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Sialyl‐Lewisx – ein “präorganisiertes Wasseroligomer”?

Florian Binder、Katrin Lemme、Roland C. Preston 等 4 位作者2012-07-02Angewandte Chemie

Als Cluster von Wassermolekülen, die auf einem Gerüst präsentiert werden – ein „präorganisiertes Wasseroligomer“ –, lässt sich Sialyl-Lewisx (sLex) beschreiben. Den Antrieb für die Bindung von sLex an E-Selectin liefern der hohe Grad an Präorganisation, der ein Netzwerk von gerichteten Wasserstoffbrücken ermöglicht, u…

Glycosylation and Glycoproteins ResearchCarbohydrate Chemistry and SynthesisSupramolecular Self-Assembly in Materials

Electron Beam Induced Growth of Silver Nanoparticles

Guanghua Shi、Shengxiang Bao、Wei-Ming Lai 等 6 位作者2012-07-02Scanning

An electron beam inducing method for sprouting large quantities of silver nanoparticles on the surface of silver chloride particles is reported. The electron beam driven process was characterized by time-dependent scanning electron microscope (SEM) and energy dispersive spectrum (EDS), allowing for observing several k…

Gold and Silver Nanoparticles Synthesis and ApplicationsElectron and X-Ray Spectroscopy Techniquesnanoparticles nucleation surface interactions

Gold anion catalysis of methane to methanol

A. Z. Msezane、Z. Felfli、Kelvin Suggs 等 5 位作者2012-07-02Gold bulletin

The oxidation of CH 4 has been investigated in the presence and absence of the atomic Au − ion catalyst. We have employed the first principles density functional theory (DFT) and dispersion-corrected DFT calculations for the transition state on the Au − ion and analyzed the thermodynamics properties of the reactions a…

Advanced Chemical Physics StudiesCatalytic Processes in Materials ScienceCatalysis and Oxidation Reactions

The effect of Ga content on In2xGa2−2xO3nanowire transistor characteristics

Misook Suh、M. Meyyappan、Sanghyun Ju2012-07-02Nanotechnology

We have investigated the change in structural and electrical properties of In(2x)Ga(2-2x)O(3) nanowires (x = 1, 0.69 and 0.32) grown with varied indium (In) and gallium (Ga) contents. The as-grown In(2x)Ga(2-2x)O(3) nanowires kept the cubic crystal structure of In(2)O(3) intact even when the atomic percentages of Ga w…

ZnO doping and propertiesGas Sensing Nanomaterials and SensorsGa2O3 and related materials

Large Tunnel Magnetoresistance in Epitaxial Oxide Spin‐Filter Tunnel Junctions

T. Harada、I. Ohkubo、Mikk Lippmaa 等 8 位作者2012-07-02Advanced Functional Materials

Abstract A high‐performance spin filter tunnel junction composed of an epitaxial oxide heterostructure is reported. By independently controlling the magnetic orientations of ferromagnetic tunnel barrier and electrode layers, a tunnel magnetoresistance ratio exceeding 120% is obtained purely by the spin filtering effec…

Magnetic and transport properties of perovskites and related materialsAdvanced Condensed Matter PhysicsElectronic and Structural Properties of Oxides

Determination of Morphological Parameters of Supported Gold Nanoparticles: Comparison of AFM Combined with Optical Spectroscopy and Theoretical Modeling versus TEM

Frank Hubenthal、David Blázquez‐Sánchez、Frank N. Trager2012-07-02Applied Sciences

The morphology of small gold particles prepared by Volmer–Weber growth on sapphire substrates have been investigated by two different characterization techniques. First, by non-extensive atomic force microscopy (AFM) in combination with optical spectroscopy and modeling of the optical properties using a theoretical mo…

Gold and Silver Nanoparticles Synthesis and Applicationsnanoparticles nucleation surface interactionsLaser-Ablation Synthesis of Nanoparticles

Fatigue cracking at twin boundary: Effect of dislocation reactions

Z. J. Zhang、L. L. Li、Peng Zhang 等 4 位作者2012-07-02Applied Physics Letters

This Letter addresses a new finding of the connection between the macroscopic fatigue cracking behaviors of twin boundaries (TBs) and the microscopic TB-dislocation interactions. According to the difference in crystallography beside TBs, slipping dislocations usually interact with TBs in different modes during plastic…

Microstructure and mechanical propertiesAluminum Alloys Composites PropertiesHigh-Velocity Impact and Material Behavior

Stimulated Mie scattering in nanocrystals suspension

Guang S. He、Wing‐Cheung Law、Liwei Liu 等 5 位作者2012-07-02Applied Physics Letters

In this letter, we report the observation of backward stimulated Mie scattering in a suspension of CdSe/Cds/ZnS nanocrystals in chloroform, pump by 816-nm or 1064-nm nanosecond laser pulses. The observed stimulated scattering exhibits the features of no frequency-shift, low pump threshold requirement, and easy control…

Gold and Silver Nanoparticles Synthesis and ApplicationsQuantum Dots Synthesis And PropertiesNonlinear Optical Materials Studies

Platinum Clusters on Vacancy-Type Defects of Nanometer-Sized Graphene Patches

Takashi Yumura、Tatsuya Awano、Hisayoshi Kobayashi 等 4 位作者2012-07-02Molecules

Density functional theory calculations found that spin density distributions of platinum clusters adsorbed on nanometer-size defective graphene patches with zigzag edges deviate strongly from those in the corresponding bare clusters, due to strong Pt-C interactions. In contrast, platinum clusters on the pristine patch…

Carbon Nanotubes in CompositesGraphene research and applicationsFullerene Chemistry and Applications

Theoretical modeling of spacer-yarn arrangement for warp-knitted spacer fabrics and experimental verification

Xiaofang Guo、Hairu Long、Yao Sun 等 4 位作者2012-07-02Textile Research Journal

Different surface structure of spacer fabric implies different spacer yarn arrangement and therefore the compression resistance of fabric. The spacer yarns' arrangement modeling of warp knitted spacer fabrics having identical parameters (thickness, density, material etc.) but different surface structures on double-nee…

Textile materials and evaluationsVibration and Dynamic AnalysisMechanical stress and fatigue analysis

PEGylation of Nanosubstrates (Titania) with Multifunctional Reagents: At the Crossroads between Nanoparticles and Nanocomposites

Tania Kotsokechagia、Noha M. Zaki、Karen L. Syres 等 7 位作者2012-07-02Langmuir

Titania (anatase) nanoparticles were successfully PEGylated through the use of catechol (dopamine)-terminated PEG derivatives. The resulting materials were characterized by excellent stability at neutral pH and extremely low toxicity (phagocytic and nonphagocytic cell lines). In particular, we focused on the compariso…

Nanoparticle-Based Drug DeliveryAdvanced Nanomaterials in CatalysisGraphene and Nanomaterials Applications

Effect of metals and annealing on specific contact resistivity of GeTe/metal contacts

E. K. Chua、Rong Zhao、Luping Shi 等 6 位作者2012-07-02Applied Physics Letters

The circular transfer length method was employed to extract the specific contact resistivity, ρc of GeTe (amorphous and crystalline state) with metals (Ni, W, TiW) to quantify the series contact resistance. The ρc of amorphous-GeTe with metals was also determined for different annealing conditions. Higher metal work f…

Chalcogenide Semiconductor Thin FilmsPhase-change materials and chalcogenidesSemiconductor materials and interfaces

TEM analysis of nanoparticle dispersions with application towards the quantification ofin vitrocellular uptake

Nicole Hondow、P. Wang、Rik Brydson 等 7 位作者2012-07-02Journal of Physics Conference Series

TEM analysis of nanoparticle dispersions in solution has previously been limited, in the main, to the measurement of primary particle size due to the drying effects that occur during sample preparation. We show that solutions prepared for TEM by plunge freezing specimen grids coated with a blotted solution is a sensit…

Nanoparticle-Based Drug DeliveryCoagulation and Flocculation StudiesElectrostatics and Colloid Interactions

Strong blue light emission from a-SiNx:O films via localized surface plasmon enhancement

Zhongyuan Ma、Minyi Yan、Xiaofan Jiang 等 12 位作者2012-07-02Applied Physics Letters

Strong and stable blue photoluminescence (PL) at room temperature has been observed from amorphous oxidized silicon nitride (a-SiNx:O) films with Ag nanoparticles inserted between a-SiNx:O films and Si substrates. The resonant excitation of localized surface plasmons (LSPs) with the emission of a-SiNx:O films has resu…

Thin-Film Transistor TechnologiesSilicon Nanostructures and PhotoluminescenceNanowire Synthesis and Applications

Beating of magnetic oscillations in a graphene device probed by quantum capacitance

M. Tahir、Udo Schwingenschlögl2012-07-02Applied Physics Letters

We report the quantum capacitance of a monolayer graphene device in an external perpendicular magnetic field including the effects of Rashba spin-orbit interaction (SOI). The SOI mixes the spin up and spin down states of neighbouring Landau levels into two (unequally spaced) energy branches. In order to investigate th…

Graphene research and applicationsQuantum and electron transport phenomenaTopological Materials and Phenomena

On the radiation hardness of (Mg,Zn)O thin films grown by pulsed-laser deposition

Florian Schmidt、Holger von Wenckstern、D. Spemann 等 4 位作者2012-07-02Applied Physics Letters

We report on electrical properties and the generation of the E4 defect in pulsed-laser deposited MgxZn1−xO thin films irradiated with 2.25 MeV protons. Whereas the electrical properties of the Schottky diodes as well as the net doping density of the samples did not change due to irradiation, the concentration of the E…

ZnO doping and propertiesGa2O3 and related materialsElectronic and Structural Properties of Oxides

Polarization Rotation in the Monoclinic Perovskite BiCo1−xFexO3

Kengo Oka、Tsukasa Koyama、Tomoatsu Ozaaki 等 6 位作者2012-07-02Angewandte Chemie

Der monokline Perowskit BiCo1−xFexO3 (x≈0.7) durchläuft einen Strukturübergang zweiter Ordnung von tetragonal nach monoklin, der mit einer Drehung des Polarisationsvektors von der [001]- in die [111]-Richtung einer pseudokubischen Zelle einhergeht. Die durch Elektronenbeugung und Synchrotron-Pulverröntgenbeugung ermit…

Ferroelectric and Piezoelectric MaterialsMagnetic and transport properties of perovskites and related materialsThermal Expansion and Ionic Conductivity

Enhancement of superconductivity in FeSe 1− x Te x by Li doping

Chia‐Ming Yang、Po‐Wei Chen、In‐Gann Chen 等 6 位作者2012-07-02Superconductor Science and Technology

The study investigated the chemical doping effect of Li in the Fe(Se,Te) system. With the addition of Li, the NiAs phase was precipitated, which resulted in worse superconductivity in FeSe samples. The XRD results indicated that chemical stress was found in the FeTe system which showed no superconductivity by doping L…

Rare-earth and actinide compoundsIron-based superconductors researchIntellectual Capital and Performance Analysis

Effects of Stone-Wales Defects on the Thermal Conductivity of Carbon Nanotubes

Wei Li、Yanhui Feng、Peng Jia 等 4 位作者2012-07-02ASME Journal of Heat and Mass Transfer

The thermal conductivity of carbon nanotubes with Stone-Wales (SW) defects was investigated using non-equilibrium molecular dynamics method. The defect effects were analyzed by the temperature profile and local thermal resistance of the nanotubes with one or more SW defects and further compared with perfect tubes. The…

Carbon Nanotubes in CompositesGraphene research and applicationsThermal properties of materials

Reaction Mechanisms of Ethylenediaminetetraacetic Acid and Diethanolamine in the Precursor Solution for Producing (K, Na)NbO3 Thin Films with Outstanding Piezoelectric Properties

Phoi Chin Goh、Kui Yao、Zhong Chen2012-07-02The Journal of Physical Chemistry C

An understanding of the reaction mechanisms of ethylenediaminetetraacetic acid (EDTA) and diethanolamine (DEA) for producing solution-derived (K, Na)NbO 3 (KNN) thin films with outstanding piezoelectric properties and low leakage current is developed. X-ray photoelectron spectroscopy (XPS), Fourier transform infrared…

Ferroelectric and Piezoelectric MaterialsAcoustic Wave Resonator TechnologiesMicrowave Dielectric Ceramics Synthesis