Materials Literature
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The preparation of nanoparticles from 75% methylated poly(beta-L-malic acid) is described. Their degradation in aqueous environments was examined and the influence of pH and lipase on the rate of hydrolysis was evaluated. Six proteins were used to estimate the loading efficiency of the nanoparticles. The amount of pro…
Liquid foams are an extreme case of multiphase flow systems: capable of flow despite a very high dispersed phase volume fraction, yet exhibiting many characteristics of not only viscoelastic materials but also elastic solids. The non-trivial, well-defined geometry of foam bubbles is at the heart of a plethora of dynam…
PS/silica core/shell structured microspheres were easily prepared in a simple process. Because of the acid-base interaction between the TEOS and seed particles prepared by dispersion polymerization, uniform silica shell was formed on the PVP-stabilized PS particles without additional PVP-coating process.
Abstract The fluorescent imidazolium salt (1,3‐bis(9‐anthracenylmethyl)imidazolium chloride, [bamim]Cl) has been grafted onto the surfaces of single‐walled carbon nanotubes (SWNTs) using an ion exchange strategy based on metathesis of the K + ion in CO 2 K derivatized SWNTs with [bamim] + . The resulting SWNT‐[bamim]…
Abstract The Maxwell Garnett effective medium theory was originally developed for a very small volume fraction of metal particles in a transparent medium. In contrast to the bulk situation, it can be applied to high coverages for thin metal particulate films and predicts the plasmon resonance energy accurately in cont…
Adsorption and disproportionation of dinitrogen tetraoxide on sodium-, potassium-, and rubidium-exchanged zeolites X with Si/Al ratio of 1.18 were studied using density functional theory calculations with periodic boundary conditions. It is found that the stabilization and activation of most of the N 2 O 4 isomers con…
Gelcasting is a very useful technique for producing ceramic parts with complex shapes. In this work, gelcasting in air and pressureless sintering in hydrogen were applied to manufacture translucent alumina ceramics. A stable suspension with 75 wt% solids was prepared by ball milling. Trapped bubbles were removed compl…
The phase diagram for the cubic BNC ternary system in a heterodiamond structure was examined by Monte Carlo simulations and the cluster expansion technique based on first-principles calculations. All the atomic arrangements exhibit positive formation energies, indicating phase separation into cubic BN $(c\text{\ensure…
Based on the molecular structure mechanics method, the dynamic properties of super carbon nanotubes (STs), together with ST-based mass and strain sensors, are investigated. The following results are obtained: (a) the fundamental frequency of the STs is found to be lower than that of the single-wall carbon nanotube (SW…
We investigated the densification of undoped, nanocrystalline yttria (Y 2 O 3 ) powder by spark plasma sintering (SPS) at sintering temperatures between 650°C and 1050°C at a heating rate of 10°C/min and an applied stress of 83 MPa. In spite of the low sinterability of the undoped Y 2 O 3 , a remarkable densification…
Surface modification of silica particles by an amphiphilic poly(amido amine) (PAMAM) dendron and investigation of their advanced application toward water purification have been demonstrated. The amphiphilic dendron-surface-modified silica particles (C18GnS, n = 1−3) were prepared by solid-phase synthetic strategy incl…
Crystal clear: Strong supramolecular interactions between tris(dipicolinate)lanthanide complexes and arginine-like moieties have been evidenced by NMR chemical shift titration and X-ray diffraction analyses. Since the lanthanide atom is a strong anomalous scatterer, and the complex itself is luminescent, this interact…
The hydrogen storage in zeolite-like hexacyanometalates with different exchangeable alkali metals within the cavities was studied. The H 2 adsorption isotherms were recorded at 75 and 85 K in order to estimate the involved adsorption heats using the isosteric method. The electric field gradient within the porous frame…
This study focuses on the formation mechanism of the bicontinuous cubic Ia 3̅ d mesoporous material KIT-6, both on the molecular and on the mesoscopic levels. KIT-6 is synthesized with Pluronic P123 (PEO 20 PPO 70 PEO 20 ), low acid concentration, and n -butanol at 40 °C. Through in situ EPR measurements on a series o…
Electron paramagnetic resonance and electron-nuclear double resonance (ENDOR) experiments on ZnO nanoparticles doped with Al reveal the presence of shallow, effective-masslike donors related to substitutional Al atoms. The shallow character of the Al donor is evidenced by the multitude of ENDOR transitions of the $^{6…
We present a generalization of the self-consistent analysis of carbon nanotube (CNT) field effect transistors (FETs) to the case of multi-wall/multi-band coherent carrier transport. The contribution to charge diffusion, due to different walls and sub-bands of a multi-wall (mw) CNT is shown to be non-negligible, especi…
Abstract Nylon‐6/Attapulgite (ATP) composites were prepared by melt blending in a twin screw extruder. Nylon‐6/ATP composites were tested for its mechanical, rheological, thermal and morphological properties. The results have shown drastic improvement in the flexural modulus by 74% at the loading level of 4% of ATP. T…
Experimental and theoretical simulations of linear and nonlinear optical susceptibilities of the novel Na3La9O3(BO3)8, a ternary oxyborate nonlinear single crystal, are reported here. The calculations were based on one of the most accurate methods for the computation of the linear and nonlinear optical susceptibilitie…
Corrosion behavior of ZrB 2 powder during wet processing in water or ethyl alcohol was studied both with and without an organic additive. Incorporation of oxygen and pH change did not intensively occur during static aging of aqueous slurries, but corrosion was enhanced when stirring the slurries. The oxygen content of…
Abstract PET‐glass fiber composites were prepared by melt mixing of recycled PET with chopped glass fibers (15, 20, and 30 wt%) and their degree of dispersion was assessed by scanning electron microscopy. Rotational rheometry was employed to analyze the interfacial shear strength between the fibers and polymer matrix…