Materials Literature
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Fresh-cut green bell peppers (Capsicum annuum L.) were stored in modified atmosphere packaging (MAP) made of impermeable high-density polyethylene film. Two in-packaging atmospheres and storage temperatures (0 oC and 5 oC) were tested. The respiration rate of the unpackaged produce and the in-package gas concentration…
Leakage is a major source of lost revenue in pipeline distribution networks. In UK water distribution networks, the amount of treated water lost within distribution networks can reach up to 40% of the total supply. Existing leakage location techniques are heavily dependent on acoustic sensing, which can perform poorly…
Optical reflectivity and electrical resistivity of multi-component AgMgAl alloys, both crystalline and amorphous, were measured. The crystalline alloys exhibit high reflection in infrared region but a steeper drop in visible and ultraviolet regions. By contrast, amorphous alloys show a lower but relatively uniform ref…
We utilize 198 and 204 nm excited UV resonance Raman spectroscopy (UVRR) and circular dichroism spectroscopy (CD) to monitor the backbone conformation and the Gln side chain hydrogen bonding (HB) of a short, mainly polyGln peptide with a D(2)Q(10)K(2) sequence (Q10). We measured the UVRR spectra of valeramide to deter…
Design of monodisperse ultra-small nanocrystals (NCs) into large scale patterns with ad hoc features is demonstrated. The process makes use of solid state dewetting of a thin film templated through alloy liquid metal ion source focused ion beam (LMIS-FIB) nanopatterning. The solid state dewetting initiated at the edge…
We study the mechanism of lattice parameter accommodation and the structure of GaAs nanowires (NWs) grown on Si(111) substrates using the Ga-assisted growth mode in molecular beam epitaxy. These nanowires grow preferentially in the zincblende structure, but contain inclusions of wurtzite at the base. By means of grazi…
A theoretical model for the radially dependent effective piezoelectric coefficient and corresponding piezoelectric potential in intrinsic ZnO nanowires (NWs)/nanotubes (NTs) is presented. Substrate-bound ZnO structures oriented along the c-axis with diameters of 100–5000 nm (NWs) and inner diameters of 100–900 nm (NTs…
An isomorphous series of 10 microporous copper-based metal-organic frameworks (MOFs) with the general formulas (∞)(3)[{Cu(3)(μ(3)-OH)(X)}(4){Cu(2)(H(2)O)(2)}(3)(H-R-trz-ia)(12)] (R = H, CH(3), Ph; X(2-) = SO(4)(2-), SeO(4)(2-), 2 NO(3)(2-) (1-8)) and (∞)(3)[{Cu(3)(μ(3)-OH)(X)}(8){Cu(2)(H(2)O)(2)}(6)(H-3py-trz-ia)(24)C…
The cyano-bridged 3D heteronuclear polymeric complex, [Cd(NH 3 )( μ -ampy)Ni( μ -CN) 4 ] n , ( 1 ) (ampy = 3-aminomethylpyridine), has been synthesized and characterized by FT-IR and Raman spectral, thermal and elemental analyses. The crystal structure of 1 has been determined by X-ray single crystal diffraction. The…
In this study, powdered activated carbon (PAC) was produced from agricultural waste biomass of kenaf (Hibiscus cannabinus L.) core or stalk, and the process variables were optimized by applying central composite design (CCD). The influences of carbonization temperature, duration of activation, and impregnation ratio o…
RATIONALE: Amyloid formation is implicated in a number of human diseases. β(2)-Microglobulin (β(2)m) is the precursor protein in dialysis-related amyloidosis and it has been shown that partial, or more complete, unfolding is key to amyloid fibril formation in this pathology. Here the relationship between conformationa…
We report on the analyses of trapping properties of metal-organic chemical vapor deposition grown AlGaN/GaN high-electron-mobility transistor (HEMT) heterostructures on silicon with increasing buffer thickness (Tbuff). An exact exponential dependence of AlGaN/GaN hetero-interface trap time constants with gate bias was…
A pulsed, slow positron beam, with a diameter of 200 μm, was extracted into air through a thin SiN window of an atmospheric positron probe microanalyzer (PPMA), and used to measure the ortho-positronium lifetimes τ in polyvinyl alcohol and polycaprolactam sub-μm-thick films. By measuring the variation of τ as a functi…
Lanthanum strontium manganite (La(0.8)Sr(0.2)MnO(3), LSM) nanofibers have been synthesized by the electrospinning method. The electrospun nanofibers are intact without morphological and structural changes after annealing at 1050 °C. The LSM nanofibers are employed as the sensing electrode of an electrochemical sensor…
The antioxidant activities of five extracts from Polygonatum odoratum rhizomes were measured by three antioxidant assays in vitro. The crude flavonoid extracts (FE) exhibited the strongest antioxidant activity among all extracts with IC(50/DPPH) = 0.06 ± 0.035 mg mL(-1), IC(50/OH) = 0.68 ± 0.030 mg mL(-1) and reducing…
Arrays of periodically disposed silver nanowires embedded in alumina were shown to be capable of conducting plasmons excited by laser illuminating one end of the array to its opposite end where surface-enhanced Raman of molecules resident among the tips of the nanowires was excited. The SERS signals, in turn, excited…
Cancer-cell-specific pH-activatable polymer nanogels consisting of CD44-receptor-targeting hyaluronic acid (HA), pH-sensitive poly(β-amino ester) (PBAE), and near-infrared (NIR) fluorescent indocyanine green (ICG) were synthesized and used to detect cancer cells. The HA/PBAE/ICG-polymer-nanogel-based NIR probe was non…
A material with high dielectric constant, low dielectric loss, and good mechanical and thermal properties was produced using multi-wall carbon nanotubes (MWCNTs) wrapped with poly(ether sulphone) (PES) dispersed in a poly(ether ether ketone) (PEEK) matrix. The material was fabricated using melt-blending, and MWCNT/PEE…
POMs sorgen für Poren: Eine Ionothermalsynthese führte zu porösen offenen Gerüsten auf Polyoxometallat(POM)-Basis, deren Strukturen beim Erwärmen bis 300 °C unverändert bleiben. Die sperrigen Tetrabutylammonium-Kationen in den Nanokanälen können außerdem gegen Übergangsmetallionen ausgetauscht werden. Gasadsorptionsme…
A chiral 1,1-bi-2-naphthol-derived calix[4]arene (1) was synthesized via a click reaction. Fluorescence spectra and dynamic light-scattering revealed that Cu(II)-1 complexes were generated in situ and exhibited remarkable enantioselectivity toward mandelic acid. Using this dynamic light-scattering technique, the detec…