fs electron t…
We have investigated the early stages of graphitization on detonation nanodiamond during sequential annealing treatments under vacuum using x-ray photoelectron spectroscopy. Two different temperature-dependent regimes were observed. Below 900 \ifmmode^\circ\else\textdegree\fi{}C, the nanodiamond surface reconstructs i…
The transport properties of domain walls in oxygen deficient multiferroic YMnO3 single crystals have been probed using conductive atomic force microscopy and piezoresponse force microscopy. Domain walls exhibit significantly enhanced conductance after being poled in electric fields, possibly induced by oxygen vacancy…
Layered double hydroxides (LDHs), members of a family of two-dimensional anionic clay with flexibility in composition, have found a wide variety of applications in industry, including as additives in polymers, as precursors to magnetic materials, in biology and medicine, in catalysis, and in environmental remediation.…
We examine the size quantization of plasmons in metallic nanoparticles using time-dependent density functional theory. For small particles in the quantum limit, we identify "quantum core plasmons" and "classical surface plasmons", both of which are collective oscillations comprised of multiple single-particle transiti…
We present the design, characterization, and experimental demonstration of a polarization insensitive and omnidirectional broadband near perfect planar metamaterial absorber (MA) in the near infrared regime, which does not need to stack multilayer composite structures. Experimental result shows that greater than 80% a…
The race to develop newer materials with superior properties/applications in diversified fields is gathering momentum in modern day science. In this context, an exciting avenue of research deals with the development of hybrid materials resulting from the combination of gels with nanoparticles of different origins. The…
A novel redox responsive controlled drug release system based on magnetic nanoparticles for efficient intracellular anticancer drug delivery is fabricated. Disulfide bonds are employed as intermediate linkers to immobilize PEI/β-CD molecules as nanoreservoirs for drug loading onto magnetic nanoparticles. The endocytot…
The high intrinsic spin and long spin relaxation time of manganese-12-acetate (Mn(12)) makes it an archetypical single molecular magnet. While these characteristics have been measured on bulk samples, questions remain whether the magnetic properties replicate themselves in surface supported isolated molecules, a prere…
Metallic conductance in charged ferroelectric domain walls was predicted more than 40 years ago as the first example of an electronically active homointerface in a nonconductive material. Despite decades of research on oxide interfaces and ferroic systems, the metal-insulator transition induced solely by polarization…
The adsorption and corrosion inhibiting effect of aqueous extracts of Punica granatum (PNG) on mild steel in 1 M HCl and 0.5 M H 2 SO 4 at 30 ± 1 °C was investigated using gravimetric, electrochemical impedance spectroscopy (EIS), and potentiodynamic polarization techniques. The experimental findings revealed that PNG…
This paper describes the one-pot, aqueous synthesis of cationic polymer nanofibers with embedded silver nanoparticles. Poly[2-(tert-butylaminoethyl) methacrylate] (PTBAM) was used as a cationic polymer substrate to reinforce the antimicrobial activity of the embedded silver nanoparticles. Electron microscope analyses…
Crystalline structure and molecular dynamics in α and α′ crystals of poly( l -lactide) (PLLA) and PLLA/poly( d -lactide) (PDLA) stereocomplex (sc) crystals have been investigated by the temperature-variable FTIR and solid-state 13 C CP-MAS NMR spectroscopy. The crystal forms of polylactide (PLA) have different band fr…
The quaternary intermetallic Heusler compounds CoFeMn$Z$ ($Z=\text{Al}$, Ga, Si, or Ge) with $1:1:1:1$ stoichiometry were predicted to exhibit half-metallic ferromagnetism by ab initio electronic structure calculations. The compounds were synthesized using an arc-melting technique and the crystal structures were analy…
We experimentally demonstrate an infrared broadband absorber based on an array of nanostrip antennas of several different sizes. The broadband property is due to the collective effect of magnetic responses excited by these nanoantennas at distinct wavelengths. By manipulating the differences of the nanostrip widths, t…
Capillarity can be used to direct anisotropic colloidal particles to precise locations and to orient them by using interface curvature as an applied field. We show this in experiments in which the shape of the interface is molded by pinning to vertical pillars of different cross-sections. These interfaces present well…
Selective fatty acid hydrophobization of the inner surface of tubule halloysite clay is demonstrated. Aqueous phosphonic acid was found to bind to alumina sites at the tube lumen and did not bind the tube's outer siloxane surface. The bonding was characterized with solid-state nuclear magnetic resonance ((29)Si, (13)C…