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Architectural Effect on the Surface Tension of an ABA Triblock Copolymer Melt

M. W. Matsen2009-12-10Macromolecules

By carefully comparing ABA triblock copolymers with che-mically matched AB diblock copolymers, Khanna et al.1 have recently shown that molecular architecture affects the surface energy of an ordered block copolymer melt. In particular, their experiment revealed a greater tendency for the B-rich domains of the diblock…

Theoretical and Computational PhysicsForce Microscopy Techniques and ApplicationsBlock Copolymer Self-Assembly

Strain-Induced Enthalpy Relaxation in Poly(lactic acid)

Sang Cheol Lee、Jae Il Han、Young Gyu Jeong 等 4 位作者2009-12-10Macromolecules

ADVERTISEMENT RETURN TO ISSUEPREVCommunication to the...Communication to the EditorNEXTStrain-Induced Enthalpy Relaxation in Poly(lactic acid)Sang Cheol Lee*, Jae Il Han, Young Gyu Jeong, and Mirinae KwonView Author Information School of Advanced Materials and System Engineering, Kumoh National Institute of Technology…

Polymer crystallization and propertiesConducting polymers and applicationsbiodegradable polymer synthesis and properties

Direct and Selective Immobilization of Proteins by Means of an Inorganic Material-Binding Peptide: Discussion on Functionalization in the Elongation to Material-Binding Peptide

Nozomi Yokoo、Takanari Togashi、Mitsuo Umetsu 等 12 位作者2009-12-10The Journal of Physical Chemistry B

Using an artificial peptide library, we have identified a peptide with affinity for ZnO materials that could be used to selectively accumulate ZnO particles on polypropylene-gold plates. In this study, we fused recombinant green fluorescent protein (GFP) with this ZnO-binding peptide (ZnOBP) and then selectively immob…

Advanced biosensing and bioanalysis techniquesSupramolecular Self-Assembly in MaterialsDiatoms and Algae Research

Textured high Curie point piezoelectric ceramics prepared by spark plasma sintering

Haixue Yan、Huanpo Ning、Haitao Zhang 等 4 位作者2009-12-10Advances in Applied Ceramics Structural Functional and Bioceramics

The Curie point T c of ferroelectrics sets the upper temperature limit for their application as piezoelectrics. Some Aurivillius phase and perovskite-like layer structured (PLS) materials are good candidates for high temperature piezoelectric applications because of their high T c. The Aurivillius phase CaBi2Nb2O9 and…

Ferroelectric and Piezoelectric MaterialsAcoustic Wave Resonator TechnologiesMicrowave Dielectric Ceramics Synthesis

Positive temperature coefficient properties of multiwall carbon nanotubes/poly(vinylidene fluoride) nanocomposites

Shenglin Jiang、Yan Yu、J. J. Xie 等 7 位作者2009-12-10Journal of Applied Polymer Science

Abstract Favorable positive temperature coefficient (PTC) properties of multiwall carbon nanotubes (MWCNT)/poly(vinylidene fluoride) (PVDF) nanocomposites were obtained. The results showed that such composites presented high PTC intensity, as well as eliminated negative temperature coefficient effect and high thermal…

Carbon Nanotubes in CompositesAdvanced Sensor and Energy Harvesting MaterialsDielectric materials and actuators

Vesicle-Directed Generation of Gold Nanoflowers by Gemini Amphiphiles and the Spacer-Controlled Morphology and Optical Property

Ling Zhong、Xiaodong Zhai、Xuefeng Zhu 等 5 位作者2009-12-10Langmuir

In this article, we developed an effective approach to generate gold nanoflowers (AuNFs) by vesicles made from a series of gemini amphiphiles (G2-G10) with different spacer lengths. The gemini amphiphiles were found to form vesicles in aqueous solution. Upon mixing with vesicles in the presence of AgNO(3), HAuCl(4) co…

Gold and Silver Nanoparticles Synthesis and ApplicationsSurfactants and Colloidal SystemsPickering emulsions and particle stabilization

Single-Crystalline β-Ga2O3 Hexagonal Nanodisks: Synthesis, Growth Mechanism, and Photocatalytic Activities

Heqing Yang、Ruyu Shi、Jie Yu 等 8 位作者2009-12-10The Journal of Physical Chemistry C

β-Ga 2 O 3 hexagonal nanodisks were in situ grown on the surface of gallium grain and Si substrate via a reaction of metallic gallium with NH 4 Cl and H 2 O at 650−800 °C for 30 min. The as-synthesized nanodisks have perfect hexagonal shape with diagonals of 0.6−4.0 μm and thicknesses of 140−480 nm. Size of the hexago…

Advanced Photocatalysis TechniquesZnO doping and propertiesGa2O3 and related materials

Protein-Resistant Polymer Coatings Based on Surface-Adsorbed Poly(aminoethyl methacrylate)/Poly(ethylene glycol) Copolymers

Leonid Ionov、Alla Synytska、Elisabeth Kaul 等 4 位作者2009-12-10Biomacromolecules

We report on the protein-resistant properties of glass substrates coated with novel copolymers of 2-aminoethyl methacrylate hydrochloride and poly(ethylene glycol) methyl ether methacrylate (AEM-PEG). In comparison to currently available protein-blocking polymer systems, such as poly-l-lysine-poly(ethylene glycol), si…

Polymer Surface Interaction StudiesNanofabrication and Lithography TechniquesAdvanced Biosensing Techniques and Applications

Nonisothermal crystallization behavior and mechanical properties of poly(butylene succinate)/silica nanocomposites

Junjia Bian、Lijing Han、Xuemei Wang 等 7 位作者2009-12-10Journal of Applied Polymer Science

Abstract Silica nanoparticles and poly(butylene succinate) (PBS) nanocomposites were prepared by a melt‐blending process. The influence of silica nanoparticles on the nonisothermal crystallization behavior, crystal structure, and mechanical properties of the PBS/silica nanocomposites was investigated. The crystallizat…

Polymer crystallization and propertiesPolymer Nanocomposites and Propertiesbiodegradable polymer synthesis and properties

Confocal Fluorescence Microscopy of the Morphology and Composition of Interstitial Fluids in Freezing Electrolyte Solutions

Jie Cheng、Cherrie Soetjipto、Michael R. Hoffmann 等 4 位作者2009-12-10The Journal of Physical Chemistry Letters

Ice rheology, the integrity of polar ice core records, and ice−atmosphere interactions are among the phenomena controlled by the morphology and composition of interstitial fluids threading polycrystalline ice. Herein, we investigate how ionic impurities affect such features via time-resolved confocal fluorescence micr…

Material Dynamics and PropertiesSpectroscopy and Quantum Chemical Studiesnanoparticles nucleation surface interactions

Contrasting Pressure Effects in Sr2VFeAsO3and Sr2ScFePO3

Hisashi Kotegawa、Takayuki Kawazoe、Hideki Tou 等 7 位作者2009-12-10Journal of the Physical Society of Japan

We report the resistivity measurements under pressure of two Fe-based superconductors with a thick perovskite oxide layer, Sr2VFeAsO3 and Sr2ScFePO3. The superconducting transition temperature Tc of Sr2VFeAsO3 markedly increases with increasing pressure. Its onset value, which was Tc{onset}=36.4 K at ambient pressure,…

Magnetic and transport properties of perovskites and related materialsIron-based superconductors researchSuperconductivity in MgB2 and Alloys

Size effects in the torsion of thin metal wires

Martín I. Idiart、N.A. Fleck2009-12-10Modelling and Simulation in Materials Science and Engineering

The elasto-plastic torsional response of a thin metal wire is analysed using the phenomenological flow theory of strain-gradient plasticity proposed by Fleck and Willis (2009 Part I J. Mech. Phys. Solids 57 161, 2009 Part II J. Mech. Phys. Solids 57 1045). Numerical results are obtained via minimum principles, and clo…

Microstructure and mechanical propertiesMetal and Thin Film MechanicsNonlocal and gradient elasticity in micro/nano structures

Specific-heat jump at the superconducting transition and the quantum critical nature of the normal state of pnictide superconductors

Jan Zaanen2009-12-10Physical Review B

Recently it was discovered that the jump in the specific heat at the superconducting transition in pnictide superconductors is proportional to the superconducting transition temperature to the third power, with the superconducting transition temperature varying from 2 to 25 K including underdoped and overdoped cases.…

Rare-earth and actinide compoundsIron-based superconductors researchSuperconductivity in MgB2 and Alloys

Electrospinning of antibacterial poly(vinylidene fluoride) nanofibers containing silver nanoparticles

Jiang Yuan、Jia Geng、Zhicai Xing 等 6 位作者2009-12-10Journal of Applied Polymer Science

Abstract Poly(vinylidene fluoride) (PVDF) nanofibrous mats containing silver nanoparticles were prepared by electrospinning. The diameter of the nanofibers ranged between 100 and 300 nm, as revealed by scanning electron microscopy. The silver nanoparticles were dispersed, but some aggregation was observed with transmi…

Advanced Sensor and Energy Harvesting MaterialsConducting polymers and applicationsElectrospun Nanofibers in Biomedical Applications

Shear deformation kinematics of bicrystalline grain boundaries in atomistic simulations

Garritt J. Tucker、Jonathan A. Zimmerman、David L. McDowell2009-12-10Modelling and Simulation in Materials Science and Engineering

The shear deformation behavior of bicrystalline grain boundaries is analyzed using continuum mechanical metrics extracted from atomistic simulations. Calculating these quantities at this length-scale is premised on determining the atomic deformation gradient tensor using interatomic distances. Employing interatomic di…

Microstructure and mechanical propertiesMetal and Thin Film MechanicsAdvanced materials and composites

Biomimetic Principles in Polymer and Material Science

Markus Antonietti、Peter Fratzl2009-12-10Macromolecular Chemistry and Physics

Abstract “Not to copy Biology: to learn in modesty from her principles and to transfer it to materials space and conditions previously not accessible to biology” magnified image

3D Printing in Biomedical ResearchCalcium Carbonate Crystallization and InhibitionDiatoms and Algae Research

Epitaxial LaFeAsO1−xFxthin films grown by pulsed laser deposition

M. Kidszun、S. Haindl、Elke Reich 等 7 位作者2009-12-10Superconductor Science and Technology

Superconducting and epitaxially grown LaFeAsO 1− x F x thin films were successfully prepared on (001)-oriented LaAlO 3 substrates using pulsed laser deposition. The prepared thin films show exclusively a single in-plane orientation with the epitaxial relation and a full width at half-maximum value of 1°. Furthermore,…

Corporate Taxation and AvoidanceIron-based superconductors research

Crystal nucleation in undercooled liquid zirconium

Stefan Klein、D. Holland‐Moritz、D.M. Herlach2009-12-10Physical Review B

Electromagnetic and electrostatic levitation are applied to undercool melts of pure Zr. Each sample is undercooled approximately 100 times and the distribution functions of undercoolings are determined. They are analyzed within a statistical approach of classical nucleation theory. Despite large undercoolings the anal…

Metallic Glasses and Amorphous AlloysSolidification and crystal growth phenomenananoparticles nucleation surface interactions

A transparent and luminescent ionogel based on organosilica and ionic liquid coordinating to Eu3+ ions

Feng Yu、Huanrong Li、Quanying Gan 等 6 位作者2009-12-10Journal of Materials Chemistry

Herein we present a facile method to prepare a transparent and luminescent ionogel monolith by hydrolysis and condensation of the silylated bipyridine, which can sensitize the luminescence of europium(III) in the presence of a carboxyl-functionalized ionic liquid where Eu3+ ions are coordinated to the oxygen atoms of…

Luminescence Properties of Advanced MaterialsLanthanide and Transition Metal ComplexesAnalytical Chemistry and Sensors

Silica-Coated Gold Nanorods with a Gold Overcoat: Controlling Optical Properties by Controlling the Dimensions of a Gold−Silica−Gold Layered Nanoparticle

Huai‐Ping Cong、Rasmus Toftegaard、Jacob Arnbjerg 等 4 位作者2009-12-10Langmuir

Silica shells were directly coated onto surfactant-capped gold nanorods by a simple one-step method. The procedure required no intermediate coating of the gold nanorod prior to the formation of the smooth silica shell, the thickness of which could be accurately controlled over the range 60-150 nm. These silica-encased…

Gold and Silver Nanoparticles Synthesis and ApplicationsNanocluster Synthesis and ApplicationsAdvanced Nanomaterials in Catalysis