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Optical absorption parameters of amorphous carbon films from Forouhi–Bloomer and Tauc–Lorentz models: a comparative study

N. Laidani、Ruben Bartali、Gloria Gottardi 等 5 位作者2007-12-07Journal of Physics Condensed Matter

Parametrization models of optical constants, namely Tauc–Lorentz (TL), Forouhi–Bloomer (FB) and modified FB models, were applied to the interband absorption of amorphous carbon films. The optical constants were determined by means of transmittance and reflectance measurements in the visible range. The studied films we…

Nonlinear Optical Materials StudiesCarbon Nanotubes in CompositesDiamond and Carbon-based Materials Research

Excitable Er fraction and quenching phenomena in Er-dopedSiO2layers containing Si nanoclusters

B. Garrido、Cristina García-Beltrán、S.-Y. Seo 等 9 位作者2007-12-07Physical Review B

This paper investigates the interaction between Si nanoclusters (Si-nc) and Er in $\mathrm{Si}{\mathrm{O}}_{2}$, reports on the optical characterization and modeling of this system, and attempts to clarify its effectiveness as a gain material for optical waveguide amplifiers at $1.54\phantom{\rule{0.3em}{0ex}}\ensurem…

Photonic and Optical DevicesNanowire Synthesis and ApplicationsSilicon Nanostructures and Photoluminescence

Highly Efficient Inorganic Transparent UV‐Protective Thin‐Film Coating by Low Temperature Sol‐Gel Procedure for Application on Heat‐Sensitive Substrates

Hongtao Cui、Marcos Zayat、P. García Parejo 等 4 位作者2007-12-07Advanced Materials

Transparent inorganic UV-protective coatings are prepared by an epoxide-derived sol-gel route at low temperature. The obtained coatings show high transparency in visible range and highly efficient absorption in the whole UV range, which makes them ideal candidates for the protection against UV radiation.

Aerogels and thermal insulationPhotopolymerization techniques and applicationsSurface Modification and Superhydrophobicity

High-Temperature Adsorption of Carbon Dioxide on Mixed Oxides Derived from Hydrotalcite-Like Compounds

Xiaoping Wang、Jun Yu、Jie Cheng 等 5 位作者2007-12-07Environmental Science & Technology

Various XnY(3-n)Al-hydrotalcite-like compounds (HTlcs) were synthesized by the constant pH coprecipitation method with the (X2+ + Y2+)/Al3+ molar ratio fixed at 3.0. Well-mixed oxides Xn,Y(3-n)AlO were derived from corresponding HTlcs precursors upon calcination. Physicochemical characterization with X-ray diffraction…

Carbon Dioxide Capture TechnologiesLayered Double Hydroxides Synthesis and ApplicationsThermal Expansion and Ionic Conductivity

Dermal inorganic gadolinium concentrations: evidence for in vivo transmetallation and long-term persistence in nephrogenic systemic fibrosis

Jerrold L. Abraham、Charu Thakral、Lone Skov 等 5 位作者2007-12-07British Journal of Dermatology

BACKGROUND: Gadolinium (Gd)-based magnetic resonance contrast agents (GBMCA), including gadodiamide, have been identified as the probable causative agents of the serious disease, nephrogenic systemic fibrosis (NSF). OBJECTIVES: To investigate retained Gd-containing deposits in skin biopsies from patients with NSF and…

Lanthanide and Transition Metal ComplexesInorganic Fluorides and Related CompoundsGeochemistry and Elemental Analysis

Evaluation of the skin sensitizing potential of biodegradable magnesium alloys

Frank Witte、Inken Abeln、Elinor Switzer 等 6 位作者2007-12-07Journal of Biomedical Materials Research Part A

Corroding metals made of magnesium alloys represent a new class of degradable implants for musculoskeletal surgery. These implants may be associated with skin sensitizing reactions because of the release of metal ions. This study was conducted to compare the sensitizing potential of four different magnesium alloys (AZ…

Engineering and Materials Science StudiesOrthopaedic implants and arthroplastyMagnesium Alloys: Properties and Applications

Bulk Growth and Characterization of a Novel Nonlinear Optical Crystal BaTeMo2O9

Weiguo Zhang、Xutang Tao、Chengqian Zhang 等 9 位作者2007-12-07Crystal Growth & Design

A new nonlinear optical crystal BaTeMo 2 O 9 was grown from the TeO 2 −MoO 3 flux system with sufficient size (30 × 23 × 18 mm 3 ) and optical quality that allowed the characterization of its properties. It crystallizes in the noncentrosymmetrical system, space group P 2 1 (no. 4), with a = 5.5346 Å, b = 7.4562 Å, c =…

Optical and Acousto-Optic TechnologiesNonlinear Optical Materials ResearchCrystal Structures and Properties

Glasses for Seeing Beyond Visible

Xianghua Zhang、Bruno Bureau、Pierre Lucas 等 5 位作者2007-12-07Chemistry - A European Journal

Conventional glasses based on oxides have a transparency limited by phonon absorption in the near IR region and have a limited interest for analyzing information located far beyond the visible. The IR spectral domain is nevertheless of prime interest, since it covers fundamental wavelength ranges used for thermal imag…

Glass properties and applicationsPhase-change materials and chalcogenidesThermography and Photoacoustic Techniques

Realizable response matrices of multiterminal electrical, acoustic, and elastodynamic networks at a given frequency

Graeme W. Milton、Pierre Seppecher2007-12-07arXiv

We give a complete characterization of the possible response matrices at a fixed frequency of n-terminal electrical networks of inductors, capacitors, resistors and grounds, and of n-terminal discrete linear elastodynamic networks of springs and point masses, both in the three-dimensional case and in the two-dimension…

Materials Science

Pyrometric Measurement of the Temperature of Shocked Molybdenum

Achim Seifter、Damian C. Swift2007-12-07arXiv

Measurements of the temperature of Mo shocked to ~60 GPa and then released to ~28 GPa were previously attempted using high explosive driven flyer plates and pyrometry. Analysis of the radiance traces at different wavelengths indicates that the temporal evolution of the radiance can be explained by a contribution from…

Materials Science

Magnetocaloric effect in R2Ti3Ge4 (R = Gd, Tb and Er) Compounds

R. Nirmala、Darshan C. Kundaliya、A. V. Morozkin 等 4 位作者2007-12-07arXiv

Heat capacity of polycrystalline R2Ti3Ge4 (R = Gd, Tb and Er) compounds (Orthorhombic, Sm5Ge4-type, Space group Pnma) has been studied in the temperature range of 1.8 K to 300 K in various applied magnetic fields. The compounds with magnetic lanthanide elements show interesting low field magnetism intrigued by possibl…

Materials Science

Factors influencing the martensitic transformation in Ni 50 Mn 35 Sn 15 : an EXAFS study

P A Bhobe、K R Priolkar、P R Sarode2007-12-07Journal of Physics Condensed Matter

Extended x-ray absorption fine-structure (EXAFS) measurements have been carried out on Ni$_{50}$Mn$_{35}$Sn$_{15}$ in the austenitic and martensitic phase. The temperatures associated with structural and magnetic phase transformations are obtained from magnetization measurements. The system orders ferromagnetically be…

Shape Memory Alloy TransformationsMagnetic and transport properties of perovskites and related materialsThermal Expansion and Ionic Conductivity

Non-adiabatic Effects in the Dissociation of Oxygen Molecules at the Al(111) Surface

Jorg Behler、Karten Reuter、Matthias Scheffler2007-12-07arXiv

The measured low initial sticking probability of oxygen molecules at the Al(111) surface that had puzzled the field for many years was recently explained in a non-adiabatic picture invoking spin-selection rules [J. Behler et al., Phys. Rev. Lett. 94, 036104 (2005)]. These selection rules tend to conserve the initial s…

Materials Science

Linear optical response of current-carrying molecular junction: A NEGF-TDDFT approach

Michael Galperin、Sergei Tretiak2007-12-07arXiv

We propose a scheme for calculation of linear optical response of current-carrying molecular junctions for the case when electronic tunneling through the junction is much faster than characteristic time of external laser field. We discuss relationships between nonequilibrium Green function (NEGF) and time-dependent de…

Materials ScienceMesoscale and Nanoscale Physics

High multipole transitions in NIXS: valence and hybridization in 4f systems

R. A. Gordon、G. T. Seidler、T. T. Fister 等 7 位作者2007-12-07arXiv

Momentum-transfer (q) dependent non-resonant inelastic x-ray scattering measurements were made at the N4,5 edges for several rare earth compounds. With increasing q, giant dipole resonances diminish, to be replaced by strong multiplet lines at lower energy transfer. These multiplets result from two different orders of…

Strongly Correlated ElectronsMaterials Science

Tunable n‐Type Conductivity and Transport Properties of Ga‐doped ZnO Nanowire Arrays

G. D. Yuan、Wenjun Zhang、Jiansheng Jie 等 9 位作者2007-12-07Advanced Materials

Well-aligned ZnO nanowires (NWs) with tunable n-type conductivity are synthesized by introducing Ga2O3 as a dopant source in thermal evaporation. The crystallographic orientation of the NWs depends on the dopant content. Electrical transport property measurements on single nanowires verify that the resistivity of ZnO…

ZnO doping and propertiesGa2O3 and related materialsGas Sensing Nanomaterials and Sensors

A comparative study of the magnetic properties of bulk and nanocrystalline Co3O4

Prasanta Dutta、M. S. Seehra、Subhash Thota 等 4 位作者2007-12-07Journal of Physics Condensed Matter

A comparative study of the magnetic and electron paramagnetic resonance (EPR) parameters of bulk and Co3O4 nanoparticles (NP), synthesized by a sol–gel process, is presented. Both samples possess the cubic phase with a slightly lower (by 0.34%) lattice parameter for the Co3O4 NP. The average crystallite size D = 17 nm…

Magnetic Properties and Synthesis of FerritesIron oxide chemistry and applicationsMagnetism in coordination complexes

Tunable Emission from Binary Organic One‐Dimensional Nanomaterials: An Alternative Approach to White‐Light Emission

Yong Sheng Zhao、Hongbo Fu、Fangqin Hu 等 6 位作者2007-12-07Advanced Materials

Uniformly doped crystalline organic nanorods and nanowires are prepared by adsorbent-assisted physical vapor deposition. The emission color of the binary 1D nanomaterials can be controlled – and made to approach white light (see figure) – by changing the doping content, which is ascribed to intermolecular fluorescence…

Luminescence and Fluorescent MaterialsConducting polymers and applicationsOrganic Electronics and Photovoltaics

Towards a microscopic theory of toroidal moments in bulk periodic crystals

Claude Ederer、Nicola A. Spaldin2007-12-07Physical Review B

We present a theoretical analysis of magnetic toroidal moments in periodic systems, in the limit in which the toroidal moments are caused by a time and space reversal symmetry breaking arrangement of localized magnetic dipole moments. We summarize the basic definitions for finite systems and address the question of ho…

Advanced Condensed Matter PhysicsMagnetic and transport properties of perovskites and related materialsMultiferroics and related materials

Wetting of Silicon Nanograss: From Superhydrophilic to Superhydrophobic Surfaces

Christian Dorrer、Jürgen Rühe2007-12-07Advanced Materials

The generation of “nanograss” surfaces, where the surface chemistry of nanorough silicon is precisely adjusted by the photochemical immobilization of polymeric thin films, is reported. The wetting properties of the surfaces can range from superwetting to impaled drops and superhydrophobicity. Superhydrophobic nanogras…

Surface Modification and SuperhydrophobicityElectrohydrodynamics and Fluid DynamicsNanomaterials and Printing Technologies